TY  - JOUR
AB  - Fenton's reagent (Fe2+/H2O2) is known as one of the most effective and most often employed advanced oxidation process (AOPs) for the treatment of textile dyes and dyehouse effluent. In the present study, a synthetic acid dyebath effluent (SADB) bearing two azo and one anthraquinone dye together with two dye auxiliaries was subjected to pretreatment with Fenton's reagent. Firstly, initial Fe2+ and H2O2 concentrations as well as pH were optimized to achieve highest COD and color removals during Fenton's treatment of SADB. In the second stage of the experimental work, kinetic studies were conducted to elucidate the effect of operating temperature (20 °C &lt; T &lt; 60 °C) on COD, color abatement and H2O2 consumption kinetics. Obtained results indicated that 30% COD and practically complete color removal (99%) could be achieved at T = 50 °C. The kinetic studies revealed that a strong correlation existed between COD removal and H2O2 utilization rates. In the final part of the study, the acute toxicity of raw (untreated) and pretreated SADB on heterotrophic biomass was investigated employing a modified (COD-balanced), activated sludge inhibition test. The toxicity experiments demonstrated that the inhibitory effect of SADB towards sewage sludge could be completely eliminated when the effluent was pretreated with Fenton's reagent.
AU  - Alaton, Idil Arslan
AU  - Teksoy, Senem
DA  - 2007
DO  - 10.1016/j.dyepig.2005.09.027
DP  - ScienceDirect
J2  - Dyes and Pigments
KW  - Acid dyebath effluent
Activated sludge inhibition
Acute toxicity
Advanced oxidation processes (AOPs)
Fenton's pretreatment
Thermal enhancement
L1  - files/498/Alaton and Teksoy - 2007 - Acid dyebath effluent pretreatment using Fenton's .pdf
M1  - 1
PY  - 2007
SN  - 0143-7208
SP  - 31-39
ST  - Acid dyebath effluent pretreatment using Fenton's reagent
T2  - Dyes and Pigments
TI  - Acid dyebath effluent pretreatment using Fenton's reagent: Process optimization, reaction kinetics and effects on acute toxicity
UR  - http://www.sciencedirect.com/science/article/pii/S0143720805003311
files/497/S0143720805003311.html
VL  - 73
Y2  - 2013/01/15/09:25:35
ID  - 178
ER  - 


TY  - JOUR
AB  - This study evaluates the effectiveness of Fenton's oxidation (FO) process and ozone (O3) oxidation compared with a coagulation–flocculation (CF) process to remove effluent toxicity as well as colour and COD from a textile industry wastewater. Daphnia magna was used to test acute toxicity in raw and pre-treated wastewater. The operational parameters for each process were determined on the basis of complete toxicity removal. The FO process removed COD at a higher rate (59%) than O3 (33%) while colour removal was similar (89% and 91%, respectively). The CF process removed both COD and colour at rates similar to the FO process. A colour range of 150–250 platin–cobalt (Pt–Co) unit was assessed for toxicity.
AU  - Meriç, Süreyya
AU  - Selçuk, Hüseyin
AU  - Belgiorno, Vincenzo
DA  - 2005/03//
DO  - 10.1016/j.watres.2004.12.021
DP  - ScienceDirect
J2  - Water Research
KW  - Acute toxicity
Coagulation and flocculation
Colour and COD removal
Daphnia magna
Fenton's oxidation process
ozonation
Textile finishing effluent
L1  - files/510/Meriç et al. - 2005 - Acute toxicity removal in textile finishing wastew.pdf
M1  - 6
PY  - 2005
SN  - 0043-1354
SP  - 1147-1153
ST  - Acute toxicity removal in textile finishing wastewater by Fenton's oxidation, ozone and coagulation–flocculation processes
T2  - Water Research
TI  - Acute toxicity removal in textile finishing wastewater by Fenton's oxidation, ozone and coagulation–flocculation processes
UR  - http://www.sciencedirect.com/science/article/pii/S0043135404006074
files/509/S0043135404006074.html
VL  - 39
Y2  - 2013/01/15/09:41:07
ID  - 179
ER  - 


TY  - JOUR
AB  - Removal of simazine from aqueous solution by Fenton's reagent oxidation was investigated. Box–Behnken statistical experiment design and the response surface methods were used to investigate the effects of simazine, H2O2 and Fe (II) concentrations on simazine degradation and mineralization. Total organic carbon (TOC) and simazine removals were investigated at different reagent doses to determine the experimental conditions yielding the highest removal of simazine and TOC. Fe (II) concentration had more profound effect than H2O2 for simazine removal while all parameters affected mineralization (TOC removal). Complete disappearance of simazine was achieved within 6 min reaction period. However, only 32% of simazine was mineralized after 15 min indicating formation of some intermediate products. The optimal H2O2/Fe (II)/simazine ratio resulting in the maximum pesticide (100%) and TOC removal (32%) was found to be 55/15/3 (mg L−1). The initial rate of simazine degradation was found to be first-order with respect to the initial simazine concentration.
AU  - Catalkaya, Ebru Cokay
AU  - Kargi, Fikret
DA  - 2009/09/15/
DO  - 10.1016/j.jhazmat.2009.02.091
DP  - ScienceDirect
J2  - Journal of Hazardous Materials
KW  - Advanced oxidation
Box–Behnken design
Fenton's reagent
Reagent doses
Simazine
L1  - files/522/Catalkaya and Kargi - 2009 - Advanced oxidation and mineralization of simazine .pdf
M1  - 2–3
PY  - 2009
SN  - 0304-3894
SP  - 688-694
ST  - Advanced oxidation and mineralization of simazine using Fenton's reagent
T2  - Journal of Hazardous Materials
TI  - Advanced oxidation and mineralization of simazine using Fenton's reagent
UR  - http://www.sciencedirect.com/science/article/pii/S0304389409002775
files/521/S0304389409002775.html
VL  - 168
Y2  - 2013/01/15/09:43:56
ID  - 180
ER  - 


TY  - JOUR
AB  - Advanced oxidation of amoxicillin was realized in aqueous solution by using Fenton's reagent treatment. Box–Behnken statistical experiment design was used to determine the effects of reagent concentrations on amoxicillin degradation and mineralization. Amoxicillin (10–200 mg L−1), hydrogen peroxide (10–500 mg L−1) and Fe(II) (0–50 mg L−1) concentrations were considered as independent variables in batch oxidation experiments. Percent amoxicillin and total organic carbon (TOC) removals (mineralization) were considered as the objective functions to be maximized. Required reaction times were 2.5 min and 15 min, respectively for degradation and mineralization of amoxicillin. Both peroxide and amoxicillin concentrations affected the extent of amoxicillin degradation and mineralization. Complete amoxicillin degradation was obtained within 2.5 min while 37% mineralization took place within 15 min. The optimum peroxide/Fe/amoxicillin ratio resulting in complete amoxicillin degradation and 37% mineralization was 255/25/105 mg L−1.
AU  - Ay, Filiz
AU  - Kargi, Fikret
DA  - 2010/07/15/
DO  - 10.1016/j.jhazmat.2010.03.048
DP  - ScienceDirect
J2  - Journal of Hazardous Materials
KW  - Advanced oxidation
Amoxicillin
Degradation
Fenton reagent
Mineralization
TOC removal
L1  - files/501/Ay and Kargi - 2010 - Advanced oxidation of amoxicillin by Fenton's reag.pdf
M1  - 1–3
PY  - 2010
SN  - 0304-3894
SP  - 622-627
ST  - Advanced oxidation of amoxicillin by Fenton's reagent treatment
T2  - Journal of Hazardous Materials
TI  - Advanced oxidation of amoxicillin by Fenton's reagent treatment
UR  - http://www.sciencedirect.com/science/article/pii/S0304389410003547
files/500/S0304389410003547.html
VL  - 179
Y2  - 2013/01/15/09:35:17
ID  - 181
ER  - 


TY  - JOUR
AU  - Heredia, Jesús Beltrán de
AU  - Domínguez, Joaquín R.
AU  - López, Raquel
DA  - 2004/04//
DO  - 10.1002/jctb.1002
DP  - CrossRef
L1  - files/427/wiley_Advanced oxidation of cork-processing wastewater.pdf
M1  - 4
PY  - 2004
SN  - 0268-2575, 1097-4660
SP  - 407-412
ST  - Advanced oxidation of cork-processing wastewater using Fenton's reagent
T2  - Journal of Chemical Technology & Biotechnology
TI  - Advanced oxidation of cork-processing wastewater using Fenton's reagent: kinetics and stoichiometry
UR  - http://doi.wiley.com/10.1002/jctb.1002
VL  - 79
Y2  - 2012/12/25/09:23:05
ID  - 291
ER  - 


TY  - JOUR
AB  - The use of Fenton's reagents in destruction of waste material present in Tambla Tributory (Durgapur,India) industrial wastewater has been investigated. Significant drop in COD removal has been observed. Optimisation of process parameters like pH, temperature, H2O2 and FeSO4 has been done. Temperature and pH played a key role in this treatment process, in addition the process initially liberated heat due to reaction between FeSO4 and H2O2. From the experimental results it has been observed that with increasing FeSO4 and H2O2 concentration the degradation of waste increases. At an optimum concentration of FeSO4 (6 gm/l) and H2O2 44.40 gm/l reduced 60% COD, whereas 220gm/l H2O2 was required for 95% COD removal. To reduce cost and the H2O2 concentration for maximum waste degradation, Fenton's oxidation process followed by biochemical treatment was tried at same experimental condition. The treatment enhanced the overall removal efficiency of COD, BOD, salinity and colour significantly. The microbial treatment by Thiobacillus ferrooxidans, following Fenton's reagents treatment, showed that the COD reduction has reached to about 97% compared to 60% with Fenton's reagents and 17% with T. ferrooxidans alone in 24 h, showing the synergistic effect. Thus the combined treatment results indicate the possibility to minimize the Fenton's reagents without compromising the efficiency of the process but ultimately reducing the overall treatment cost. This study seems to be very much important and economical by reducing the required H2O2 amount to about five times using a suitable micro-organism. This hybrid treatment system showed 97% COD reduction can be achieved within two days.
AU  - Mandal, Tamal
AU  - Maity, Sudakshina
AU  - Dasgupta, Dalia
AU  - Datta, Siddhartha
DA  - 2010/01/01/
DO  - 10.1016/j.desal.2009.04.012
DP  - ScienceDirect
J2  - Desalination
KW  - Biochemical treatment (T. ferrooxidans)
Combined treatment process
Fenton's oxidation and coagulation
Fenton's reagents
H2O2/FeSo4 ratio
Synergistic effect
Wastewater
L1  - files/486/Mandal et al. - 2010 - Advanced oxidation process and biotreatment Their.pdf
M1  - 1
PY  - 2010
SN  - 0011-9164
SP  - 87-94
ST  - Advanced oxidation process and biotreatment
T2  - Desalination
TI  - Advanced oxidation process and biotreatment: Their roles in combined industrial wastewater treatment
UR  - http://www.sciencedirect.com/science/article/pii/S0011916409009060
files/485/S0011916409009060.html
VL  - 250
Y2  - 2013/01/15/09:19:04
ID  - 182
ER  - 


TY  - JOUR
AU  - Pignatello, Joseph J.
AU  - Oliveros, Esther
AU  - MacKay, Allison
DA  - 2006/01//
DO  - 10.1080/10643380500326564
DP  - CrossRef
L1  - files/445/10643380500326564.pdf
files/454/10643380500326564.pdf
M1  - 1
PY  - 2006
SN  - 1064-3389, 1547-6537
SP  - 1-84
ST  - Advanced Oxidation Processes for Organic Contaminant Destruction Based on the Fenton Reaction and Related Chemistry
T2  - Critical Reviews in Environmental Science and Technology
TI  - Advanced Oxidation Processes for Organic Contaminant Destruction Based on the Fenton Reaction and Related Chemistry
UR  - http://login.oaresciences.org/whalecomwww.tandfonline.com/whalecom0/doi/full/10.1080/10643380500326564
files/238/10643380500326564.html
VL  - 36
Y2  - 2013/01/14/09:47:31
ID  - 313
ER  - 


TY  - JOUR
AB  - The protection and conservation of natural resources is one of the main priorities of modern society. Water is perhaps our most valuable resource, and thus should be recycled. Many of the current recycling techniques for polluted water only concentrate the pollutant without degrading it or eliminating it. In this sense, advanced oxidation processes are possibly one of the most effective methods for the treatment of wastewater containing organic products (effluents from chemical and agrochemical industries, the textile industry, paints, dyes, etc.). More conventional techniques cannot be used to treat such compounds because of their high chemical stability and/or low biodegradability. This article describes, classifies, and analyzes different types of advanced oxidation processes and their application to the treatment of polluted wastewater.
AU  - Poyatos, J. M.
AU  - Muñio, M. M.
AU  - Almecija, M. C.
AU  - Torres, J. C.
AU  - Hontoria, E.
AU  - Osorio, F.
DA  - 2010/01/01/
DO  - 10.1007/s11270-009-0065-1
DP  - link.springer.com
J2  - Water Air Soil Pollut
KW  - Advanced oxidation processes
Atmospheric Protection/Air Quality Control/Air Pollution
Climate Change
Dye
Environment, general
Hydrogeology
Polluted water
Recycling
Soil Science & Conservation
Waste Water Technology / Water Pollution Control / Water Management / Aquatic Pollution
L1  - files/342/Poyatos et al. - 2010 - Advanced Oxidation Processes for Wastewater Treatm.pdf
LA  - en
M1  - 1-4
PY  - 2010
SN  - 0049-6979, 1573-2932
SP  - 187-204
ST  - Advanced Oxidation Processes for Wastewater Treatment
T2  - Water, Air, and Soil Pollution
TI  - Advanced Oxidation Processes for Wastewater Treatment: State of the Art
UR  - http://link.springer.com/article/10.1007/s11270-009-0065-1
files/343/s11270-009-0065-1.html
VL  - 205
Y2  - 2013/01/15/04:58:07
ID  - 320
ER  - 


TY  - CHAP
A2  - Valdez, Benjamin
AU  - Heponiemi, Anne
AU  - Lassi, Ulla
DP  - CrossRef
L1  - files/423/InTech-Advanced_oxidation_processes_in_food_industry_wastewater_treatment_a_review.pdf
PB  - InTech
PY  - 2012
SN  - 978-953-307-905-9
ST  - Advanced Oxidation Processes in Food Industry Wastewater Treatment – A Review
T2  - Food Industrial Processes - Methods and Equipment
TI  - Advanced Oxidation Processes in Food Industry Wastewater Treatment – A Review
UR  - http://www.intechopen.com/books/food-industrial-processes-methods-and-equipment/advanced-oxidation-processes-in-food-industry-wastewater-treatment-a-review
files/422/advanced-oxidation-processes-in-food-industry-wastewater-treatment-a-review.html
Y2  - 2013/01/15/06:55:17
ID  - 292
ER  - 


TY  - JOUR
AU  - Güçlü, Dünyamin
AU  - Şirin, Nazan
AU  - Şahinkaya, Serkan
AU  - Sevimli, Mehmet Faik
DA  - 2011
DO  - 10.1002/ep.10626
DP  - CrossRef
L1  - files/426/wiley_cork processing wastewater treatment by fenton.pdf
PY  - 2011
SN  - 19447442
SP  - n/a-n/a
ST  - Advanced treatment of coking wastewater by conventional and modified fenton processes
T2  - Environmental Progress & Sustainable Energy
TI  - Advanced treatment of coking wastewater by conventional and modified fenton processes
UR  - http://doi.wiley.com/10.1002/ep.10626
Y2  - 2012/12/25/09:23:05
ID  - 293
ER  - 


TY  - JOUR
AB  - The performance of combined Fenton oxidation and membrane bioreactor (MBR) process for the advanced treatment of an effluent from an integrated dyeing wastewater treatment plant was evaluated. The experimental results revealed that under the optimum Fenton oxidation conditions (initial pH 5, H2O2 dosage 17 mmol/L, and Fe2+ 1.7 mmol/L) the average total organic carbon (TOC) and color removal ratios were 39.3% and 69.5% after 35 min of reaction, respectively. Results from Zahn-Wallens Test also represented that Fenton process was effective to enhance the biodegradability of the test wastewater. As for the further purification of MBR process, TOC removal capacity was examined at different hydraulic retention times (HRT) of 10, 18 and 25 hr. Under the optimum HRT of 18 hr, the average TOC concentration and color of the final MBR effluent were 16.8 mg/L and 2 dilution time, respectively. The sludge yield coefficient was 0.13 g MLSS/g TOC and TOC degradation rate was 0.078 kg TOC/(m3·day). The final effluent of MBR can meet the reuse criteria of urban recycling water - water quality standard for miscellaneous water consumption GBT18920-2002.
AU  - Feng, Fei
AU  - Xu, Zhenliang
AU  - Li, Xiaohuan
AU  - You, Wenting
AU  - Zhen, Yang
DA  - 2010/11//
DO  - 10.1016/s1001-0742(09)60303-x
DP  - ScienceDirect
J2  - Journal of Environmental Sciences
KW  - dyeing wastewater
Fenton oxidation
membrane bioreactor
Zahn-Wallens Test
L1  - files/143/Feng et al. - 2010 - Advanced treatment of dyeing wastewater towards re.pdf
M1  - 11
PY  - 2010
SN  - 1001-0742
SP  - 1657-1665
ST  - Advanced treatment of dyeing wastewater towards reuse by the combined Fenton oxidation and membrane bioreactor process
T2  - Journal of Environmental Sciences
TI  - Advanced treatment of dyeing wastewater towards reuse by the combined Fenton oxidation and membrane bioreactor process
UR  - http://www.sciencedirect.com/science/article/pii/S100107420960303X
files/142/S100107420960303X.html
VL  - 22
Y2  - 2013/01/14/04:09:22
ID  - 183
ER  - 


TY  - JOUR
AB  - A central composite factorial design methodology was employed to optimise the amoxicillin degradation using the Fenton's oxidation treatment. In this study, the variables considered for the process optimisation were the hydrogen peroxide and ferrous ion initial concentrations and the temperature, for an antibiotic concentration of 450 μg L− 1 at pH = 3.5. This methodology also allowed assessing and identifying the effects of the different factors studied and their interactions in the process response. An appropriate quadratic model was developed in order to plot the response surface and contour curves, which was used to perform the process optimisation. From this study, it was concluded that ferrous ion concentration and temperature were the variables that most influenced the response. Under the optimal conditions (hydrogen peroxide concentration = 3.50–4.28 mg L− 1, ferrous ion concentration = 254–350 μg L− 1 and temperature = 20–30 °C), it was possible to achieve total amoxicillin degradation after 30 min of reaction.
AU  - Homem, Vera
AU  - Alves, Arminda
AU  - Santos, Lúcia
DA  - 2010/11/15/
DO  - 10.1016/j.scitotenv.2010.08.058
DP  - ScienceDirect
J2  - Science of The Total Environment
KW  - Amoxicillin
Antibiotic
Design of experiments
Fenton's reagent
L1  - files/504/Homem et al. - 2010 - Amoxicillin degradation at ppb levels by Fenton's .pdf
M1  - 24
PY  - 2010
SN  - 0048-9697
SP  - 6272-6280
ST  - Amoxicillin degradation at ppb levels by Fenton's oxidation using design of experiments
T2  - Science of The Total Environment
TI  - Amoxicillin degradation at ppb levels by Fenton's oxidation using design of experiments
UR  - http://www.sciencedirect.com/science/article/pii/S0048969710009319
files/503/S0048969710009319.html
VL  - 408
Y2  - 2013/01/15/09:35:17
ID  - 184
ER  - 


TY  - JOUR
AB  - Industrial and remedial processes produce wastewater containing chelated heavy metal. Chelated heavy metal containing wastewater needs to be treated not only for the toxic heavy metal, but also for the chelating agent. The treatment of strong stability chelated heavy metal wastewater is a hot and difficult issue in these years. To solve this problem, a novel strategy, advanced Fenton-chemical precipitation process (AF-CPP) is proposed to address chelated heavy metal containing wastewater. The process uses zero-valent iron and hydrogen peroxide for degrading the chelated compound, followed by alkali precipitation of heavy metal. NiEDTA was selected as a model of strong stability of chelated heavy metal pollutant. This process can remove not only nickel ions, but also reduces COD values. Parameters affecting nickel removal are discussed. At optimum condition, the nickel removal efficiency attained was 98.4% and the residual concentrations of nickel fell below the value stipulated in Integrated Wastewater Discharge Standard of China (GB8978-1996). AF-CPP appears promising and effective for the treatment of strong stability chelated heavy metal containing wastewaters.
AU  - Fu, Fenglian
AU  - Xie, Liping
AU  - Tang, Bing
AU  - Wang, Qi
AU  - Jiang, Shuxian
DA  - 2012/05/01/
DO  - 10.1016/j.cej.2012.02.073
DP  - ScienceDirect
J2  - Chemical Engineering Journal
KW  - Advanced Fenton-chemical precipitation process
Chelated heavy metal containing wastewater
Nickel
Removal efficiency
L1  - files/725/Fu et al. - 2012 - Application of a novel strategy—Advanced Fenton-ch.pdf
M1  - 0
PY  - 2012
SN  - 1385-8947
SP  - 283-287
ST  - Application of a novel strategy—Advanced Fenton-chemical precipitation to the treatment of strong stability chelated heavy metal containing wastewater
T2  - Chemical Engineering Journal
TI  - Application of a novel strategy—Advanced Fenton-chemical precipitation to the treatment of strong stability chelated heavy metal containing wastewater
UR  - http://www.sciencedirect.com/science/article/pii/S1385894712003063
files/724/S1385894712003063.html
VL  - 189–190
Y2  - 2013/01/16/06:34:39
ID  - 185
ER  - 


TY  - JOUR
AB  - The removal of organic matter (TOC and COD) from a cosmetic wastewater by Fenton oxidation treatment has been evaluated. The operating conditions (temperature as well as ferrous ion and hydrogen peroxide dosage) have been optimized. Working at an initial pH equal to 3.0, a Fe2+ concentration of 200 mg/L and a H2O2 concentration to COD initial weight ratio corresponding to the theoretical stoichiometric value (2.12), a TOC conversion higher than 45% at 25 °C and 60% at 50 °C was achieved. Application of the Fenton oxidation process allows to reach the COD regional limit for industrial wastewaters discharges to the municipal sewer system. A simple kinetic analysis based on TOC was carried out. A second-order equation describes well the overall kinetics of the process within a wide TOC conversion range covering up to the 80–90% of the maximum achievable conversion.
AU  - Bautista, P.
AU  - Mohedano, A. F.
AU  - Gilarranz, M. A.
AU  - Casas, J. A.
AU  - Rodriguez, J. J.
DA  - 2007/05/08/
DO  - 10.1016/j.jhazmat.2006.09.004
DP  - ScienceDirect
J2  - Journal of Hazardous Materials
KW  - Cosmetic wastewater
Fenton's reagent
Kinetics
Oxidation
L1  - files/465/Bautista et al. - 2007 - Application of Fenton oxidation to cosmetic wastew.pdf
M1  - 1–2
PY  - 2007
SN  - 0304-3894
SP  - 128-134
ST  - Application of Fenton oxidation to cosmetic wastewaters treatment
T2  - Journal of Hazardous Materials
TI  - Application of Fenton oxidation to cosmetic wastewaters treatment
UR  - http://www.sciencedirect.com/science/article/pii/S0304389406010442
files/464/S0304389406010442.html
VL  - 143
Y2  - 2013/01/15/09:01:16
ID  - 186
ER  - 


TY  - JOUR
AU  - Argun, Mehmet Emin
AU  - Karatas, Mustafa
DA  - 2011/12//
DO  - 10.1002/ep.10504
DP  - CrossRef
L1  - files/424/wiley_kinetic and thermodynamic by fenton.pdf
M1  - 4
PY  - 2011
SN  - 19447442
SP  - 540-548
ST  - Application of Fenton process for decolorization of reactive black 5 from synthetic wastewater
T2  - Environmental Progress & Sustainable Energy
TI  - Application of Fenton process for decolorization of reactive black 5 from synthetic wastewater: Kinetics and thermodynamics
UR  - http://doi.wiley.com/10.1002/ep.10504
VL  - 30
Y2  - 2012/12/25/09:23:05
ID  - 295
ER  - 


TY  - CHAP
A2  - Stoytcheva, Margarita
AU  - Ratanatamskul, Chavalit
AU  - Masomboon, Nalinrut
AU  - Lu, Ming-Chun
DP  - CrossRef
L1  - files/420/InTech-Application_of_fenton_processes_for_degradation_of_aniline.pdf
PB  - InTech
PY  - 2011
SN  - 978-953-307-459-7
ST  - Application of Fenton Processes for Degradation of Aniline
T2  - Pesticides in the Modern World - Pesticides Use and Management
TI  - Application of Fenton Processes for Degradation of Aniline
UR  - http://www.intechopen.com/books/pesticides-in-the-modern-world-pesticides-use-and-management/application-of-fenton-processes-for-degradation-of-aniline
files/259/application-of-fenton-processes-for-degradation-of-aniline.html
Y2  - 2013/01/14/10:27:36
ID  - 296
ER  - 


TY  - JOUR
AB  - The effectiveness of Fenton process in municipal landfill leachate treatment, as a pre- or post-treatment approach, has been demonstrated. However, no general recommendations of universal validity could be made in the term of optimized conditions affecting Fenton process. At the first stage of this study, collected leachate samples from Aradkooh site, Tehran, Iran, were investigated using one-factor-at-a-time method to find out optimum coagulation pH and flocculation time values. Subsequently, the obtained results in addition to data issued previously by the authors were employed to develop a predictive model of the true response surface, namely chemical oxygen demand (COD) removal efficiency. Finally, the main parameters of Fenton procedure, i.e. initial pH, [H2O2]/[Fe2+] molar ratio, Fe2+ dosage, and coagulation pH were optimized taking advantage of the above-mentioned quadratic model. The derived second-order model included both significant linear and quadratic terms and seemed to be adequate in predicting responses (R2 = 0.9896 and prediction R2 = 0.6954). It was found that the interaction between initial pH and Fe2+ dosage has a significant effect on COD removal. While, the optimal [H2O2]/[Fe2+] molar ratio was independent of ferrous ion dosage. The optimum conditions for the maximum COD removal of 50.76% for the parameters of initial pH, [H2O2]/[Fe2+] molar ratio, Fe2+ dosage, and coagulation pH were found to be 5.8, 8.0, 22,500 mg/L, and 8.7 respectively.
AU  - Ghanbarzadeh Lak, Mehdi
AU  - Sabour, Mohammad Reza
AU  - Amiri, Allahyar
AU  - Rabbani, Omid
DA  - 2012/10//
DO  - 10.1016/j.wasman.2012.05.020
DP  - ScienceDirect
J2  - Waste Management
KW  - Analysis of variance (ANOVA)
Fenton treatment
landfill leachate
Optimization
Quadratic regression model
L1  - files/555/Ghanbarzadeh Lak et al. - 2012 - Application of quadratic regression model for Fent.pdf
M1  - 10
PY  - 2012
SN  - 0956-053X
SP  - 1895-1902
ST  - Application of quadratic regression model for Fenton treatment of municipal landfill leachate
T2  - Waste Management
TI  - Application of quadratic regression model for Fenton treatment of municipal landfill leachate
UR  - http://www.sciencedirect.com/science/article/pii/S0956053X12002292
files/554/S0956053X12002292.html
VL  - 32
Y2  - 2013/01/15/13:04:02
ID  - 187
ER  - 


TY  - JOUR
AB  - The central composite design (CCD) technique was used to study the effect of the Fenton's peroxidation on the removal of organic pollutants from olive oil mill wastewater (OMW). The ratio of hydrogen peroxide-to-Fe(II) (x1) was between 1.67 and 8.33. Fe(II) concentration was constant at 0.03 M while the H2O2 concentration was set at three levels: 0.05, 0.15 and 0.25 M. Based on the molarity ratio, the selected ratio were in the low range of Fe(II)-to-H2O2 ratio (≪1). While based on the wt/wt ratio, the tested Fe(II)-to-H2O2 ratios were in the range of ≤1:5. pH (x2) was between 3 and 5. The concentration of OMW (x3) was varied between 40 and 100%. The influence of these three independent variables on the four dependent variables, i.e. COD, total phenolics (TP), color and aromatocity removal was evaluated using a second-order polynomial multiple regression model. Analysis of variance (ANOVA) showed a high coefficient of determination (R2) value of 0.902–0.998, thus ensuring a satisfactory adjustment of the second-order regression model with the experimental data. H2O2-to-Fe(II) ratio had significant effect on all the four dependent variables. The positive sign for the regression coefficient of this regressor variable indicated that the level of the pollutant removal increased with the increased levels of factor x1 from 1.67 to 8.33 and this effect was the most pronounced for TP removal. pH had also significant effect on the pollutant removal and the effect was the most noticeable for TP reduction. The negative coefficient of this variable (pH) indicated that level of the pollutant removal decreased as the pH increased from 3 to 5. The negative coefficient of the interaction between variable x1 and x2 indicated that a simultaneous increase in H2O2-to-Fe(II) ratio with decrease in the pH of the reaction led to an increase in the COD, TP and color removal. Quadratic models were predicted for the response variable, i.e. pollutant removal, and the maximum model-predicted removals were 56, 100, 33 and 32% for COD, TP, color and aromatocity, respectively. Optimum conditions for this wastewater treatment was obtained based on the performance of the Fenton's peroxidation in the experiment where the H2O2-to-Fe(II) ratio was at its high level (8.33) and the pH and OMW concentration were 4 and 70%, respectively.
AU  - Ahmadi, M.
AU  - Vahabzadeh, F.
AU  - Bonakdarpour, B.
AU  - Mofarrah, E.
AU  - Mehranian, M.
DA  - 2005/08/31/
DO  - 10.1016/j.jhazmat.2005.03.042
DP  - ScienceDirect
J2  - Journal of Hazardous Materials
KW  - Advanced oxidation process
Central composite design
Empirical modeling
Fenton's peroxidation
Olive oil mill wastewater
Response surface methodology
L1  - files/155/Ahmadi et al. - 2005 - Application of the central composite design and re.pdf
M1  - 1–3
PY  - 2005
SN  - 0304-3894
SP  - 187-195
ST  - Application of the central composite design and response surface methodology to the advanced treatment of olive oil processing wastewater using Fenton's peroxidation
T2  - Journal of Hazardous Materials
TI  - Application of the central composite design and response surface methodology to the advanced treatment of olive oil processing wastewater using Fenton's peroxidation
UR  - http://www.sciencedirect.com/science/article/pii/S0304389405001615
files/154/S0304389405001615.html
VL  - 123
Y2  - 2013/01/14/04:20:24
ID  - 188
ER  - 


TY  - JOUR
AB  - Industrial wastewater typically contains various metal ions. Traditional metal ion treatment processes such as chemical precipitation generate large volumes of toxic sludge which needs to be further solidified or disposed of. The ferrite process (FP), which is another effective approach of treating metal ion-containing wastewater, can crystallize metal ions into ferrites; the sludge easily precipitates, is stable and can be recycling. This investigation explores the feasibility of the Fenton process and the FP (FFP) for treating wastewater that contains metal ions. It considers one factor that adds noise to the FP, ethylenediaminetetraacetic acid, and establishes the optimum parameters of each procedure. The analytical results demonstrate that the proper conditions for Fenton process were pH = 2, [Fe2+] = 10−2 M, H2O2 dosing rate = 5 × 10−4 mol min−1, reaction time = 12 min. For the proposed multi-stage FP, the preferred Fe2+ dosage was 0.098 mol in each stage and the sludge met the toxicity characteristic leaching procedure standards. Following the FFP, the effluent water or the sludge easily met Taiwan’s standards. Finally, the SEM test demonstrated that size of the sludge particles was 50–110 nm.
AU  - Lou, Jie-Chung
AU  - Huang, Yu-Jen
DA  - 2009/04/01/
DO  - 10.1007/s10661-008-0266-x
DP  - link.springer.com
J2  - Environ Monit Assess
KW  - Atmospheric Protection/Air Quality Control/Air Pollution
Ecology
Ecotoxicology
EDTA
Environmental Management
Fenton process
Ferrite process
L1  - files/297/Lou and Huang - 2009 - Assessing the performance of wastewater treatment .pdf
LA  - en
M1  - 1-4
PY  - 2009
SN  - 0167-6369, 1573-2959
SP  - 251-258
ST  - Assessing the performance of wastewater treatment with the combination of Fenton and ferrite process
T2  - Environmental Monitoring and Assessment
TI  - Assessing the performance of wastewater treatment with the combination of Fenton and ferrite process
UR  - http://link.springer.com/article/10.1007/s10661-008-0266-x
files/298/s10661-008-0266-x.html
VL  - 151
Y2  - 2013/01/15/04:12:03
ID  - 321
ER  - 


TY  - JOUR
AB  - The recycling of domestic wastewater is an effective means of coping with the water shortage in Tunisia. After hydrogen peroxide oxidation, the refractory organic substances in wastewater were decomposed. COD, offensive odor and foaminess in the effluents were reduced with increasing dose. Hydrogen peroxide oxidizes both organic and inorganic pollutants which contribute to BOD and COD. The Oxidation of sulfides into sulfates by H2O2 may be applied directly to aqueous wastes containing these odorants. Inactivation efficiencies of bacteria in the secondary effluents by H2O2 oxidation was investigated. The number of total coliforms exponentially decreased with increasing dose and fell to low levels at the dose of 2.5 ml/L.
AU  - Ksibi, Mohamed
DA  - 2006/06/15/
DO  - 10.1016/j.cej.2006.03.022
DP  - ScienceDirect
J2  - Chemical Engineering Journal
KW  - BOD/COD
Deodorization and disinfection
Hydrogen peroxide
Wastewater
L1  - files/618/Ksibi - 2006 - Chemical oxidation with hydrogen peroxide for dome.pdf
M1  - 2–3
PY  - 2006
SN  - 1385-8947
SP  - 161-165
ST  - Chemical oxidation with hydrogen peroxide for domestic wastewater treatment
T2  - Chemical Engineering Journal
TI  - Chemical oxidation with hydrogen peroxide for domestic wastewater treatment
UR  - http://www.sciencedirect.com/science/article/pii/S1385894706001331
files/617/S1385894706001331.html
VL  - 119
Y2  - 2013/01/15/14:19:09
ID  - 189
ER  - 


TY  - JOUR
AB  - New instrumental methods and tendencies of development of direct potentiometric determination of the chemical oxygen demand in the framework of the standard technique are considered.
AU  - Pisarevsky, A. M.
AU  - Polozova, I. P.
AU  - Hockridge, P. M.
DA  - 2005/01/01/
DO  - 10.1007/s11167-005-0239-6
DP  - link.springer.com
J2  - Russ J Appl Chem
KW  - Chemistry/Food Science, general
Industrial Chemistry/Chemical Engineering
L1  - files/294/Pisarevsky et al. - 2005 - Chemical Oxygen Demand.pdf
LA  - en
M1  - 1
PY  - 2005
SN  - 1070-4272, 1608-3296
SP  - 101-107
ST  - Chemical Oxygen Demand
T2  - Russian Journal of Applied Chemistry
TI  - Chemical Oxygen Demand
UR  - http://link.springer.com/article/10.1007/s11167-005-0239-6
files/295/s11167-005-0239-6.html
VL  - 78
Y2  - 2013/01/15/04:06:52
ID  - 322
ER  - 


TY  - JOUR
AB  - Phenol oxidation by Fenton's reagent (H2O2 + Fe2+) in aqueous solution has been studied in depth for the purpose of learning more about the reactions involved and the extent of the oxidation process, under various operating conditions. An initial phenol concentration of 100 mg/L was used as representative of a phenolic industrial wastewater. Working temperatures of 25 and 50 °C were tested, and the initial pH was set at 3. The H2O2 and the Fe2+ doses were varied in the range of 500?5000 and 1?100 mg/L, respectively, corresponding to 1?10 times the stoichiometric ratio. A series of intermediates were identified, corresponding mainly to ring compounds and short-chain organic acids. Most significant among the former were catechol, hydroquinone, and p-benzoquinone; the main organic acids were maleic, acetic, oxalic, and formic, with substantially lower amounts of muconic, fumaric, and malonic acids. Under milder operating conditions (H2O2 and Fe2+ at lower concentrations), a great difference was found between the measured total organic carbon (TOC) and the amount of carbon in all analyzed species in the reaction medium. This difference decreased as the doses of H2O2 and Fe2+ increased, indicating that the unidentified compounds must correspond to oxidation intermediates between phenol and the organic acids. To establish a complete oxidation pathway, experiments were carried out using each of the identified intermediates as starting compounds. Dihydroxybenzenes were identified in the earlier oxidation stages. Muconic acid was detected in catechol but not in the hydroquinone and p-benzoquinone oxidation runs; the last two compounds were oxidized to maleic acid. Oxalic and acetic acid appeared to be fairly refractory to this oxidation treatment. A detailed knowledge of the time evolution of the oxidation intermediates is of environmental interest particularly in the case of hydroquinone and p-benzoquinone because their toxicities are several orders of magnitudes higher than that of phenol itself. The time evolution of the intermediates and TOC was fitted to a simple second-order kinetic equation, and the values of the kinetic constants were determined. This provides a simplified approach useful for design purposes.
AU  - Zazo, J. A.
AU  - Casas, J. A.
AU  - Mohedano, A. F.
AU  - Gilarranz, M. A.
AU  - Rodríguez, J. J.
DA  - 2005/12/01/
DO  - 10.1021/es050452h
DP  - ACS Publications
J2  - Environ. Sci. Technol.
L1  - files/746/Zazo et al. - 2005 - Chemical Pathway and Kinetics of Phenol Oxidation .pdf
files/748/es050452h.pdf
M1  - 23
PY  - 2005
SN  - 0013-936X
SP  - 9295-9302
ST  - Chemical Pathway and Kinetics of Phenol Oxidation by Fenton's Reagent
T2  - Environmental Science & Technology
TI  - Chemical Pathway and Kinetics of Phenol Oxidation by Fenton's Reagent
UR  - http://dx.doi.org/10.1021/es050452h
files/747/es050452h.html
VL  - 39
Y2  - 2013/01/16/07:30:30
ID  - 297
ER  - 


TY  - JOUR
AB  - Various chemical wet oxidation techniques to remove toxic non-biodegradable pollutants from wastewater were compared in this work. Techniques applied included catalytic wet air oxidation (CWAO) over active carbon (AC) alone and with hydrogen peroxide (H2O2) as well as wet peroxide oxidation (WPO) without or plus Fe2+ initiator. The oxidation tests were conducted in a Trickle Bed Reactor and a tubular coil reactor at 25–550°C and 10–150 bar. The refractoriness to chemical wet oxidation was investigated for various organic pollutants including phenol, o-cresol, m-xylene, o-chlorophenol, p-nitrophenol, aniline, nitrobenzene, sulfolane and two industrial phenolic wastewater. CWAO over AC destroyed readily phenol, o-cresol, m-xylene and o-chlorophenol at 140°C and 9 bar of O2. More refractory aniline, p-nitrophenol, and particularly sulfolane and nitrobenzene, were tested with either H2O2 promoted CWAO or WPO at higher temperatures. The use of Fe2+ initiator was attempted to reduce the treatment severity of WPO. In a final step, the wet oxidation techniques were tested on the industrial effluents to obtain treatment efficiencies under field conditions.
AU  - Stüber, F.
AU  - Font, J.
AU  - Eftaxias, A.
AU  - Paradowska, M.
AU  - Suarez, M. E.
AU  - Fortuny, A.
AU  - Bengoa, C.
AU  - Fabregat, A.
DA  - 2005/07//
DO  - 10.1205/psep.05017
DP  - ScienceDirect
J2  - Process Safety and Environmental Protection
KW  - active carbon
CWAO
Fe2+
H2O2 promotion
Industrial wastewater
Organic pollutants
WPO
L1  - files/579/Stüber et al. - 2005 - Chemical Wet Oxidation for the Abatement of Refrac.pdf
M1  - 4
PY  - 2005
SN  - 0957-5820
SP  - 371-380
ST  - 7th World Congress of Chemical Engineering
T2  - Process Safety and Environmental Protection
TI  - Chemical Wet Oxidation for the Abatement of Refractory Non-Biodegradable Organic Wastewater Pollutants
UR  - http://www.sciencedirect.com/science/article/pii/S0957582005712659
files/578/S0957582005712659.html
VL  - 83
Y2  - 2013/01/15/13:38:51
ID  - 190
ER  - 


TY  - JOUR
AB  - Peroxide damage of albumin by the action of iron(II) sulfate-hydrogen peroxide was studied by the chemiluminescence method. Orders of the reaction with respect to particular reactants were determined, and side processes complicating the peroxidation were identified.
AU  - Shugalei, I. V.
AU  - Lukogorskaya, S. A.
AU  - Guseinova, V. V.
AU  - Ivanova, A. A.
AU  - Dubyago, N. P.
AU  - Tselinskii, I. V.
AU  - Yudin, I. V.
DA  - 2008/06/01/
DO  - 10.1134/s1070363208060182
DP  - link.springer.com
J2  - Russ J Gen Chem
KW  - Chemistry/Food Science, general
L1  - files/386/Shugalei et al. - 2008 - Chemiluminescence study on peroxide damage of albu.pdf
LA  - en
M1  - 6
PY  - 2008
SN  - 1070-3632, 1608-3350
SP  - 1206-1209
ST  - Chemiluminescence study on peroxide damage of albumin, initiated by Fenton’s reagent
T2  - Russian Journal of General Chemistry
TI  - Chemiluminescence study on peroxide damage of albumin, initiated by Fenton’s reagent
UR  - http://link.springer.com/article/10.1134/S1070363208060182
files/387/S1070363208060182.html
VL  - 78
Y2  - 2013/01/15/05:32:56
ID  - 323
ER  - 


TY  - JOUR
AB  - In this study, Reactive Black 5 (RB5) was removed from synthetic wastewater using Fenton’s oxidation (FO) process. Experiments were conducted on the samples containing 100 and 200 mg l−1 of RB5 to remove the dye toxicity. Seventy-five milligram per litre of RB5 caused 25% toxicity on 24-h born daphnids whereas 100 mg l−1 of RB5 displayed 100% toxicity on Daphnia magna. The study was performed in a systematic approach searching optimum values of FeSO4 and H2O2 concentrations, pH and temperature. Optimum pH and temperature for 100 mg l−1 of RB5 were observed as 3.0 and 40 °C, respectively, using 100 mg l−1 of FeSO4 and 400 mg l−1 of H2O2 resulted in 71% chemical oxygen demand (COD) and 99% color removal. For 200 mg l−1 of RB5, 84% COD removal was obtained using 225 mg l−1 of FeSO4 and 1000 mg l−1 of H2O2 yielding 0.05 molar ratio at pH 3.0 and 40 °C. Color removal was also more than 99%. The optimum conditions determined in accordance with the literature data. The H2O2 requirement seems to be related to initial COD of the sample. FeSO4/H2O2 ratios found were not changed for both concentrations. The temperature affected the COD removal significantly at high degrees. Toxicity was completely removed for each concentration of RB5 at optimum removal conditions.
AU  - Meriç, Süreyya
AU  - Kaptan, Deniz
AU  - Ölmez, Tuğba
DA  - 2004/01//
DO  - 10.1016/j.chemosphere.2003.08.010
DP  - ScienceDirect
J2  - Chemosphere
KW  - Color and COD removal
Fenton’s oxidation process
Reactive Black 5
Toxicity reduction
L1  - files/513/Meriç et al. - 2004 - Color and COD removal from wastewater containing R.pdf
M1  - 3
PY  - 2004
SN  - 0045-6535
SP  - 435-441
ST  - Color and COD removal from wastewater containing Reactive Black 5 using Fenton’s oxidation process
T2  - Chemosphere
TI  - Color and COD removal from wastewater containing Reactive Black 5 using Fenton’s oxidation process
UR  - http://www.sciencedirect.com/science/article/pii/S0045653503008038
files/512/S0045653503008038.html
VL  - 54
Y2  - 2013/01/15/09:41:07
ID  - 191
ER  - 


TY  - JOUR
AB  - Nowadays there is a continuously increasing worldwide concern for development of alternative water reuse technologies, mainly focused on agriculture and industry. In this context, Advanced Oxidation Processes (AOPs) are considered a highly competitive water treatment technology for the removal of those organic pollutants not treatable by conventional techniques due to their high chemical stability and/or low biodegradability. Although chemical oxidation for complete mineralization is usually expensive, its combination with a biological treatment is widely reported to reduce operating costs. This paper reviews recent research combining AOPs (as a pre-treatment or post-treatment stage) and bioremediation technologies for the decontamination of a wide range of synthetic and real industrial wastewater. Special emphasis is also placed on recent studies and large-scale combination schemes developed in Mediterranean countries for non-biodegradable wastewater treatment and reuse. The main conclusions arrived at from the overall assessment of the literature are that more work needs to be done on degradation kinetics and reactor modeling of the combined process, and also dynamics of the initial attack on primary contaminants and intermediate species generation. Furthermore, better economic models must be developed to estimate how the cost of this combined process varies with specific industrial wastewater characteristics, the overall decontamination efficiency and the relative cost of the AOP versus biological treatment.
AU  - Oller, I.
AU  - Malato, S.
AU  - Sánchez-Pérez, J. A.
DA  - 2011/09/15/
DO  - 10.1016/j.scitotenv.2010.08.061
DP  - ScienceDirect
J2  - Science of The Total Environment
KW  - Advanced oxidation processes
Biodegradability
Biological treatment
Industrial wastewater
Toxicity
L1  - files/203/Oller et al. - 2011 - Combination of Advanced Oxidation Processes and bi.pdf
M1  - 20
PY  - 2011
SN  - 0048-9697
SP  - 4141-4166
ST  - Combination of Advanced Oxidation Processes and biological treatments for wastewater decontamination—A review
T2  - Science of The Total Environment
TI  - Combination of Advanced Oxidation Processes and biological treatments for wastewater decontamination—A review
UR  - http://www.sciencedirect.com/science/article/pii/S0048969710009344
files/202/S0048969710009344.html
VL  - 409
Y2  - 2013/01/14/05:01:44
ID  - 192
ER  - 


TY  - JOUR
AB  - The technological and economic aspects of using the Fenton process to treat industrial wastewater containing morpholyne and diethylethanolamine, as well as sodium salts of naphthalene sulfonic acid and of ethylenediaminetetraacetic acid based on data obtained in pilot tests are discussed. Chemical Fenton technology was tested using commercial 30–35% solutions of H2O2 and iron (II) salts, which was followed by the additional electrochemical destruction of organic pollutants in an undivided reactor with catalytic stable anodes (CSA) and 1 g L−1 NaCl as a supporting electrolyte and a source of active chlorine. An alternative electrochemical method involving the electrogeneration of hydrogen peroxide in polluted water at the gas -diffusion cathode was studied both with the addition of ferrous salt to the electrolyte prior to electrolysis (in-cell electro-Fenton) as well as with the post-electrolysis addition of Fe2+ in another reactor (ex-cell electro-Fenton). The accumulation of hydrogen peroxide in concentrations sufficient for the mineralization of organic pollutants was achieved in both cases with near 100% current efficiency. In comparison with wastewater treatment processes which use a purchased hydrogen peroxide reagent, the Fenton-like processes achieved an economic savings of as much as 64.5% in running costs due to the on-site electrochemical generation of H2O2. Preparative electrolysis in the membrane reactor showed higher current efficiencies and lower specific energy consumptions for H2O2 electrogeneration in comparison with the results of tests carried out in an undivided cell.
AU  - Agladze, G. R.
AU  - Tsurtsumia, G. S.
AU  - Jung, B. I.
AU  - Kim, J. S.
AU  - Gorelishvili, G.
DA  - 2007/09/01/
DO  - 10.1007/s10800-007-9325-1
DP  - link.springer.com
J2  - J Appl Electrochem
KW  - Electrochemistry
Electro-Fenton
Gas-diffusion electrode
Hydrogen peroxide
Industrial Chemistry/Chemical Engineering
Physical Chemistry
Proton-exchange membrane
Wastewater treatment
L1  - files/300/Agladze et al. - 2007 - Comparative study of chemical and electrochemical .pdf
LA  - en
M1  - 9
PY  - 2007
SN  - 0021-891X, 1572-8838
SP  - 985-990
ST  - Comparative study of chemical and electrochemical Fenton treatment of organic pollutants in wastewater
T2  - Journal of Applied Electrochemistry
TI  - Comparative study of chemical and electrochemical Fenton treatment of organic pollutants in wastewater
UR  - http://link.springer.com/article/10.1007/s10800-007-9325-1
files/301/s10800-007-9325-1.html
VL  - 37
Y2  - 2013/01/15/04:17:23
ID  - 324
ER  - 


TY  - JOUR
AB  - Decolourisation of wastewater using Fenton (Fe2+/H2O2) and Fenton-like (Fe3+/H2O2) reactions was investigated and compared to that of a typical azo dye, C.I. Acid Black 1, under neutral conditions. The effects of different system variables namely initial concentration of Fe2+ or Fe3+, initial concentration of H2O2, initial pH of solution and reaction temperature were studied. Dye degradation in Fenton oxidation was faster initially than Fenton-like oxidation but the extent of degradation achieved for the two systems was similar after 100 min. The kinetics of Fenton oxidation is complex and can be described by a combined pseudo-first-order kinetic model while the Fenton-like reaction follows comparatively simpler, pseudo-first-order kinetics. The apparent reaction orders regarding Fe and H2O2 concentrations for the two systems were similar, with values of 3 and 0.7, respectively. The degradation rate was strongly dependent on the initial concentration of Fe2+ or Fe3+, the initial concentration of H2O2 and initial pH. Maximum degradation rate was achieved at optimum concentrations of Fe and H2O2 as well as solution pH. The reaction temperature (15–45 °C) had little effect on overall dye oxidation rate in the Fenton-like reaction.
AU  - Wang, Shaobin
DA  - 2008
DO  - 10.1016/j.dyepig.2007.01.012
DP  - ScienceDirect
J2  - Dyes and Pigments
KW  - Azo dye
Fenton reagent
Kinetics
Wet peroxide oxidation
L1  - files/630/Wang - 2008 - A Comparative study of Fenton and Fenton-like reac.pdf
M1  - 3
PY  - 2008
SN  - 0143-7208
SP  - 714-720
ST  - A Comparative study of Fenton and Fenton-like reaction kinetics in decolourisation of wastewater
T2  - Dyes and Pigments
TI  - A Comparative study of Fenton and Fenton-like reaction kinetics in decolourisation of wastewater
UR  - http://www.sciencedirect.com/science/article/pii/S0143720807000216
files/629/S0143720807000216.html
VL  - 76
Y2  - 2013/01/15/14:25:50
ID  - 173
ER  - 


TY  - JOUR
AB  - The decomposition of polycyclic aromatic hydrocarbons in a creosote oily solution and in synthetic solutions containing naphthalene and pyrene was investigated in the presence of an amphoteric surfactant using electrooxidation by comparison to Fenton oxidation process. Electrolysis was carried out using a parallelepipedic electrolytic 1.5-L cell containing five anodes (expanded titanium covered with ruthenium) and five cathodes (stainless steel) alternated in the electrode pack, whereas Fenton oxidation process was carried out in 500 mL Erlenmeyer glass-flasks in which H2O2 and Fe2+ were added. Using electrochemical oxidation, the sum concentration of 16 polycyclic aromatic hydrocarbons investigated could be optimally diminished by up to 80–82% by applying a current density of 9.23 mA cm−2 and a pH of 4.0 or 7.0 for 90-min reaction period. By comparison, the best yield (46%) of Fenton oxidation process for polycyclic aromatic hydrocarbons degradation was recorded by using H2O2/Fe2+ molar ratio of 11.0 and a pH of 4.0.
AU  - Tran, Lan-Huong
AU  - Drogui, Patrick
AU  - Mercier, Guy
AU  - Blais, Jean-François
DA  - 2010/08/01/
DO  - 10.1007/s10800-010-0128-4
DP  - link.springer.com
J2  - J Appl Electrochem
KW  - Electrochemical degradation
Electrochemistry
Fenton oxidation
Hydroxyl radical
Industrial Chemistry/Chemical Engineering
Physical Chemistry
Polycyclic aromatic hydrocarbon
Ruthenium oxide electrode
Surfactant
L1  - files/306/Tran et al. - 2010 - Comparison between Fenton oxidation process and el.pdf
LA  - en
M1  - 8
PY  - 2010
SN  - 0021-891X, 1572-8838
SP  - 1493-1510
ST  - Comparison between Fenton oxidation process and electrochemical oxidation for PAH removal from an amphoteric surfactant solution
T2  - Journal of Applied Electrochemistry
TI  - Comparison between Fenton oxidation process and electrochemical oxidation for PAH removal from an amphoteric surfactant solution
UR  - http://link.springer.com/article/10.1007/s10800-010-0128-4
files/307/s10800-010-0128-4.html
VL  - 40
Y2  - 2013/01/15/04:19:41
ID  - 325
ER  - 


TY  - JOUR
AB  - The study was undertaken to compare from technical and economic point of view the treatment of antibiotic aqueous solution containing amoxicillin, ampicillin, and cloxacillin by Fenton, photo-Fenton, TiO2 photocatalytic and UV/ZnO processes. The best operating conditions for treatment of antibiotic aqueous solution containing 104, 105 and 103 mg/L of amoxicillin, ampicillin, and cloxacillin, respectively were: Fenton process — COD/H2O2/Fe2+ molar ratio 1:3:0.30 and pH 3; photo-Fenton process — COD/H2O2/Fe2+ molar ratio 1:1.5:0.075 and pH 3; UV/TiO2/H2O2 process — TiO2 1 g/L, ambient pH ∼ 5 and H2O2 100 g/L; UV/ZnO process — ZnO 0.5 g/L and pH 11. All studied processes were able to degrade the antibiotics and improve biodegradability (BOD5/COD ratio), except for UV/ZnO process which did not improve biodegradability. Photo-Fenton process exhibited higher rate constant (0.029 min− 1) than that of Fenton process (0.0144 min− 1) and this may be ascribed to photochemical regeneration of Fe2 + ions by photoreduction of Fe3 + ions and hence increasing hydroxyl radical production rate. Rate constants of UV/ZnO process (0.00056 min− 1) and UV/TiO2/H2O2 process (0.0005 min− 1) were lower than that of Fenton and photo-Fenton processes. Photo-Fenton process appeared to be the most cost-effective compared to the other studied processes.
AU  - Elmolla, Emad S.
AU  - Chaudhuri, Malay
DA  - 2010/06//
DO  - 10.1016/j.desal.2010.02.019
DP  - ScienceDirect
J2  - Desalination
KW  - Amoxicillin
Ampicillin
Antibiotics
Cloxacillin
Comparison
Fenton
Photo-Fenton
TiO2 photocatalysis
UV/ZnO process
L1  - files/507/Elmolla and Chaudhuri - 2010 - Comparison of different advanced oxidation process.pdf
M1  - 1–3
PY  - 2010
SN  - 0011-9164
SP  - 43-47
ST  - Comparison of different advanced oxidation processes for treatment of antibiotic aqueous solution
T2  - Desalination
TI  - Comparison of different advanced oxidation processes for treatment of antibiotic aqueous solution
UR  - http://www.sciencedirect.com/science/article/pii/S0011916410000962
files/506/S0011916410000962.html
VL  - 256
Y2  - 2013/01/15/09:35:17
ID  - 193
ER  - 


TY  - JOUR
AB  - In this paper, a comparison of various advanced oxidation processes (O3, O3/UV, H2O2/UV, O3/H2O2/UV, Fe2+/H2O2) and chemical treatment methods using Al2(SO4)3 · 18H2O, FeCl3 and FeSO4 for the chemical oxygen demand (COD) and color removal from a polyester and acetate fiber dyeing effluent is undertaken. Advanced oxidation processes (AOPs) showed a superior performance compared to conventional chemical treatment, which maximum achievable color and COD removal for the textile effluent used in this study was 50% and 60%, respectively. Although O3/H2O2/UV combination among other AOPs methods studied in this paper was found to give the best result (99% removal for COD and 96% removal for color), use of Fe2+/H2O2 seems to show a satisfactory COD and color removal performance and to be economically more viable choice for the acetate and polyester fiber dyeing effluent on the basis of 90% removal.
AU  - Azbar, N.
AU  - Yonar, T.
AU  - Kestioglu, K.
DA  - 2004/04//
DO  - 10.1016/j.chemosphere.2003.10.046
DP  - ScienceDirect
J2  - Chemosphere
KW  - Advanced oxidation
Fenton’s reagent
Ozone
Textile dyeing
UV radiation
L1  - files/93/Azbar et al. - 2004 - Comparison of various advanced oxidation processes.pdf
M1  - 1
PY  - 2004
SN  - 0045-6535
SP  - 35-43
ST  - Comparison of various advanced oxidation processes and chemical treatment methods for COD and color removal from a polyester and acetate fiber dyeing effluent
T2  - Chemosphere
TI  - Comparison of various advanced oxidation processes and chemical treatment methods for COD and color removal from a polyester and acetate fiber dyeing effluent
UR  - http://www.sciencedirect.com/science/article/pii/S0045653503010609
files/92/S0045653503010609.html
VL  - 55
Y2  - 2013/01/14/03:16:48
ID  - 194
ER  - 


TY  - JOUR
AB  - Soil contamination by persistent organic pollutants (POPs) is a problem faced in many countries as a result of rapid industrialisation. The suitability of Fenton oxidation for degradation of recalcitrant POPs as a short-term remediation approach has led to intense research within the field over the last few decades. In this review article, the fundamental principles and governing factors of Fenton oxidation for treating soils contaminated with POPs such as polycyclic aromatic hydrocarbons (PAHs), polychlorinated biphenyls (PCBs), polychlorinated dibenzo-p-dioxins and furans (PCDD/Fs), are firstly discussed. Current practices of soil remediation through Fenton oxidation based on studies reported in the specialised literature are then reviewed with a focus on the potential of Fenton-bioremediation and electrokinetic (EK)-Fenton treatments in conjunction with in situ applications. An exhaustive bibliography on column studies is also covered in this work with emphasis on the technical approaches used. Finally, the last section of the article is focused on assisting soil scientists and environmental professionals in implementing in situ Fenton oxidation (ISFO) and provides some insights into future development of ISFO.
AU  - Venny
AU  - Gan, Suyin
AU  - Ng, Hoon Kiat
DA  - 2012/12/01/
DO  - 10.1016/j.cej.2012.10.005
DP  - ScienceDirect
J2  - Chemical Engineering Journal
KW  - Bioremediation
Column
Electrokinetic
Fenton
In situ
POP
L1  - files/585/Venny et al. - 2012 - Current status and prospects of Fenton oxidation f.pdf
M1  - 0
PY  - 2012
SN  - 1385-8947
SP  - 295-317
ST  - Current status and prospects of Fenton oxidation for the decontamination of persistent organic pollutants (POPs) in soils
T2  - Chemical Engineering Journal
TI  - Current status and prospects of Fenton oxidation for the decontamination of persistent organic pollutants (POPs) in soils
UR  - http://www.sciencedirect.com/science/article/pii/S1385894712013290
files/584/S1385894712013290.html
VL  - 213
Y2  - 2013/01/15/13:49:47
ID  - 195
ER  - 


TY  - CHAP
A2  - Hauser, Peter
AU  - Yonar, Taner
DP  - CrossRef
L1  - files/418/InTech-Decolorisation_of_textile_dyeing_effluents_using_advanced_oxidation_processes.pdf
PB  - InTech
PY  - 2011
SN  - 978-953-307-704-8
ST  - Decolorisation of Textile Dyeing Effluents Using Advanced Oxidation Processes
T2  - Advances in Treating Textile Effluent
TI  - Decolorisation of Textile Dyeing Effluents Using Advanced Oxidation Processes
UR  - http://www.intechopen.com/books/advances-in-treating-textile-effluent/decolorisation-of-textile-dyeing-effluents-using-advanced-oxidation-processes
files/255/decolorisation-of-textile-dyeing-effluents-using-advanced-oxidation-processes.html
Y2  - 2013/01/14/10:16:15
ID  - 298
ER  - 


TY  - JOUR
AU  - Daud, N. K.
AU  - Akpan, U. G.
AU  - Hameed, B. H.
DA  - 2012/01//
DO  - 10.1080/19443994.2012.661246
DP  - CrossRef
L1  - files/443/19443994.2012.661246.pdf
M1  - 1-3
PY  - 2012
SN  - 1944-3994, 1944-3986
SP  - 1-7
ST  - Decolorization of Sunzol Black DN conc. in aqueous solution by Fenton oxidation process
T2  - Desalination and Water Treatment
TI  - Decolorization of Sunzol Black DN conc. in aqueous solution by Fenton oxidation process: effect of system parameters and kinetic study
UR  - http://login.oaresciences.org/whalecomwww.tandfonline.com/whalecom0/doi/abs/10.1080/19443994.2012.661246
files/397/19443994.2012.html
VL  - 37
Y2  - 2013/01/15/06:05:13
ID  - 314
ER  - 


TY  - JOUR
AB  - The oxidative decolorization of Reactive Black 5 (RB5) in aqueous solution has been studied using Fenton (H2O2/Fe2+) and photo-Fenton (H2O2/Fe2+/UV) processes. This investigation reveals that both methods can remove the color of RB5. Batch experiments were carried out to investigate the process's optimal operational conditions: pH, H2O2 dosage, Fe2+ dosage, RB5 concentration and optimal [Fe2+]0/[H2O2]0/[RB5]0 ratio, to obtain the bests results at low cost, render AOP competitive with other processes. The optimal conditions found were a ratio [H2O2]0/[RB5]0 of 4.9:1, a ratio [H2O2]0/[Fe2+]0 of 9.6:1 and pH = 3.0. The decolorization experiments indicate that RB5 can be effectively decolorized using Fenton and photo-Fenton processes with a little difference between the two processes, 97.5% and 98.1%, respectively, for optimal conditions. This small difference in dye decolorization is not similar to TOC removal: with photo-Fenton process there is a significant increment (46.4% TOC removal) relatively to Fenton process (only 21.6% TOC removal). This fact indicates that although UV low-pressure mercury lamp has little effect on dye decolorization it is particularly important in dye mineralization.
AU  - Lucas, Marco S.
AU  - Peres, José A.
DA  - 2006
DO  - 10.1016/j.dyepig.2005.07.007
DP  - ScienceDirect
J2  - Dyes and Pigments
KW  - Advanced Oxidation Processes (AOP's)
Azo dye
Fenton process
Photo-Fenton process
Reactive Black 5
Textile wastewater
L1  - files/459/Lucas and Peres - 2006 - Decolorization of the azo dye Reactive Black 5 by .pdf
M1  - 3
PY  - 2006
SN  - 0143-7208
SP  - 236-244
ST  - Decolorization of the azo dye Reactive Black 5 by Fenton and photo-Fenton oxidation
T2  - Dyes and Pigments
TI  - Decolorization of the azo dye Reactive Black 5 by Fenton and photo-Fenton oxidation
UR  - http://www.sciencedirect.com/science/article/pii/S0143720805002378
files/458/S0143720805002378.html
VL  - 71
Y2  - 2013/01/15/08:57:47
ID  - 196
ER  - 


TY  - JOUR
AB  - Background Olive mill wastewater (OMW) generated by the olive oil extracting industry is a major pollutant, because of its high organic load and phytotoxic and antibacterial phenolic compounds which resist biological degradation. Mediterranean countries are mostly affected by this serious environmental problem since they are responsible for 95% of the worldwide oliveoil production. There are many methods used for OMW treatment, such as adsorption, electro coagulation, electro-oxidation, biological degradation, advanced oxidation processes (AOPs), chemical coagulation, flocculation, filtration, lagoons of evaporation and burning systems, etc. Currently, there is no such economical and easy solution. The aim of this study was to evaluate the feasibility of decolourization and removal of phenol, lignin, TOC and TIC in OMW by UV/H2O2 (AOPs). The operating parameters, such as hydrogen peroxide dosage, times, pH, effect of UV and natural sunlight were determined to find the suitable operating conditions for the best removal. Moreover, there is no study reported in the literature related to the use of UV/H2O2 and lime together in OMW treatment. Methods OMW was obtained from an olive-oil producing plant (Muğla area of Turkey) which uses a modern production process. No chemical additives are used during olive oil production. This study was realised by using two different UV sources, while taking the time and energy consumption into consideration. These two sources were mercury lamps and natural sunlight. Before starting AOPs experiments, one litre of OMW was treated by adding lime until a pH of 7.00. Then, 100 ml was taken from each sample, and 1 to 10 ml of a 30% H2O2 (Riedel-deHaen) solution was added. These solutions in closed vessels were laid in the natural sunlight for a week and their compositions and colour changes were analysed daily by UV-Vis spectrophotometer. At the end of the one-week period, they were treated with lime. In this study, the effect of changes in the initial pH, times and H2O2 concentrations on removal was investigated. At the end of all experiments, changes in colour, phenol, lignin, TOC and TIC concentrations were analysed according to standard methods. Results and Discussion In the samples exposed to natural sunlight and having an H2O2/OMW ratio of 3 ml/100 ml, a significant colour removal was achieved approximately 90% of the time at the end of 7 days. When the same samples were treated with lime (pH: up to 7), 99% efficiency was achieved. When phenol and lignin removals were examined in the same concentration, phenol and lignin removal were found 99.5%, 35%, respectively. However, for maximum lignin removal, more use of H2O2 (10 ml H2O2/100 ml OMW) was found to be necessary. Under these conditions, it was found that lignin can be removed by 70%, but to 90% with lime, at the end of a seven-day period. Rate constants obtained in the experiments performed with direct UV were found to be much higher than those of the samples exposed to natural sunlight (ka lignin = 0.3883 ≫ kb lignin = 0.0078; ka phenol = 0.5187 ≫ kb phenol = 0.0146). Moreover, it should be remembered in this process that energy consumption may induce extra financial burden for organisations. Conclusions It was found, in general, that colour, lignin, total organic carbon and phenol were removed more efficiently from OMW by using H2O2 UV and lime OMW. Moreover, in the study, lime was found to contribute, both initially and after radical reactions, to the efficiency to a great extent. Recommendations and Perspectives Another result obtained from the study is that pre-purification carried out with hydrogen peroxide and lime may constitute an important step for further purification processes such as adsorption, membrane processes, etc.
AU  - Uğurlu, Mehmet
AU  - Kula, İbrahim
DA  - 2007/07/01/
DO  - 10.1065/espr2006.06.315
DP  - link.springer.com
J2  - Env Sci Poll Res Int
KW  - Advanced oxidation processes (AOPs)
Atmospheric Protection/Air Quality Control/Air Pollution
colour
Environment, general
Industrial Pollution Prevention
lignin
lime treatment
olive mill wastewater (OMW)
phenols
total inorganic carbon (TIC)
total organic carbon (TOC)
Waste Water Technology / Water Pollution Control / Water Management / Aquatic Pollution
L1  - files/291/Uğurlu and Kula - 2007 - Decolourization and removal of some organic compou.pdf
LA  - en
M1  - 5
PY  - 2007
SN  - 0944-1344, 1614-7499
SP  - 319-325
ST  - Decolourization and removal of some organic compounds from olive mill wastewater by advanced oxidation processes and lime treatment
T2  - Environmental Science and Pollution Research - International
TI  - Decolourization and removal of some organic compounds from olive mill wastewater by advanced oxidation processes and lime treatment
UR  - http://link.springer.com/article/10.1065/espr2006.06.315
files/292/espr2006.06.html
VL  - 14
Y2  - 2013/01/15/04:02:29
ID  - 326
ER  - 


TY  - JOUR
AB  - Water pollution control is presently one of the major thrust areas of scientific research. While coloured organic compounds generally impart only a minor fraction of the organic load to wastewaters, their colour renders them aesthetically unacceptable. Stringent regulating measures are coaxing industries to treat their waste effluents to increasingly high standards. Colour removal, in particular, has recently become an area of major scientific interest as indicated by the multitude of related research reports. During the past two decades, several decolourization techniques have been reported, few of which have been accepted by some industries. There is a need to find alternative treatments that are effective in removing dyes and colourants from large volume of effluents, which are cost-effective, like the biological or integrated systems. This article reviews some of the widely used and most promising industrial wastewater decolourization methods. Data on decolourizing efficiencies of different causative agents, obtained by means of different physical, chemical and biological methods are discussed. Further a critical review is made on the various treatment methodologies and emerging technologies with a note on their advantages and disadvantages.
AU  - Anjaneyulu, Y.
AU  - Chary, N. Sreedhara
AU  - Raj, D. Samuel Suman
DA  - 2005/11/01/
DO  - 10.1007/s11157-005-1246-z
DP  - link.springer.com
J2  - Rev Environ Sci Biotechnol
KW  - Atmospheric Protection/Air Quality Control/Air Pollution
colourants
Decolourization
dyes and pigments
effluents
emerging technology
Environmental Biotechnology
low cost
Microbiology
organic compounds
L1  - files/303/Anjaneyulu et al. - 2005 - Decolourization of Industrial Effluents – Availabl.pdf
LA  - en
M1  - 4
PY  - 2005
SN  - 1569-1705, 1572-9826
SP  - 245-273
ST  - Decolourization of Industrial Effluents – Available Methods and Emerging Technologies – A Review
T2  - Reviews in Environmental Science and Bio/Technology
TI  - Decolourization of Industrial Effluents – Available Methods and Emerging Technologies – A Review
UR  - http://link.springer.com/article/10.1007/s11157-005-1246-z
files/304/s11157-005-1246-z.html
VL  - 4
Y2  - 2013/01/15/04:17:23
ID  - 327
ER  - 


TY  - JOUR
AB  - Abstract For 50 years, farmers around the world have relied on the herbicide atrazine—one of the triazine family of herbicides—to fight weeds in corn, grain sorghum, sugar cane, and other crops. Although prohibited in the European Union because of widespread contamination of waterways and drinking water supplies, it is still one of the most widely used herbicides in the world. Atrazine and some of its degradation products are among the most commonly found xenobiotics in groundwater and soils in the world. It is also an endocrine disruptor that causes abnormal reproductive development and immune suppression in wildlife. The purpose of this study was to identify the degradation products of atrazine. Fenton reaction treatment, a hydroxyl radical oxidation process recently developed for the degradation of aqueous pesticide waste, was applied to the degradation of atrazine. Classical and modified Fenton reactions have been used as Advanced Oxidation Process treatment methods. A HPLC method was developed and optimized for the identification of resulting degradation products. In general, very good atrazine degradation efficiencies were achieved by both of the methods used. The degradation products, such as oxalic acid, urea, formic acid, acetic acid, and acetone, were identified by HPLC with a photodiode array detector. Graphical abstract
AU  - Mackul’ak, Tomáš
AU  - Prousek, Josef
AU  - Švorc, L’ubomír
DA  - 2011/06/01/
DO  - 10.1007/s00706-011-0504-8
DP  - link.springer.com
J2  - Monatsh Chem
KW  - Analytical Chemistry
Atrazine
Chemistry/Food Science, general
Degradation
Fenton reaction
Herbicide
HPLC
Inorganic Chemistry
Organic Chemistry
Physical Chemistry
Theoretical and Computational Chemistry
L1  - files/276/Mackul’ak et al. - 2011 - Degradation of atrazine by Fenton and modified Fen.pdf
LA  - en
M1  - 6
PY  - 2011
SN  - 0026-9247, 1434-4475
SP  - 561-567
ST  - Degradation of atrazine by Fenton and modified Fenton reactions
T2  - Monatshefte für Chemie - Chemical Monthly
TI  - Degradation of atrazine by Fenton and modified Fenton reactions
UR  - http://link.springer.com/article/10.1007/s00706-011-0504-8
files/277/s00706-011-0504-8.html
VL  - 142
Y2  - 2013/01/15/03:58:27
ID  - 328
ER  - 


TY  - JOUR
AB  - This article presents an overview with critical analysis of technical applicability of advanced oxidation process (AOP) in removing chelating agents from aqueous solution. Apart from the effect of metals for chelating agents as a major influencing factor, selected information such as pH, oxidant’s dose, concentrations of pollutants and treatment performance is presented. The performance of individual AOP is compared. It is evident from our literature survey that photocatalysis with UV irradiation alone or coupled with TiO2, ozonation and Fenton’s oxidation are frequently applied to mineralize target pollutants. Overall, the selection of the most suitable AOP depends on the characteristics of effluents, technical applicability, discharge standard, regulatory requirements and environmental impacts.
AU  - Sillanpää, Mika E. T.
AU  - Agustiono Kurniawan, Tonni
AU  - Lo, Wai-hung
DA  - 2011/06//
DO  - 10.1016/j.chemosphere.2011.01.007
DP  - ScienceDirect
J2  - Chemosphere
KW  - Complexing agents
EDTA
NTA
Phosphonate
Photocatalytic oxidation (PCO)
Wastewater treatment
L1  - files/660/Sillanpää et al. - 2011 - Degradation of chelating agents in aqueous solutio.pdf
M1  - 11
PY  - 2011
SN  - 0045-6535
SP  - 1443-1460
ST  - Degradation of chelating agents in aqueous solution using advanced oxidation process (AOP)
T2  - Chemosphere
TI  - Degradation of chelating agents in aqueous solution using advanced oxidation process (AOP)
UR  - http://www.sciencedirect.com/science/article/pii/S0045653511000099
files/659/S0045653511000099.html
VL  - 83
Y2  - 2013/01/15/14:46:36
ID  - 197
ER  - 


TY  - JOUR
AB  - Waste effluents from textile industries are a major source of water pollution. These waste streams contain numerous toxic dyes, which are resistant to natural breakdown and degradation. Therefore, there is a need to find economical and bio-friendly methods to degrade textile dyes. In this study, degradation of Methyl Red, an azo dye, was studied using the ferrous-hydrogen peroxide system. The oxidation and subsequent degradation of the dye was found to be dependent on both the amount of Fe2+ ions as well as hydrogen peroxide. In order to study the effect of other salts that are normally present in textile waste streams, a systematic study was carried out using 10 different salt solutions. Some of the ions tested enhanced the rate and extent of degradation of the dye, whereas some had an inhibitory effect. The rates of degradation were found to fit to first-order kinetics.
AU  - Ashraf, S. Salman
AU  - Rauf, Muhammad A.
AU  - Alhadrami, Seham
DA  - 2006
DO  - 10.1016/j.dyepig.2005.02.009
DP  - ScienceDirect
J2  - Dyes and Pigments
KW  - Decolourization
Dye degradation
Fenton’s reagent
Hydrogen peroxide
Methyl Red
Textile waste
L1  - files/271/Ashraf et al. - 2006 - Degradation of Methyl Red using Fenton's reagent a.pdf
M1  - 1–2
PY  - 2006
SN  - 0143-7208
SP  - 74-78
ST  - Degradation of Methyl Red using Fenton's reagent and the effect of various salts
T2  - Dyes and Pigments
TI  - Degradation of Methyl Red using Fenton's reagent and the effect of various salts
UR  - http://www.sciencedirect.com/science/article/pii/S0143720805001075
files/270/S0143720805001075.html
VL  - 69
Y2  - 2013/01/15/03:52:38
ID  - 198
ER  - 


TY  - JOUR
AB  - Alkanolamines in the wastewater from gas treating plants are not readily biodegradable. In this work, we have investigated the effectiveness of the Fenton’s reagent (H2O2-Fe2+) to treat monoethanolamine (MEA) as a model compound in simulated wastewater. Degradation studies were carried out in a jacketed glass reactor. The effects of concentrations of ferrous sulfate, hydrogen peroxide, and the pH of a solution on the rate of reaction were determined. A pH of 3 was found to be the optimum. The degradation reaction proceeds very fast at the beginning but slows down significantly at a longer time. A larger fractional degradation of the organics in solution was observed if the initial chemical oxygen demand (COD) of the feed solution was high. Gradual addition of H2O2 to the reaction mixture increased the COD removal by about 60% compared to one-time addition of the reagent at the beginning of the process. A rate equation for mineralization of the amine was developed on the basis of a simplified mechanistic model, and the lumped value of the rate constant for COD removal was determined. A partially degraded MEA solution as well as “pure” MEA was subjected to biological oxidation by activated sludge. The former substrate degraded much faster. The degradation rate and biomass generation data could be fitted by the Monod kinetic equations.
AU  - Harimurti, Sabtanti
AU  - Dutta, Binay K.
AU  - Ariff, Idzham Fauzi B. M.
AU  - Chakrabarti, Sampa
AU  - Vione, Davide
DA  - 2010/09/01/
DO  - 10.1007/s11270-009-0298-z
DP  - link.springer.com
J2  - Water Air Soil Pollut
KW  - Advanced oxidation
Atmospheric Protection/Air Quality Control/Air Pollution
Biological oxidation
Climate Change
Environment, general
Fenton’s reagent
Hydrogeology
Monoethanolamine
Soil Science & Conservation
Waste Water Technology / Water Pollution Control / Water Management / Aquatic Pollution
L1  - files/279/Harimurti et al. - 2010 - Degradation of Monoethanolamine in Aqueous Solutio.pdf
LA  - en
M1  - 1-4
PY  - 2010
SN  - 0049-6979, 1573-2932
SP  - 273-286
ST  - Degradation of Monoethanolamine in Aqueous Solution by Fenton’s Reagent with Biological Post-treatment
T2  - Water, Air, & Soil Pollution
TI  - Degradation of Monoethanolamine in Aqueous Solution by Fenton’s Reagent with Biological Post-treatment
UR  - http://link.springer.com/article/10.1007/s11270-009-0298-z
files/280/s11270-009-0298-z.html
VL  - 211
Y2  - 2013/01/15/03:58:27
ID  - 329
ER  - 


TY  - JOUR
AB  - The degradation of organic matter present in olive-oil mill wastewater from two-phase olive-oil extraction process was carried out by chemical oxidation reaction. It was shown that organic matter is efficiently degraded through a Fenton-like reaction using FeCl3 as catalyst in the presence of hydrogen peroxide. Oxidation was carried out in a batch reactor with controlled temperature. Operating at pH 3.0, H2O2 concentration = 100 g dm−3, [FeCl3]/[H2O2] ratio = 0.04, and ambient temperature (281–285 K), 92.6% of chemical oxygen demand and 99.8% of total phenols were removed. Kinetics can be described by a two step first order model. The kinetic parameters at ambient temperature and pH 3 were calculated. In the temperature range 278–313 K, the best performance was obtained at 303 K. The experiments performed at different temperatures allowed to calculate the apparent activation energy Ea = 8.7 kJ mol−1.
AU  - Nieto, Leopoldo Martínez
AU  - Hodaifa, Gassan
AU  - Rodríguez, Salvador
AU  - Giménez, José A.
AU  - Ochando, Javier
DA  - 2011/09/15/
DO  - 10.1016/j.cej.2011.08.022
DP  - ScienceDirect
J2  - Chemical Engineering Journal
KW  - COD
Fenton's reagent
Kinetics study
Olive-oil mill wastewater
Oxidation
Phenols compounds
L1  - files/594/Nieto et al. - 2011 - Degradation of organic matter in olive-oil mill wa.pdf
M1  - 2
PY  - 2011
SN  - 1385-8947
SP  - 503-510
ST  - Degradation of organic matter in olive-oil mill wastewater through homogeneous Fenton-like reaction
T2  - Chemical Engineering Journal
TI  - Degradation of organic matter in olive-oil mill wastewater through homogeneous Fenton-like reaction
UR  - http://www.sciencedirect.com/science/article/pii/S1385894711009508
files/593/S1385894711009508.html
VL  - 173
Y2  - 2013/01/15/13:53:19
ID  - 199
ER  - 


TY  - JOUR
AB  - Background, aim, and scope The optimal conditions of o-toluidine degradation by fluidized-bed Fenton process were determined using Box–Behnken designs (BBD). The BBD can be used to find the optimal conditions in multivariable systems. The optimal conditions obtained by the design were further applied in the kinetic analysis of o-toluidine oxidation in fluidized-bed Fenton process. Materials and methods The 1.35-L fluidized-bed reactor used in all experiments was a cylindrical vessel with an inlet, outlet, and recirculation pump. The o-toluidine was determined by high-performance liquid chromatography. Results and discussion Analytical results indicated that pH, Fe2+, and H2O2 were significant factors in o-toluidine and chemical oxygen demand (COD) removal, but loading carrier was not. The pH significantly affected not only o-toluidine degradation, but also total iron removal. The predicted conditions for optimal removal of 1 mM of o-toluidine using 100 g of carriers were pH 3 ± 0.5, 1 mM of Fe2+, and 17 mM of H2O2. Removal of o-toluidine and COD in the actual experiment was higher than predicted, whereas removal of total iron was slightly lower. The kinetic study showed that the initial rate and rate constant (k) of o-toluidine degradation in the fluidized-bed Fenton process correlated Fe2+ concentration. In the Fe2+/H2O2 stage, high concentration of H2O2 produced a scavenging effect. Conclusions The predicted removal efficiencies of o-toluidine and COD were 90.2% and 41.4%, respectively. Moreover, the removals of o-toluidine and COD in the actual experiment were 99.8% and 61.8%, respectively.
AU  - Anotai, Jin
AU  - Thuptimdang, Pumis
AU  - Su, Chia-Chi
AU  - Lu, Ming-Chun
DA  - 2012/01/01/
DO  - 10.1007/s11356-011-0553-x
DP  - link.springer.com
J2  - Environ Sci Pollut Res
KW  - Advanced oxidation process
Atmospheric Protection/Air Quality Control/Air Pollution
Box–Behnken design
Degradation
Environment, general
Fluidized-bed Fenton
Industrial Pollution Prevention
Kinetics
o-Toluidine
Waste Water Technology / Water Pollution Control / Water Management / Aquatic Pollution
L1  - files/371/Anotai et al. - 2012 - Degradation of o-toluidine by fluidized-bed Fenton.pdf
LA  - en
M1  - 1
PY  - 2012
SN  - 0944-1344, 1614-7499
SP  - 169-176
ST  - Degradation of o-toluidine by fluidized-bed Fenton process
T2  - Environmental Science and Pollution Research
TI  - Degradation of o-toluidine by fluidized-bed Fenton process: statistical and kinetic study
UR  - http://link.springer.com/article/10.1007/s11356-011-0553-x
files/372/s11356-011-0553-x.html
VL  - 19
Y2  - 2013/01/15/05:22:45
ID  - 330
ER  - 


TY  - JOUR
AB  - The potential of the Fenton’s reagent for oxidation of p-aminophenols, which are the main developers used in white and black processes, was assessed. Metol [N-methyl-p-aminophenol] was chosen as a model. Degradation of this compound by Fenton’s reagent was examined under dark conditions as a function of reagent concentrations and pH used in batch treatments. Under optimal conditions, 0.2 M H2O2, 9.0×10−4 M Fe2+, pH 3–5 and room temperature, the initial COD of a 5×10−3 M metol solution was reduced by about 50% within 2 h. After this time, additional COD reduction was very slow (about 20% in five days). No aromatic compounds were detected about 4 h of reaction indicating that residual organic matter was mainly made up of ring cleavage products. Metol conversion behaved as a first-order reaction with respect to metol and Fe2+. Complete destruction of residual organic matter could be achieved at high temperatures (about 60°C) or by using the photo-Fenton reaction, which thus opens up prospects for an effective treatment of p-aminophenols in effluents from photographic processes.
AU  - Lunar, Loreto
AU  - Sicilia, Dolores
AU  - Rubio, Soledad
AU  - Pérez-Bendito, Dolores
AU  - Nickel, Ulrich
DA  - 2000/04/01/
DO  - 10.1016/s0043-1354(99)00339-5
DP  - ScienceDirect
J2  - Water Research
KW  - chemical degradation
Fenton’s reagent
p-aminophenols
photo-Fenton reaction
photographic developers
L1  - files/600/Lunar et al. - 2000 - Degradation of photographic developers by Fenton’s.pdf
M1  - 6
PY  - 2000
SN  - 0043-1354
SP  - 1791-1802
ST  - Degradation of photographic developers by Fenton’s reagent
T2  - Water Research
TI  - Degradation of photographic developers by Fenton’s reagent: condition optimization and kinetics for metol oxidation
UR  - http://www.sciencedirect.com/science/article/pii/S0043135499003395
files/599/S0043135499003395.html
VL  - 34
Y2  - 2013/01/15/14:04:53
ID  - 200
ER  - 


TY  - JOUR
AB  - Propylene glycol (PG) wastewater seriously threatens aquatic lives and causes health damage to human beings. Several early studies for PG degradation focused on biological process, which usually proceeds at a slow rate and is often inhibited by substances which are toxic to the microorganisms. In this paper, Fenton method was exploited for treating PG wastewater in a semi-continuous reactor with adding ferrous sulfate (FeSO4) and hydrogen peroxide (H2O2) to the reactor, respectively. Semi-continuous applications of H2O2 and Fe2+ could result in low steady state of HO, which would minimize HO scavenging and further increase PG oxidation efficiency. Under the optimal conditions, 99.1% of PG conversion and 88.4% of COD removal were achieved. In addition, pseudo-first-order model, in which the concentration of HO was assumed to remain constant, was established. The intrinsic activation energy of HO with PG, calculated by Arrhenius-equation was 35.18 kJ/mol. The intrinsic reaction rate constant of HO with PG around optimal conditions was 1.56–1.72 × 108 M−1 s−1. After Fenton's reaction, PG molecules could not be thoroughly oxidized to H2O and CO2. Intermediates, such as aldehyde, acetone, methanol, formic acid, and acetic acid, were checked by GC–MS, which all had a very low content and toxicity. As a homogeneous catalytic oxidation, Fenton oxidation is a feasible treatment for PG wastewater for its low toxicity, low price, and high efficiency.
AU  - Wang, Hao-Yi
AU  - Hu, Yu-Na
AU  - Cao, Gui-Ping
AU  - Yuan, Wei-Kang
DA  - 2011/05/15/
DO  - 10.1016/j.cej.2011.03.030
DP  - ScienceDirect
J2  - Chemical Engineering Journal
KW  - Fenton's reagent
Kinetics
Propylene glycol
Semi-continuous reactor
L1  - files/597/Wang et al. - 2011 - Degradation of propylene glycol wastewater by Fent.pdf
M1  - 1
PY  - 2011
SN  - 1385-8947
SP  - 75-81
ST  - Degradation of propylene glycol wastewater by Fenton's reagent in a semi-continuous reactor
T2  - Chemical Engineering Journal
TI  - Degradation of propylene glycol wastewater by Fenton's reagent in a semi-continuous reactor
UR  - http://www.sciencedirect.com/science/article/pii/S1385894711003172
files/596/S1385894711003172.html
VL  - 170
Y2  - 2013/01/15/13:55:27
ID  - 201
ER  - 


TY  - JOUR
AB  - The degradation of salicylic acid (SA) was carried out utilizing classical Fenton reagents and modified Fenton with ferric iron salt and goethite as source of iron catalyst. The efficiency of the treatments was evaluated on the basis of SA degradation degree, COD and BOD reduction. Due to the tendency of SA to form complexes with ferric iron, decreasing the concentration of catalyst and increasing that of hydrogen peroxide intensified SA degradation by the classical Fenton process. Application of Fe3+/H2O2 led to the same SA degradation degree as classical Fenton process with the following termination, where the entire residual SA is complexed with Fe3+. SA degradation by modified Fenton was intensified with higher goethite concentration and in acidic pH conditions. The addition of UV-irradiation did not improve the action of the Fenton's/modified Fenton's reagent system. Overall COD and BOD removal efficiency comprised nearly 90% under optimal treatment conditions applied.
AU  - Goi, A.
AU  - Veressinina, Y.
AU  - Trapido, M.
DA  - 2008/09/15/
DO  - 10.1016/j.cej.2008.01.018
DP  - ScienceDirect
J2  - Chemical Engineering Journal
KW  - COD reduction
Complex formation
Degradation degree
Iron catalyst addition
L1  - files/253/Goi et al. - 2008 - Degradation of salicylic acid by Fenton and modifi.pdf
M1  - 1–3
PY  - 2008
SN  - 1385-8947
SP  - 1-9
ST  - Degradation of salicylic acid by Fenton and modified Fenton treatment
T2  - Chemical Engineering Journal
TI  - Degradation of salicylic acid by Fenton and modified Fenton treatment
UR  - http://www.sciencedirect.com/science/article/pii/S1385894708000302
files/252/S1385894708000302.html
VL  - 143
Y2  - 2013/01/14/10:03:29
ID  - 202
ER  - 


TY  - JOUR
AB  - The present study was used to probe the treatment of simulated wastewater containing cresols by Fenton process. Experiments were conducted in a batch reactor to examine the effects of operating variables like pH, hydrogen peroxide concentration (H2O2) and ferrous ion concentration (Fe2+) on chemical oxygen demand (COD) removal. The progress of the degradation reaction was monitored by the decrease in COD content in the treated solution. The optimal reacting conditions were experimentally determined and it was found to be [H2O2]=31.64 mM, [Fe2+]=0.90 mM for o- and p-cresol while 0.72 mM for m-cresol at pH=3.0±0.2. The degradation efficiency for cresol isomers was as high as 82% within 120 min at optimum conditions. A pseudo-first-order kinetic model was adopted to represent the Fenton oxidation for cresols. The mineralization rate for cresols obeys the following sequence: m-&gt;p-&gt;o-. Maximum degradation occurred at 30 °C for the temperature range of 20–50 °C studied. The global activation energy for the first-order reaction was estimated to be in the range of 12.90–16.25 kJ/mol. Air/nitrogen did not play an active role in completely mineralizing the organic intermediates at the experimental conditions adopted. Irrespective of the position of methyl group in o-, m- or p-position, the maximum dissolved organic carbon (DOC) removal efficiency was 42%. Only 2/5th of cresol was mineralized to CO2 by Fenton process. The results showed that the cresols were completely oxidized and degraded into lower molecular weight aliphatic acids. Among the acids, acetic and oxalic acids were identified as the major products formed during the degradation.
AU  - Kavitha, V.
AU  - Palanivelu, K.
DA  - 2005/08//
DO  - 10.1016/j.watres.2005.05.011
DP  - ScienceDirect
J2  - Water Research
KW  - Acetic acid
Cresols
Fenton's reagent
Mineralization
Oxalic acid
Oxidation
L1  - files/208/Kavitha and Palanivelu - 2005 - Destruction of cresols by Fenton oxidation process.pdf
M1  - 13
PY  - 2005
SN  - 0043-1354
SP  - 3062-3072
ST  - Destruction of cresols by Fenton oxidation process
T2  - Water Research
TI  - Destruction of cresols by Fenton oxidation process
UR  - http://www.sciencedirect.com/science/article/pii/S0043135405002538
files/207/S0043135405002538.html
VL  - 39
Y2  - 2013/01/14/05:21:18
ID  - 203
ER  - 


TY  - JOUR
AB  - This work studied the destruction of various M–EDTA complexes and trace organic pollutants in treated reusable wastewater under advanced oxidation using UV irradiation and ozonation. Effect of dosage of hydrogen peroxide and acidity of reaction matrices on oxidation efficiencies were investigated. The rate constant of mineralization presents a decreasing trend as Fe(III)–EDTA &gt; Fe(II)–EDTA &gt; Al(III)–EDTA &gt; Pb(II)–EDTA &gt; Na(I)–EDTA &gt; Zn(II)–EDTA &gt; Cu(II)–EDTA. The mineralization efficiencies using ozone alone are 15%, 40% and 15% for the water samples after reverse osmosis (RO), microfiltration (MF) and superfiltration (SF) processes, respectively. The presence of hydrogen peroxide in photochemical reaction matrixes can effectively enhance the mineralization of organic carbon species. When 150 mg l−1 of H2O2 was added in the effluents, the mineralization markedly increased to 80%, 92% and 89%, respectively.
AU  - Yang, C.
AU  - Xu, Y. R.
AU  - Teo, K. C.
AU  - Goh, N. K.
AU  - Chia, L. S.
AU  - Xie, R. J.
DA  - 2005/04//
DO  - 10.1016/j.chemosphere.2004.10.020
DP  - ScienceDirect
J2  - Chemosphere
KW  - Advanced oxidation technology
Organic pollutants
Ozone
Ultraviolet
Water
L1  - files/310/Yang et al. - 2005 - Destruction of organic pollutants in reusable wast.pdf
M1  - 3
PY  - 2005
SN  - 0045-6535
SP  - 441-445
ST  - Destruction of organic pollutants in reusable wastewater using advanced oxidation technology
T2  - Chemosphere
TI  - Destruction of organic pollutants in reusable wastewater using advanced oxidation technology
UR  - http://www.sciencedirect.com/science/article/pii/S0045653504009749
files/309/S0045653504009749.html
VL  - 59
Y2  - 2013/01/15/04:23:51
ID  - 204
ER  - 


TY  - JOUR
AB  - The examination of the effectiveness of the chemical oxidation using Fenton's reagent (H2O2/Fe2+) for the reduction of the organic content of wastewater generated from a textile industry has been studied. The experimental results indicate that the oxidation process leads to a reduction in the chemical oxygen demand (COD) concentration up to 45%. Moreover, the reduction is reasonably fast at the first stages of the process, since the COD concentration is decreased up to 45% within four hours and further treatment time does not add up to the overall decrease in the COD concentration (48% reduction within six hours). The maximum color removal achieved was 71.5%. In addition, the alterations observed in the organic matter during the development of the process, as indicated by the ratios of COD/TOC and BOD/COD and the oxidation state, show that a great part of the organic substances, which are not completely mineralized, are subjected to structural changes to intermediate organic by-products.
AU  - Papadopoulos, A. E.
AU  - Fatta, D.
AU  - Loizidou, M.
DA  - 2007/07/31/
DO  - 10.1016/j.jhazmat.2007.04.083
DP  - ScienceDirect
J2  - Journal of Hazardous Materials
KW  - Advanced chemical oxidation
Fenton's reaction
Organic load
Textile wastewater
L1  - files/146/Papadopoulos et al. - 2007 - Development and optimization of dark Fenton oxidat.pdf
M1  - 3
PY  - 2007
SN  - 0304-3894
SP  - 558-563
ST  - Environmental Applications of Advanced Oxidation Processes
T2  - Journal of Hazardous Materials
TI  - Development and optimization of dark Fenton oxidation for the treatment of textile wastewaters with high organic load
UR  - http://www.sciencedirect.com/science/article/pii/S0304389407005444
files/145/S0304389407005444.html
VL  - 146
Y2  - 2013/01/14/04:09:22
ID  - 205
ER  - 


TY  - JOUR
AB  - The study evaluated the effect of Fenton's oxidation on the particle size distribution (PSD) of significant parameters reflecting the organic carbon content of olive oil mill wastewater (OMW). The organic carbon content of the studied OMW was characterized by a COD level of around 40,000 mg/L, with 13,500 mg/L of TOC and 1670 mg/L of total phenols. The corresponding antioxidant activity (AOA) was determined as 33,400 mg/L. PSD of the selected organic carbon parameters was investigated using a sequential filtration/ultrafiltration procedure. COD fractionation based on PSD revealed two major components, a soluble fraction below 2 nm and a particulate fraction above 1600 nm representing 49% and 20% of the total COD, respectively. The remaining COD was distributed in the colloidal and supracolloidal zones. The PSD of TOC, total phenols and AOA exhibited similar profiles with peaks at the two ends of the studied size range. Overall COD removals achieved via Fenton's oxidation both at pH = 3.0 and pH = 4.6 (the original pH of the OMW) remained in the range of 40–50%. As anticipated, the effect of Fenton's treatment was more pronounced in the soluble size range. Fenton's oxidation at pH = 3.0 resulted in 46% and 63% removals for total phenols and AOA, respectively. The results obtained indicated that Fenton's process could only be useful as an alternative preliminary treatment option of the required full treatment scheme that could involve a sequence of filtration, oxidation and/or biological treatment steps.
AU  - Dogruel, S.
AU  - Olmez-Hanci, T.
AU  - Kartal, Z.
AU  - Arslan-Alaton, I.
AU  - Orhon, D.
DA  - 2009/09//
DO  - 10.1016/j.watres.2009.06.017
DP  - ScienceDirect
J2  - Water Research
KW  - Advanced oxidation
Antioxidant activity
Fenton's process
Olive mill wastewater
Organic carbon
Particle size distribution
Total phenols
L1  - files/591/Dogruel et al. - 2009 - Effect of Fenton's oxidation on the particle size .pdf
M1  - 16
PY  - 2009
SN  - 0043-1354
SP  - 3974-3983
ST  - AOPs for Effluent Treatment
T2  - Water Research
TI  - Effect of Fenton's oxidation on the particle size distribution of organic carbon in olive mill wastewater
UR  - http://www.sciencedirect.com/science/article/pii/S0043135409003911
files/590/S0043135409003911.html
VL  - 43
Y2  - 2013/01/15/13:53:19
ID  - 206
ER  - 


TY  - JOUR
AB  - In this study, the electro-Fenton and fluidized-bed Fenton processes under the given conditions were used to oxidize aniline. Factors such as feeding mode and concentration of the hydrogen peroxide were explored. Results showed that the feeding mode of H2O2 did not significantly affect the aniline oxidation in the electro-Fenton process. However, the aniline oxidation slightly decreased with the two-step addition of H2O2 in the fluidized-bed Fenton process. Presumably the decline of remaining Fe2+ led to destitute hydrogen radicals from the Fe2+-catalyzed H2O2. In addition, the removal efficiency of aniline was maintained at a maximum as H2O2 concentration was higher than 0.04 M in the electro-Fenton process. Meanwhile, the almost exhausted H2O2 would increase the amount of Fe2+ in the solution for the electro-Fenton process. This is because the Fe2+ is regenerated through the reduction of Fe3+ on the cathode. The electro-Fenton process has a stronger oxidative ability with regard to the production of the oxalic acid than fluidized-bed Fenton process which was attributed to a higher consumption of H2O2. Therefore, in the aspect of H2O2 depletion, the mineralization efficiency of the fluidized-bed Fenton process was higher than that of the electro-Fenton process.
AU  - Anotai, Jin
AU  - Su, Chia-Chi
AU  - Tsai, Yi-Chun
AU  - Lu, Ming-Chun
DA  - 2010/11/15/
DO  - 10.1016/j.jhazmat.2010.07.112
DP  - ScienceDirect
J2  - Journal of Hazardous Materials
KW  - Aniline
Electro-Fenton process
Fluidized-bed Fenton process
Hydrogen peroxide
L1  - files/185/Anotai et al. - 2010 - Effect of hydrogen peroxide on aniline oxidation b.pdf
M1  - 1–3
PY  - 2010
SN  - 0304-3894
SP  - 888-893
ST  - Effect of hydrogen peroxide on aniline oxidation by electro-Fenton and fluidized-bed Fenton processes
T2  - Journal of Hazardous Materials
TI  - Effect of hydrogen peroxide on aniline oxidation by electro-Fenton and fluidized-bed Fenton processes
UR  - http://www.sciencedirect.com/science/article/pii/S0304389410010083
files/184/S0304389410010083.html
VL  - 183
Y2  - 2013/01/14/04:51:18
ID  - 207
ER  - 


TY  - JOUR
AB  - This study investigated the treatment of textile industrial wastewater from a dyeing and finishing mill by the fluidized-bed Fenton process. Operating variables, such as the pH, concentrations of H2O2 and Fe2+, are used to explore the respective effects on the oxidation and decolorization of the textile wastewater. The experimental results were estimated in terms of chemical oxygen demand (COD) and color reductions to examine the treatment efficiency. The optimum pH was observed to be around 3. The decolorization and the oxidation efficiencies could achieve 92% and 49%, respectively, in only 2 min of reaction under the concentration ratio of [COD]:[Fe2+]:[H2O2] = 1:0.95:3.17. By using this process, the oxidation of textile wastewater increased with increasing H2O2 dosage. The highest level of oxidation was 87%.
AU  - Su, Chia-Chi
AU  - Pukdee-Asa, Massakul
AU  - Ratanatamskul, Chavalit
AU  - Lu, Ming-Chun
DA  - 2011/11/15/
DO  - 10.1016/j.seppur.2011.09.021
DP  - ScienceDirect
J2  - Separation and Purification Technology
KW  - Decolorization
Fluidized-bed Fenton
Hydrogen peroxide
Oxidation
Textile wastewater
L1  - files/119/Su et al. - 2011 - Effect of operating parameters on the decolorizati.pdf
M1  - 0
PY  - 2011
SN  - 1383-5866
SP  - 100-105
ST  - Effect of operating parameters on the decolorization and oxidation of textile wastewater by the fluidized-bed Fenton process
T2  - Separation and Purification Technology
TI  - Effect of operating parameters on the decolorization and oxidation of textile wastewater by the fluidized-bed Fenton process
UR  - http://www.sciencedirect.com/science/article/pii/S1383586611005259
files/118/S1383586611005259.html
VL  - 83
Y2  - 2013/01/14/03:50:19
ID  - 208
ER  - 


TY  - JOUR
AB  - Recently more attention has been paid to emerging pollutants in water. Among the treatments proposed for abatement of these compounds Advance Oxidation Processes (AOPs) have been used. Many studies are focused on elimination of the original pollutant and TOC while less attention has been paid for generated oxidation intermediates and their associated toxicity. In this work nicotine was used as target pollutant and Fenton's Reagent (FR) as AOP. Nicotine and TOC conversion were obtained and an estimation of the toxicity of the oxidation intermediates produced was determined by using Microtox. Reactions were carried out in a batch manner, at two different temperatures (20 and 50 °C), using different amounts of hydrogen peroxide (5% to 200% of the stoichiometric dosage required for complete mineralization). Complete nicotine removal was achieved with FR at low oxidant doses even at 20 °C. However, only about 60% TOC percent removal was achieved. Moreover some toxic intermediates were generated, especially at initial oxidation stages. For example, for nicotine conversion 80% and TOC conversion 10%, toxicity obtained was fifteen times higher than the initial one. This must be taken into account in order to elucidate the time required and the effectiveness of the process.
AU  - Rodriguez, Sergio
AU  - Santos, Aurora
AU  - Romero, Arturo
DA  - 2011/10/03/
DO  - 10.1016/j.desal.2011.06.055
DP  - ScienceDirect
J2  - Desalination
KW  - AOPs
Emerging pollutants
Fenton's reagent
Nicotine
Toxicity
L1  - files/96/Rodriguez et al. - 2011 - Effectiveness of AOP's on abatement of emerging po.pdf
M1  - 1–3
PY  - 2011
SN  - 0011-9164
SP  - 108-113
ST  - Effectiveness of AOP's on abatement of emerging pollutants and their oxidation intermediates
T2  - Desalination
TI  - Effectiveness of AOP's on abatement of emerging pollutants and their oxidation intermediates: Nicotine removal with Fenton's Reagent
UR  - http://www.sciencedirect.com/science/article/pii/S0011916411005832
files/95/S0011916411005832.html
VL  - 280
Y2  - 2013/01/14/03:23:18
ID  - 209
ER  - 


TY  - JOUR
AB  - The mineralization and biodegradability increase and their combination of two traditional and two relatively new organic contaminants by Fenton reagents with three different types of iron, Fe2+, Fe3+, and Fe0 were investigated. The traditional contaminants examined were trichloroethene (TCE) and 2,4-dichlorophenol (2,4-DCP) while 1,4-dioxane (1,4-D) and 1,2,3-trichloropropane (TCP) were studied for the relatively new contaminants. The mineralization and biodegradability were represented by dissolved organic carbon (DOC) reduction and the ratio of biodegradable dissolved organic carbon and DOC, respectively. For all four contaminants, Fenton reagent using Fe2+ was more effective in the DOC reduction than Fenton reagents using Fe3+ and Fe0 in most cases. The types of Fe that provided maximum biodegradability increase were not the same for all four compounds, Fe3+ for TCE, Fe0 for 2,4-DCP, Fe2+ for 1,4-D, and Fe3+ for TCP. When the combination of DOC elimination and biodegradability increase (least refractory fraction) was considered, Fe2+ was the best choice except for 2,4-DCP which was susceptible to Fe0 catalyzed Fenton reagent the most. The least refractory fractions remaining after 120 min of reaction were 20–25% for TCE, 2,4-DCP, and TCP and 30–40% for 1,4-D. The iron type in Fenton reaction also affected the type of mineralization kinetics of TCE, 2,4-DCP, and TCP as well as the types of degradation by-products of these contaminants. Some of the by-products found, such as isopropanol and propionic aldehyde, which were produced from Fe0 catalyzed Fenton degradation of TCP, have not been previously reported.
AU  - Khan, Eakalak
AU  - Wirojanagud, Wanpen
AU  - Sermsai, Nawarat
DA  - 2009/01/30/
DO  - 10.1016/j.jhazmat.2008.04.049
DP  - ScienceDirect
J2  - Journal of Hazardous Materials
KW  - Biodegradable dissolved organic carbon
Degradation by-products
Dissolved organic carbon
Fenton reaction
Iron type
Kinetics
L1  - files/322/Khan et al. - 2009 - Effects of iron type in Fenton reaction on mineral.pdf
M1  - 2–3
PY  - 2009
SN  - 0304-3894
SP  - 1024-1034
ST  - Effects of iron type in Fenton reaction on mineralization and biodegradability enhancement of hazardous organic compounds
T2  - Journal of Hazardous Materials
TI  - Effects of iron type in Fenton reaction on mineralization and biodegradability enhancement of hazardous organic compounds
UR  - http://www.sciencedirect.com/science/article/pii/S0304389408005931
files/321/S0304389408005931.html
VL  - 161
Y2  - 2013/01/15/04:30:29
ID  - 210
ER  - 


TY  - JOUR
AB  - This study presents the efficiency of Fenton process in the degradation of organic compounds of nuclear laundry water. The influence of Fe2+ and hydrogen peroxide ratio, hydrogen peroxide dose, pH and treatment time were investigated. The degradation of non-ionic surfactant and other organic compounds was analysed as COD, TOC and molecular weight distribution (MWD). The most cost-effective degradation conditions were at H2O2/Fe2+ stoichiometric molar ratio of 2 with 5 min mixing and H2O2 dose of 1000 mg l−1. With the initial pH of 6, the reductions of COD and TOC were 85% and 69%, respectively. However, the removal of the organic compounds was mainly carried out by Fenton-based Fe3+ coagulation rather than Fenton oxidation. Fenton process proved to be much more efficient than previously performed ozone-based oxidation processes.
AU  - Vilve, Miia
AU  - Hirvonen, Arja
AU  - Sillanpää, Mika
DA  - 2009/05/30/
DO  - 10.1016/j.jhazmat.2008.09.058
DP  - ScienceDirect
J2  - Journal of Hazardous Materials
KW  - Coagulation
Fenton process
Non-ionic surfactant
pH
Wastewater
L1  - files/111/Vilve et al. - 2009 - Effects of reaction conditions on nuclear laundry .pdf
M1  - 2–3
PY  - 2009
SN  - 0304-3894
SP  - 1468-1473
ST  - Effects of reaction conditions on nuclear laundry water treatment in Fenton process
T2  - Journal of Hazardous Materials
TI  - Effects of reaction conditions on nuclear laundry water treatment in Fenton process
UR  - http://www.sciencedirect.com/science/article/pii/S0304389408014040
files/110/S0304389408014040.html
VL  - 164
Y2  - 2013/01/14/03:46:57
ID  - 211
ER  - 


TY  - JOUR
AB  - The purpose of this study is to efficiently operate Fenton’s oxidation process with quantitative analysis of the amount of the organic substances removed by oxidation and coagulation in treatment of the non-biodegradable landfill leachate by Fenton’s reagents. The sample used was the biologically treated leachate in the Kimpo metropolitan landfill site in Korea and its COD, BOD5, NH3–N and Cl− concentrations were about 1500, 30, 1300 and 4500 mg/l, respectively. The COD removal by oxidation of the organic substances with hydrogen peroxide was most efficient in the pH range of 2.5–4. However, it drastically decreased according to the pH value above 5. The COD removal efficiency by coagulation increased with the increase of the ferrous sulfate dosage, but the overall efficiency over a minimum dosage of 500 mg/l was scarcely changed. The efficiency of hydrogen peroxide actually used in the oxidation of the organic substances was only about 45%. The optimum range of the coagulation pH to maximize the COD removal efficiency by coagulation was 3–6, but that was slightly lower than the pH range of 6–9 generally known in the literature.
AU  - Kang, Yun Whan
AU  - Hwang, Kyung-Yub
DA  - 2000/07/01/
DO  - 10.1016/s0043-1354(99)00388-7
DP  - ScienceDirect
J2  - Water Research
KW  - Coagulation
COD removal efficiency
Fenton’s oxidation
Hydrogen peroxide
landfill leachate
L1  - files/477/Kang and Hwang - 2000 - Effects of reaction conditions on the oxidation ef.pdf
M1  - 10
PY  - 2000
SN  - 0043-1354
SP  - 2786-2790
ST  - Effects of reaction conditions on the oxidation efficiency in the Fenton process
T2  - Water Research
TI  - Effects of reaction conditions on the oxidation efficiency in the Fenton process
UR  - http://www.sciencedirect.com/science/article/pii/S0043135499003887
files/476/S0043135499003887.html
VL  - 34
Y2  - 2013/01/15/09:05:15
ID  - 212
ER  - 


TY  - JOUR
AB  - A study has been conducted to enhance degradation of a mixture of polycyclic aromatic hydrocarbons (PAHs) by combining biodegradation with hydrogen peroxide oxidation in a former manufactured gas plant (MGP) soil. An active bacterial consortium enriched from the MGP surface soil (0–2 m) biodegraded more than 90% of PAHs including 2-, 3-, and 4-ring hydrocarbons in a model soil. The consortium was also able to transform about 50% of 4- and 5-ring hydrocarbons in the MGP soil. As a chemical oxidant, Fenton's reagent (H2O2+Fe2+) was very efficient in the destruction of a mixture of PAHs (i.e., naphthalene (NAP), fluorene (FLU), phenanthrene (PHE), anthracene (ANT), pyrene (PYR), chrysene (CHR), and benzo(a)pyrene (BaP)) in the model soil; noticeably, 84.5% and 96.7% of initial PYR and BaP were degraded, respectively. In the MGP soil, the same treatment destroyed more than 80% of 2- and 3-ring hydrocarbons and 20–40% of 4- and 5-ring compounds. However, the low pH requirement (pH 2–3) for optimum Fenton reaction made the process incompatible with biological treatment and posed potential hazards to the soil ecosystem where the reagent was used. In order to overcome such limitation, a modified Fenton-type reaction was performed at near neutral pH by using ferric ions and chelating agents such as catechol and gallic acid. By the combined treatment of the modified Fenton reaction and biodegradation, more than 98% of 2- or 3-ring hydrocarbons and between 70% and 85% of 4- or 5-ring compounds were degraded in the MGP soil, while maintaining its pH about 6–6.5.
AU  - Nam, Kyoungphile
AU  - Rodriguez, Wilson
AU  - Kukor, Jerome J.
DA  - 2001/10//
DO  - 10.1016/s0045-6535(01)00051-0
DP  - ScienceDirect
J2  - Chemosphere
KW  - Biodegradation
Chelating agent
Fenton's reagent
Hydrogen peroxide oxidation
MGP soil
Polycyclic aromatic hydrocarbons
L1  - files/712/Nam et al. - 2001 - Enhanced degradation of polycyclic aromatic hydroc.pdf
M1  - 1
PY  - 2001
SN  - 0045-6535
SP  - 11-20
ST  - Enhanced degradation of polycyclic aromatic hydrocarbons by biodegradation combined with a modified Fenton reaction
T2  - Chemosphere
TI  - Enhanced degradation of polycyclic aromatic hydrocarbons by biodegradation combined with a modified Fenton reaction
UR  - http://www.sciencedirect.com/science/article/pii/S0045653501000510
files/711/S0045653501000510.html
VL  - 45
Y2  - 2013/01/15/16:07:37
ID  - 213
ER  - 


TY  - JOUR
AB  - Chemical oxidation technologies are often employed for the treatment of complex industrial effluents that are not amenable to conventional biological methods. The role of chemical oxidation depends on the treatment objectives and may vary from partial remediation to complete mineralization. In the case of partial treatment, chemical oxidation aims at the selective removal of the more bioresistant fractions and their conversion to readily biodegradable intermediates that can subsequently be treated biologically. Coupling chemical pre-oxidation with biological post-treatment is conceptually beneficial as it can lead to increased overall treatment efficiencies compared with the efficiency of each individual stage. This paper reviews recent developments and highlights some important aspects that need to be addressed when considering such integrated schemes. Copyright © 2004 Society of Chemical Industry
AU  - Mantzavinos, Dionissios
AU  - Psillakis, Elefteria
DA  - 2004
DO  - 10.1002/jctb.1020
J2  - Journal of Chemical Technology & Biotechnology
KW  - advanced oxidation processes
biodegradation
effluents
pre-treatment
wet oxidation
M1  - 5
N1  - The following values have no corresponding Zotero field:<br/>journalAbbreviation: J. Chem. Technol. Biotechnol.<br/>PB - John Wiley & Sons, Ltd.<br/>
PY  - 2004
SN  - 1097-4660
SP  - 431-454
ST  - Enhancement of biodegradability of industrial wastewaters by chemical oxidation pre-treatment
T2  - Journal of Chemical Technology & Biotechnology
TI  - Enhancement of biodegradability of industrial wastewaters by chemical oxidation pre-treatment
UR  - http://dx.doi.org/10.1002/jctb.1020
VL  - 79
ID  - 299
ER  - 


TY  - JOUR
AU  - Mantzavinos, Dionissios
AU  - Psillakis, Elefteria
DA  - 2004/05//
DO  - 10.1002/jctb.1020
DP  - CrossRef
L1  - files/431/1020_ftp.pdf
M1  - 5
PY  - 2004
SN  - 0268-2575, 1097-4660
SP  - 431-454
ST  - Enhancement of biodegradability of industrial wastewaters by chemical oxidation pre-treatment
T2  - Journal of Chemical Technology & Biotechnology
TI  - Enhancement of biodegradability of industrial wastewaters by chemical oxidation pre-treatment
UR  - http://doi.wiley.com/10.1002/jctb.1020
VL  - 79
Y2  - 2013/01/15/07:22:37
ID  - 300
ER  - 


TY  - JOUR
AB  - Europe PubMed Central (Europe PMC) is an archive of life sciences journal literature.
AU  - W, Bae
AU  - Sh, Lee
AU  - Gb, Ko
DA  - 2003/12//
DP  - europepmc.org
J2  - Water Sci Technol
KW  - Fluid
info:mesh/Coloring Agents
info:mesh/Cost Control
info:mesh/Hydrogen Peroxide
info:mesh/Iron
info:mesh/Oxidation-Reduction
info:mesh/Textile Industry
info:mesh/Waste Disposal
info:mesh/Water Purification
L1  - files/442/049040091.pdf
LA  - eng
M1  - 4
PY  - 2003
SN  - 0273-1223
SP  - 91-96
ST  - Evaluation of predominant reaction mechanisms for the Fenton process in textile dyeing wastewater treatment
T2  - Water science and technology : a journal of the International Association on Water Pollution Research
TI  - Evaluation of predominant reaction mechanisms for the Fenton process in textile dyeing wastewater treatment
UR  - http://europepmc.org/abstract/MED/15077954
files/441/15077954.html
VL  - 49
Y2  - 2013/01/15/08:07:27
ID  - 346
ER  - 


TY  - JOUR
AU  - Sabour, Mohammad Reza
AU  - Lak, Mehdi Ghanbarzadeh
AU  - Rabbani, Omid
DA  - 2011/04/01/
DO  - 10.1177/0734242x10375332
DP  - login.oaresciences.org
J2  - Waste Manag Res
L1  - files/394/Sabour et al. - 2011 - Evaluation of the main parameters affecting the Fe.pdf
LA  - en
M1  - 4
PY  - 2011
SN  - 0734-242X, 1096-3669
SP  - 397-405
ST  - Evaluation of the main parameters affecting the Fenton oxidation process in municipal landfill leachate treatment
T2  - Waste Management & Research
TI  - Evaluation of the main parameters affecting the Fenton oxidation process in municipal landfill leachate treatment
UR  - http://login.oaresciences.org/whalecomwmr.sagepub.com/whalecom0/content/29/4/397
files/395/397.full.html
VL  - 29
Y2  - 2013/01/15/05:55:58
ID  - 301
ER  - 


TY  - JOUR
AB  - The experimental design methodology was applied having in mind the optimization of the azo dye Orange II degradation using the Fenton's reagent (mixture of H2O2 and Fe2+). The variables considered were the temperature, H2O2 concentration and Fe2+:H2O2 ratio, for a dye concentration of 0.3 mM and pH 3. The multivariate experimental design allowed to develop quadratic models for: (i) color removal and (ii) total organic carbon (TOC) reduction (both after 2 h of reaction), which were adequate to predict responses in all the range of experimental conditions used. Under the optimum conditions, performances of 99.7 and 70.7% for color and TOC removal, respectively, were experimentally reached. It was found that both H2O2 concentration and temperature have an important effect in the organic matter degradation efficiency.
AU  - Ramirez, J. Herney
AU  - Costa, Carlos A.
AU  - Madeira, Luis M.
DA  - 2005/10/30/
DO  - 10.1016/j.cattod.2005.07.060
DP  - ScienceDirect
J2  - Catalysis Today
KW  - Experimental design
Fenton's reagent
Hydrogen peroxide
Orange II
Oxidation
L1  - files/546/Ramirez et al. - 2005 - Experimental design to optimize the degradation of.pdf
M1  - 0
PY  - 2005
SN  - 0920-5861
SP  - 68-76
ST  - Selected Contributions of the XIX Ibero American Catalysis Symposium Selected Contributions of the XIX Ibero American Catalysis Symposium
T2  - Catalysis Today
TI  - Experimental design to optimize the degradation of the synthetic dye Orange II using Fenton's reagent
UR  - http://www.sciencedirect.com/science/article/pii/S0920586105003822
files/543/S0920586105003822.html
VL  - 107–108
Y2  - 2013/01/16/06:02:43
ID  - 214
ER  - 


TY  - JOUR
AB  - Advanced oxidation technologies (AOTs) have been widely investigated for their potential application in post-tertiary sewage treatment due to their ease of operation, high efficiency in organic mineralisation, inactivation of pathogens and low formation of disinfection by-products. This study aimed to evaluate the technical, economical and environmental feasibility for applying AOTs at decentralised wastewater treatment. A comprehensive process selection and assessment framework for the application of AOTs in decentralised wastewater systems for wastewater recycling and reuse purposes were developed in this study. Different AOTs were assessed for their suitability to retrofit as an advanced wastewater treatment option to a decentralised wastewater case study plant in South East Queensland, Australia to produce Class A+ recycled water. Among the different AOTs assessed, it was assessed that the H2O2/UV process was the best AOT treatment option, in terms of technical, economic and environmental benefits for treating sewage effluent from the decentralised wastewater system analysed in this case study. It is anticipated that additional data sets from different pilot or full scale AOT plants will allow the performance predictions of AOTs for a wide range of decentralised wastewater treatment applications. Through this study, it is anticipated that the potential future uptake of AOTs as an advanced treatment option will be enhanced, given the comprehensive and detailed technical, economic and environmental analysis presented in the paper.
AU  - Chong, Meng Nan
AU  - Sharma, Ashok K.
AU  - Burn, Stewart
AU  - Saint, Christopher P.
DA  - 2012/11//
DO  - 10.1016/j.jclepro.2012.06.003
DP  - ScienceDirect
J2  - Journal of Cleaner Production
KW  - Small-scale wastewater systems
Techno-economic assessment and advanced oxidation processes
Water recycling and reuse
L1  - files/582/Chong et al. - 2012 - Feasibility study on the application of advanced o.pdf
M1  - 0
PY  - 2012
SN  - 0959-6526
SP  - 230-238
ST  - Feasibility study on the application of advanced oxidation technologies for decentralised wastewater treatment
T2  - Journal of Cleaner Production
TI  - Feasibility study on the application of advanced oxidation technologies for decentralised wastewater treatment
UR  - http://www.sciencedirect.com/science/article/pii/S0959652612002867
files/581/S0959652612002867.html
VL  - 35
Y2  - 2013/01/15/13:38:51
ID  - 215
ER  - 


TY  - JOUR
AB  - Both Fenton oxidation and the combination of aerobic Sequencing Batch Reactor (SBR) + Fenton oxidation were investigated in a bench-scale study to degrade and reuse a real textile wastewater with a TOC = 465 mg L− 1 C, COD = 2100 mg L− 1 O2 and Escherichia coli = 80,000 CFU mL− 1, according to RD 1620/2007 (Spanish Normative for wastewater reclamation and reuse). The independent variables considered for the optimization of the oxidative process were temperature, H2O2 and Fe (II) concentrations. Under the best stand-alone Fenton operating conditions: T = 25 °C, pH = 3; [H2O2] = 1650 mg L− 1 and [Fe (II)] = 216 mg L− 1, we achieved 64% TOC reduction and &gt; 99% E. coli removal. However, the best results were obtained when applying Fenton process with [H2O2] = 1518 mg L− 1 and [Fe (II)] = 66.5 mg L− 1, as a biological polishing step. The aerobic biological treatment was conducted using a SBR with 1 day HRT. In this case 92% TOC and &gt; 99% E. coli removal were accomplished. The obtained results showed the feasibility of both processes to achieve suitable water qualities for internal reuse, according to RD 1620/2007.
AU  - Blanco, José
AU  - Torrades, Francesc
AU  - De la Varga, Meritxell
AU  - García-Montaño, Julia
DA  - 2012/02/01/
DO  - 10.1016/j.desal.2011.11.055
DP  - ScienceDirect
J2  - Desalination
KW  - Aerobic + Fenton treatment
Escherichia coli removal
Fenton treatment
SBR
Textile wastewater treatment
Water reuse
L1  - files/197/Blanco et al. - 2012 - Fenton and biological-Fenton coupled processes for.pdf
M1  - 0
PY  - 2012
SN  - 0011-9164
SP  - 394-399
ST  - Fenton and biological-Fenton coupled processes for textile wastewater treatment and reuse
T2  - Desalination
TI  - Fenton and biological-Fenton coupled processes for textile wastewater treatment and reuse
UR  - http://www.sciencedirect.com/science/article/pii/S0011916411010010
files/196/S0011916411010010.html
VL  - 286
Y2  - 2013/01/14/05:01:44
ID  - 216
ER  - 


TY  - JOUR
AB  - The simultaneous use of Fenton reagent and irradiation for the treatment of textile wastewaters generated during a hydrogen peroxide bleaching process is investigated. The experimental conditions tested during this study provide the simultaneous occurrence of Fenton, Fenton-like and photo-Fenton reactions. The batch experimental results are assessed in terms of total organic carbon reduction. Identification of some of the chemical constituents of the effluent was performed by means of GC–MS. Other pollution related features of the initial effluent-like COD and color were also measured. The main parameters that govern the complex reactive system, i.e., light intensity, temperature, pH, Fe(II) and H2O2 initial concentrations have been studied. Concentrations of Fe(II) between 0 and 400 ppm, and H2O2 between 0 and 10,000 ppm were used. Temperatures above 25°C and up to 70°C show a beneficial effect on organic load reduction. A set of experiments was conducted under different light sources with the aim to ensure the efficiency of using solar light irradiation. The combination of Fenton, Fenton-like and photon-Fenton reactions has been proved to be highly effective for the treatment of such a type of wastewaters, and several advantages for the technique application arise from the study.
AU  - Pérez, Montserrat
AU  - Torrades, Francesc
AU  - Domènech, Xavier
AU  - Peral, José
DA  - 2002/06//
DO  - 10.1016/s0043-1354(01)00506-1
DP  - ScienceDirect
J2  - Water Research
KW  - Advanced oxidation processes
Fenton
Photochemical reactions
Textile
L1  - files/567/Pérez et al. - 2002 - Fenton and photo-Fenton oxidation of textile efflu.pdf
M1  - 11
PY  - 2002
SN  - 0043-1354
SP  - 2703-2710
ST  - Fenton and photo-Fenton oxidation of textile effluents
T2  - Water Research
TI  - Fenton and photo-Fenton oxidation of textile effluents
UR  - http://www.sciencedirect.com/science/article/pii/S0043135401005061
files/566/S0043135401005061.html
VL  - 36
Y2  - 2013/01/15/13:17:39
ID  - 217
ER  - 


TY  - JOUR
AB  - In the present work, the possibility of using chemical oxidation through Fenton's reagent for the pre-treatment of cork cooking wastewaters was exploited. Aiming both the selection of the best operating conditions (pH, Fe2+:H2O2 ratio and initial H2O2 concentration) and the evaluation of the overall reaction kinetics, trials were performed in a batch reactor. Operating at pH=3.2, H2O2 concentration=10.6 g/L and Fe2+:H2O2 ratio=1:5 (by weight), about 66.4% of total organic carbon (TOC), 87.3% of chemical oxygen demand (COD) and 70.2% of biochemical oxygen demand (BOD5) were removed and an increase of the BOD5/COD ratio from 0.27 to 0.63 was achieved. In the temperature range 20–50°C, the best performance was obtained at 30°C. The kinetic study was undertaken at different initial TOC concentrations and temperatures. Overall kinetics can be described by a second-order followed by a zero-order rate equation and the apparent kinetic constants at 30°C are k=2.3×10−4 L/mg min and k0=26.0 mg/L min, respectively. The experiments performed at different temperatures confirmed the global kinetic model and allowed to calculate the global activation energy for the second-order reaction (70.7 kJ/mol).
AU  - Guedes, Anabela M. F. M.
AU  - Madeira, Luis M. P.
AU  - Boaventura, Rui A. R.
AU  - Costa, Carlos A. V.
DA  - 2003/07//
DO  - 10.1016/s0043-1354(03)00178-7
DP  - ScienceDirect
J2  - Water Research
KW  - Cork cooking wastewater
Fenton's reagent
Kinetics
Oxidation
L1  - files/99/Guedes et al. - 2003 - Fenton oxidation of cork cooking wastewater—overal.pdf
M1  - 13
PY  - 2003
SN  - 0043-1354
SP  - 3061-3069
ST  - Fenton oxidation of cork cooking wastewater—overall kinetic analysis
T2  - Water Research
TI  - Fenton oxidation of cork cooking wastewater—overall kinetic analysis
UR  - http://www.sciencedirect.com/science/article/pii/S0043135403001787
files/98/S0043135403001787.html
VL  - 37
Y2  - 2013/01/14/03:28:08
ID  - 218
ER  - 


TY  - JOUR
AB  - The Fenton oxidation process was applied as a pretreatment process to degrade non-biodegradable organic matters in pigment wastewater. It was necessary to continuously measure the fluctuating concentration of organics in the pigment wastewater and to determine the amount of Fenton’s reagent required to oxidize the organics. Batch and continuous flow tests were used to evaluate the relationship between the concentration of organics (CODCr) and the amount of Fenton’s reagent required to achieve a sufficient oxidation of the organics. On-line measurements of the oxidation-reduction potential (ORP) value in the batch and continuous flow tests showed that the maximum ORP values were highly related to the organic concentrations (expressed as CODCr) and the Fenton’s reagent dosage (expressed as H2O2 concentration). The empirical equation was [CODCr]=8808+0.494[H2O2]-14.6ORP. A control program of Fenton’s reagent dosage based on the empirical equation was applied to control of a pilot scale Fenton oxidation process using ORP measurement. The concentration of organics predicted with the control program well agreed with the observed concentration of organics in the pigment wastewater. The variation of the effluent organics concentration of the controlled Fenton oxidation process was significantly reduced compared to that of a process without the control system. These results suggested that the control system of Fenton’s reagent dosage using ORP measurement would be applicable to the Fenton oxidation process for efficient pretreatment of pigment wastewater.
AU  - Kim, Young- O.
AU  - Nam, Hai-Uk
AU  - Park, Yu-Ri
AU  - Lee, Jong-Hyun
AU  - Park, Tae-Joo
AU  - Lee, Tae-Ho
DA  - 2004/07/01/
DO  - 10.1007/bf02705523
DP  - link.springer.com
J2  - Korean J. Chem. Eng.
KW  - Auto-control System
Biotechnology
Catalysis
Fenton oxidation
Industrial Chemistry/Chemical Engineering
Materials Science
Oxidation-reduction Potential
Pigment Wastewater
Pretreatment
L1  - files/273/Kim et al. - 2004 - Fenton oxidation process control using oxidation-r.pdf
LA  - en
M1  - 4
PY  - 2004
SN  - 0256-1115, 1975-7220
SP  - 801-805
ST  - Fenton oxidation process control using oxidation-reduction potential measurement for pigment wastewater treatment
T2  - Korean Journal of Chemical Engineering
TI  - Fenton oxidation process control using oxidation-reduction potential measurement for pigment wastewater treatment
UR  - http://link.springer.com/article/10.1007/BF02705523
files/274/BF02705523.html
VL  - 21
Y2  - 2013/01/15/03:55:55
ID  - 331
ER  - 


TY  - JOUR
AB  - Treatment of simulated desizing wastewater by the Fenton process along with chemical coagulation was investigated. The simulated wastewater contained less than 0.2% polyvinyl alcohol (PVA) and Blue G (a direct dye) or Black B (a reactive dye). Experiments were conducted to investigate the effects of operating variables, including pH, temperature and the treatment time, on the COD removal efficiency. Optimal operating conditions were experimentally determined. Chemical coagulation using polyaluminum chloride and polymer was found to complement the Fenton treatment process in reducing the floc settling time, enhancing color removal and reducing Fe ion concentration. A two-step Fenton treatment process intended separately for chemical coagulation and chemical oxidation was observed to be only marginally better than the single-step one. A kinetic model for the Fenton treatment process was also proposed and the kinetic rate coefficients determined based on the experimental data.
AU  - Lin, Sheng H.
AU  - Lo, Cho C.
DA  - 1997/08//
DO  - 10.1016/s0043-1354(97)00024-9
DP  - ScienceDirect
J2  - Water Research
KW  - chemical coagulation
desizing wastewater
Fenton's reagent
Kinetic model
L1  - files/360/Lin and Lo - 1997 - Fenton process for treatment of desizing wastewate.pdf
M1  - 8
PY  - 1997
SN  - 0043-1354
SP  - 2050-2056
ST  - Fenton process for treatment of desizing wastewater
T2  - Water Research
TI  - Fenton process for treatment of desizing wastewater
UR  - http://www.sciencedirect.com/science/article/pii/S0043135497000249
files/359/S0043135497000249.html
VL  - 31
Y2  - 2013/01/15/05:13:56
ID  - 219
ER  - 


TY  - JOUR
AB  - Remediation of industrial wastewaters represents a stringent problem in modern society, which requires particular understanding and ad hoc solutions. In this work, we performed extensive experimental study of chemical Fenton oxidation in order to understand the optimal operative conditions to be applied in real industrial wastewaters treatment. We analyzed the effectiveness of chemical oxygen demand (COD) removal from different wastewaters within a wide range of initial COD content. We observed a maximum COD % removal of about 80%, assessing the efficiency of the process. In order to understand the role of different reagents in the final yield, we performed a factorial experimental approach on the Fenton's reagents (H2O2 and Fe2+) and analyzed the results developing an analytical second-order model. The model depends on three variables, namely: the initial [CODi] of the sample, the [CODi]/[H2O2] ratio and [H2O2]/[Fe2+] ratio. We obtained an accurate description of the COD % removal in different initial conditions, with a R2 = 0.85. In particular, we observed that optimal quantities of Fenton's reagents are a function of the initial COD of the treated wastes.
AU  - Bianco, Barbara
AU  - De Michelis, Ida
AU  - Vegliò, Francesco
DA  - 2011/02/28/
DO  - 10.1016/j.jhazmat.2010.12.054
DP  - ScienceDirect
J2  - Journal of Hazardous Materials
KW  - AOPs
Fenton process
Industrial wastewaters
Optimization
Oxidation
Surface response technique
L1  - files/79/Bianco et al. - 2011 - Fenton treatment of complex industrial wastewater.pdf
M1  - 2–3
PY  - 2011
SN  - 0304-3894
SP  - 1733-1738
ST  - Fenton treatment of complex industrial wastewater
T2  - Journal of Hazardous Materials
TI  - Fenton treatment of complex industrial wastewater: Optimization of process conditions by surface response method
UR  - http://www.sciencedirect.com/science/article/pii/S0304389410016341
files/78/S0304389410016341.html
VL  - 186
Y2  - 2013/01/13/14:39:26
ID  - 220
ER  - 


TY  - JOUR
AB  - The addition of solid particles, namely synthetic zeolites NH4ZSM5 and HY, was investigated in order to enhance the efficiency of AOPs for dye wastewater treatment. Experiments were conducted at the optimal operating parameters for each Fenton type process and studied coloured pollutants established in Part I of this study in order to find the optimal dose of applied zeolites and understand their role in the new combined AOPs. Degradation of the studied dyes, C.I. Reactive Blue 49 and C.I. Reactive Blue 137, was monitored by means of the UV/VIS, TOC and AOX analysis, thus determining decolourization and mineralization extents of model solutions. Organic content adsorbed onto applied zeolites after the treatment was scanned and characterized using FT-IR spectrophotometer. Applied AOPs in combination with zeolites were shown to be very successful in colour removal, &gt;98%, similarly like Fenton type processes reported in Part I of this study, while improvements in the mineralization of the studied dyes depended on the type and the dose of zeolite, as well as on dye structure and the type of applied AOP.
AU  - Kušić, Hrvoje
AU  - Lončarić Božić, Ana
AU  - Koprivanac, Natalija
AU  - Papić, Sanja
DA  - 2007
DO  - 10.1016/j.dyepig.2006.01.050
DP  - ScienceDirect
J2  - Dyes and Pigments
KW  - Coloured wastewater
Fenton “like” process
Fenton process
Reactive Blue 137
Reactive Blue 49
Zeolite
L1  - files/709/Kušić et al. - 2007 - Fenton type processes for minimization of organic .pdf
M1  - 2
PY  - 2007
SN  - 0143-7208
SP  - 388-395
ST  - Fenton type processes for minimization of organic content in coloured wastewaters. Part II
T2  - Dyes and Pigments
TI  - Fenton type processes for minimization of organic content in coloured wastewaters. Part II: Combination with zeolites
UR  - http://www.sciencedirect.com/science/article/pii/S014372080600091X
files/708/S014372080600091X.html
VL  - 74
Y2  - 2013/01/15/16:00:30
ID  - 221
ER  - 


TY  - CHAP
A2  - Puzyn, Tomasz
AU  - Telles, Cludia
AU  - Granhen Tavares, Clia Regina
DP  - CrossRef
L1  - files/417/InTech-Fenton_s_process_for_the_treatment_of_mixed_waste_chemicals.pdf
PB  - InTech
PY  - 2012
SN  - 978-953-307-917-2
ST  - Fenton´s Process for the Treatment of Mixed Waste Chemicals
T2  - Organic Pollutants Ten Years After the Stockholm Convention - Environmental and Analytical Update
TI  - Fenton´s Process for the Treatment of Mixed Waste Chemicals
UR  - http://www.intechopen.com/books/organic-pollutants-ten-years-after-the-stockholm-convention-environmental-and-analytical-update/fenton-s-process-for-the-treatment-of-mixed-waste-chemicals
files/257/fenton-s-process-for-the-treatment-of-mixed-waste-chemicals.html
Y2  - 2013/01/14/10:27:04
ID  - 302
ER  - 


TY  - JOUR
AB  - Due to stringent discharge limits, various pollutants (xenobiotics, biorecalcitrants, persistent) need to be handled carefully. A class of chemicals synthesized for tanning or retanning purposes in the leather tanning industry is collectively termed synthetic tannins (syntans, ST), resins (acrylic), oils (OLs), etc. The literature on tannins is focused on individual chemical species, e.g. tannic or gallic acid, thus providing only scanty information on tannin complex mixtures and their fate in the biological treatment/aquatic environment. The present study evaluates Fenton’s oxidation (FO) as the most basic advanced oxidation process for treatment of four types of STs [(ST1: cresol-based, ST2: poly-condensed formaldehyde and disulphane with sulfonic aromatic acids, ST3: phenol-based, ST4:condensed phenol-based). FO conditions were also tested on oils (OL1: sulphonated, OL2: sulfunated and OL3:phosphorous-based)] individually. These products generate the highest COD in a re-tanning process. FO process was performed at pH 3.0 and 40–45°C, which is original temperature of re-tanning process, in the synthetic solutions containing 300 mg/l of COD equivalent of each compound. Among various ratios of H2O2/FeSO4 applied, the highest COD and UV absorbance removal were obtained at 600/500 (mg/mg) ratio for all STs tested. At the same ratio, FO process was also performed versus time for each ST. At the end of 5 min of oxidation, more than 75% COD removal was obtained (75% for ST3, 85% for ST1 and ST2, 90% for ST4) and there was no significant increase in COD removal after 10 min of oxidation except ST1 (which increased up to 15 min) in accordance with UV and oxidation redox potential (ORP) measurements. A ratio of 600/750 mg/mg of H2O2/FeSO4 was the optimum for FO process for the three types of oils. The results obtained in this study indicated the rapid oxidation of re-tanning agents which are hardly biodegradable in biological process.
AU  - Lofrano, Giusy
AU  - Meriç, Sureyya
AU  - Belgiorno, Vincenzo
AU  - Napoli, Rodolfo M. A.
DA  - 2007/06/10/
DO  - 10.1016/j.desal.2006.03.589
DP  - ScienceDirect
J2  - Desalination
KW  - Advanced oxidation processes
COD and absorbance removal
Fenton oxidation
Leather tanning
Re-tanning materials
Synthetic tannins
L1  - files/161/Lofrano et al. - 2007 - Fenton’s oxidation of various-based tanning materi.pdf
M1  - 1–3
PY  - 2007
SN  - 0011-9164
SP  - 10-21
ST  - Ninth Environmental Science and Technology Symposium September 1–3, 2005, Rhodes, Greece
T2  - Desalination
TI  - Fenton’s oxidation of various-based tanning materials
UR  - http://www.sciencedirect.com/science/article/pii/S0011916407001932
files/160/S0011916407001932.html
VL  - 211
Y2  - 2013/01/14/04:20:24
ID  - 222
ER  - 


TY  - JOUR
AB  - The use of the Fenton’s reagent (FR) (a mixture of H2O2 and Fe2+) for the kinetic determination of individual chemical species is proposed. The possibilities of the reagent arise from the oxidant power of intermediate species generated during the slow oxidation of Fe2+ by H2O2, but very few analytical applications of the reagent can be found. The oxidation of organic compounds (known as the Fenton reaction) is in fact an induced chain reaction that proceeds to an extension which is influenced by the reaction conditions. Experimental design has been used for optimization thinking of the analytical application. The pesticide atrazine has been used as analyte to test the analytical possibilities of the FR. Partial least squares regression (PLS), applied to reaction profiles between 206 and 270 nm, was used as algorithm to make the calibration model. Atrazine concentrations ranging from 0.46 to 13.4×10−5 M have been used for calibration, and mean errors under 2.5% both for calibration and validation have been found. Other classical methods of calibration such as those using absolute values of absorbance, initial rates, etc. gave poor results in the cases considered. According to the study of interferences, the main drawback of the reagent is the lack of selectivity, but some possible ways of improving it are discussed. The method was applied for the determination of atrazine in several commercial atrazine-based pesticide preparations. In general, good results were obtained when compared with those found by gas–liquid chromatography as a reference. Recovery studies also gave satisfactory results.
AU  - López-Cueto, G.
AU  - Ostra, M.
AU  - Ubide, C.
AU  - Zuriarrain, J.
DA  - 2004/07/05/
DO  - 10.1016/j.aca.2003.10.012
DP  - ScienceDirect
J2  - Analytica Chimica Acta
KW  - Atrazine
Experimental design
Fenton’s reagent
Partial least squares regression
L1  - files/531/López-Cueto et al. - 2004 - Fenton’s reagent for kinetic determinations.pdf
M1  - 1
PY  - 2004
SN  - 0003-2670
SP  - 109-116
ST  - Papers presented at the 5th COLLOQUIUM CHEMIOMETRICUM MEDITERRANEUM
T2  - Analytica Chimica Acta
TI  - Fenton’s reagent for kinetic determinations
UR  - http://www.sciencedirect.com/science/article/pii/S0003267003013436
files/530/S0003267003013436.html
VL  - 515
Y2  - 2013/01/15/09:46:34
ID  - 223
ER  - 


TY  - JOUR
AB  - The oxidation of protocatechuic acid (PA), a typical phenol-type compound present in food processing wastewater, has been carried out by means of Fenton's reagent. Both the H2O2 and Fe(II) initial concentrations increase the PA degradation rate. Temperature also enhances the PA conversion when raised from 283 to 313 K, a further increase to 323 K results in a lower PA removal. Increasing the PA initial concentration leads to a decrease of conversion values but an opposite effect in terms of removal rate. pH values in the range 3?4 resulted in the total inhibition of the oxidation process. Similar PA depletion rates were experienced regardless of the oxidation state of the catalyst (ferrous or ferric iron). Additionally, an attempt based on the classic Fenton's chemistry plus some other stages accounting for the Fe(II) regeneration from Fe(III) and the inefficient H2O2 decomposition was conducted to model the process. Keywords: Fenton's reagent; protocatechuic acid; kinetics; phenolic compounds; water treatment; hydrogen peroxide.
AU  - Rivas, Francisco J.
AU  - Frades, Jesus
AU  - Alonso, Miguel A.
AU  - Montoya, C.
AU  - Monteagudo, J. M.
DA  - 2005/12/01/
DO  - 10.1021/jf0512712
DP  - ACS Publications
J2  - J. Agric. Food Chem.
L1  - files/676/jf0512712.pdf
M1  - 26
PY  - 2005
SN  - 0021-8561
SP  - 10097-10104
ST  - Fenton's Oxidation of Food Processing Wastewater Components. Kinetic Modeling of Protocatechuic Acid Degradation
T2  - Journal of Agricultural and Food Chemistry
TI  - Fenton's Oxidation of Food Processing Wastewater Components. Kinetic Modeling of Protocatechuic Acid Degradation
UR  - http://dx.doi.org/10.1021/jf0512712
files/675/jf0512712.html
VL  - 53
Y2  - 2013/01/15/15:09:37
ID  - 303
ER  - 


TY  - JOUR
AB  - A mixture of six phenolic acids, corresponding to an initial TOC of 370 mgC/L, was studied by Fenton's peroxidation aiming to improve the biodegradability of agro-industrial wastewaters. Input operating variables including the concentration of pollutants, iron and hydrogen peroxide as well as the reaction time were used to assess the mineralization degree through a factorial experimental methodology. A TOC removal in the range of 15.0–58.8% was attained within the operational conditions used. A reduced model was achieved using the statistically important independent factors and interactions to predict TOC degradation. On the hydrogen peroxide injection methodology, the results showed that the continuous introduction of small volumes is advantageous when compared with one single addition of the overall volume at the zero reaction time with a mineralization improvement of 11%. The use of FeSO4·7H2O correspondent to a Fe2+ load of 271 mg; [H2O2] = 488.0 mM, injected in twelve aliquots each 30 min during 6 h of reaction reached optimal efficiencies with the parent compounds (quantified by HPLC and the Folin–Ciocalteau method) quickly totally removed and TOC, COD and BOD5 final values of 123 mgC/L, 180 mgO2/L and 146 mgO2/L, respectively. Toxicity assessment by Vibrio fischeri light inhibition revealed that Fenton's process reduces the effluent ecological impact related with the decomposition of the toxic phenolic acids. Indeed, EC50 changed from 32.2% dilution to no-dilution needed. The analysis of BOD5/COD ratio pointed out a high improvement of the treated wastewater biodegradability from 0.30 to 0.80 meaning that the application of Fenton's oxidation as a pre-treatment enables a further application of an efficient post-biological technology which was also confirmed by respirometry.
AU  - Martins, Rui C.
AU  - Rossi, André F.
AU  - Quinta-Ferreira, Rosa M.
DA  - 2010/08/15/
DO  - 10.1016/j.jhazmat.2010.04.098
DP  - ScienceDirect
J2  - Journal of Hazardous Materials
KW  - Biodegradability
Ecological impact
Factorial design
Fenton's peroxidation
Phenolic wastewaters
L1  - files/152/Martins et al. - 2010 - Fenton's oxidation process for phenolic wastewater.pdf
M1  - 1–3
PY  - 2010
SN  - 0304-3894
SP  - 716-721
ST  - Fenton's oxidation process for phenolic wastewater remediation and biodegradability enhancement
T2  - Journal of Hazardous Materials
TI  - Fenton's oxidation process for phenolic wastewater remediation and biodegradability enhancement
UR  - http://www.sciencedirect.com/science/article/pii/S0304389410005443
files/151/S0304389410005443.html
VL  - 180
Y2  - 2013/01/14/04:20:24
ID  - 224
ER  - 


TY  - JOUR
AB  - The aim of our work was to compare Fenton's oxidation with existing biological SBR (sequencing batch reactor) reactor employed for treatment of the leachate, generated in local municipal landfill (35,000 inhabitants). Efficiencies of both procedures were monitored by chemical analyses and by acute toxicity studies with Vibrio fischeri and measurement of inhibition of oxygen consumption by activated sludge. Leachate was very toxic to V. fischeri and activated sludge and toxicity was not significantly reduced as well as effluent limits were not met during treatment in existing biological treatment plant. Fenton's oxidation, accomplished at different molar ratios of reagents (M(Fe2+)/M(H2O2) was 1/1; 1/3.3; 1/6.6 and 1/13.3) and various temperatures (20–45 °C), assured good removal of organic compounds (80% as COD) as well as other pollutants and slightly reduced toxicity, but effluent limits were not always met. Furthermore, additional oxidation experiments with biologically treated leachate confirmed, that Fenton's oxidation is not appropriate for polishing already treated leachate in SBR, because it degraded persistent organics into more biodegradable, still toxic ones, which could affect oxygen regime in a receiving stream. Fenton's process could not replace SBR treatment plant, but it could be a viable option for pretreatment of landfill leachate.
AU  - Žgajnar Gotvajn, A.
AU  - Zagorc-Končan, J.
AU  - Cotman, M.
DA  - 2011/07/15/
DO  - 10.1016/j.desal.2011.03.017
DP  - ScienceDirect
J2  - Desalination
KW  - Fenton's oxidation
landfill leachate
Pretreatment
Sequencing batch reactor
Toxicity
L1  - files/552/Žgajnar Gotvajn et al. - 2011 - Fenton's oxidative treatment of municipal landfill.pdf
M1  - 1–3
PY  - 2011
SN  - 0011-9164
SP  - 269-275
ST  - Fenton's oxidative treatment of municipal landfill leachate as an alternative to biological process
T2  - Desalination
TI  - Fenton's oxidative treatment of municipal landfill leachate as an alternative to biological process
UR  - http://www.sciencedirect.com/science/article/pii/S0011916411002359
files/551/S0011916411002359.html
VL  - 275
Y2  - 2013/01/15/13:04:02
ID  - 225
ER  - 


TY  - JOUR
AB  - Three multiple input and multiple output-type fuzzy-logic-based models were developed as an artificial intelligence-based approach to model a novel integrated process (UF–IER–EDBM–FO) consisted of ultrafiltration (UF), ion exchange resins (IER), electrodialysis with bipolar membrane (EDBM), and Fenton’s oxidation (FO) units treating young, middle-aged, and stabilized landfill leachates. The FO unit was considered as the key process for implementation of the proposed modeling scheme. Four input components such as H2O2/chemical oxygen demand ratio, H2O2/Fe2+ ratio, reaction pH, and reaction time were fuzzified in a Mamdani-type fuzzy inference system to predict the removal efficiencies of chemical oxygen demand, total organic carbon, color, and ammonia nitrogen. A total of 200 rules in the IF–THEN format were established within the framework of a graphical user interface for each fuzzy-logic model. The product (prod) and the center of gravity (centroid) methods were performed as the inference operator and defuzzification methods, respectively, for the proposed prognostic models. Fuzzy-logic predicted results were compared to the outputs of multiple regression models by means of various descriptive statistical indicators, and the proposed methodology was tested against the experimental data. The testing results clearly revealed that the proposed prognostic models showed a superior predictive performance with very high determination coefficients (R 2) between 0.930 and 0.991. This study indicated a simple means of modeling and potential of a knowledge-based approach for capturing complicated inter-relationships in a highly non-linear problem. Clearly, it was shown that the proposed prognostic models provided a well-suited and cost-effective method to predict removal efficiencies of wastewater parameters prior to discharge to receiving streams.
AU  - Sari, Hanife
AU  - Yetilmezsoy, Kaan
AU  - Ilhan, Fatih
AU  - Yazici, Senem
AU  - Kurt, Ugur
AU  - Apaydin, Omer
DO  - 10.1007/s11356-012-1370-6
DP  - link.springer.com
J2  - Environ Sci Pollut Res
KW  - Analytical Chemistry
Atmospheric Protection/Air Quality Control/Air Pollution
Electrodialysis with bipolar membrane
Environment, general
Fenton’s oxidation
Fuzzy logic
Industrial Pollution Prevention
landfill leachate
Modeling
Multiple regression
Waste Water Technology / Water Pollution Control / Water Management / Aquatic Pollution
L1  - files/333/Sari et al. - Fuzzy-logic modeling of Fenton’s strong chemical o.pdf
LA  - en
SN  - 0944-1344, 1614-7499
SP  - 1-19
ST  - Fuzzy-logic modeling of Fenton’s strong chemical oxidation process treating three types of landfill leachates
T2  - Environmental Science and Pollution Research
TI  - Fuzzy-logic modeling of Fenton’s strong chemical oxidation process treating three types of landfill leachates
UR  - http://link.springer.com/article/10.1007/s11356-012-1370-6
files/334/s11356-012-1370-6.html
Y2  - 2013/01/15/04:47:47
ID  - 332
ER  - 


TY  - JOUR
AB  - With acrylic acid (AA) and allylthiourea (AT) as the monomers, an “instantaneous” granular hydrogel was prepared using Fenton reagent as redox initiator under an ambient temperature in air atmosphere, and then characterized by means of Fourier transform infrared spectroscopy and scanning electron microscope. The obtained hydrogels were investigated as the adsorbents to remove Cu(II) and Ni(II) from the aqueous solution. The effects of operating parameters on the adsorption capacity were studied, including the composition ratio (AT:AA), contact time, pH and initial concentrations of heavy metal ions. The results indicate that the introduction of allylthiourea into the hydrogel can reduce greatly the swelling ratio, but with no significant variation in the adsorption capacity as the initial Cu(II) and Ni(II) concentrations lower than 400 and 200 mg/L, respectively. In addition, the adsorption capacity shows a pH-independence at pH ⩾ 4.0, and the adsorbed Cu(II) and Ni(II) can be partially desorbed using 0.01 mol/L HCl as the desorbent, rendering the as-prepared hydrogel good re-adsorption ability, especially for Cu(II). The applicability in real electroplating wastewater demonstrates that the as-prepared hydrogel with AT is promising for the removal of Cu(II) and Ni(II) for its comparable adsorption capacity with the hydrogel without AT.
AU  - Zheng, Yian
AU  - Wang, Aiqin
DA  - 2012/08/15/
DO  - 10.1016/j.cej.2012.06.115
DP  - ScienceDirect
J2  - Chemical Engineering Journal
KW  - Allylthiourea
Fenton reagent
Granular hydrogel
Heavy metals
Removal
L1  - files/728/Zheng and Wang - 2012 - Granular hydrogel initiated by Fenton reagent and .pdf
M1  - 0
PY  - 2012
SN  - 1385-8947
SP  - 601-610
ST  - Granular hydrogel initiated by Fenton reagent and their performance on Cu(II) and Ni(II) removal
T2  - Chemical Engineering Journal
TI  - Granular hydrogel initiated by Fenton reagent and their performance on Cu(II) and Ni(II) removal
UR  - http://www.sciencedirect.com/science/article/pii/S1385894712008455
files/727/S1385894712008455.html
VL  - 200–202
Y2  - 2013/01/16/06:34:39
ID  - 226
ER  - 


TY  - JOUR
AB  - Background, aim, scope Treatment of wastewater has become significant with the declining water resources. The presence of recalcitrant organics is the major issue in meeting the pollution control board norms in India. The theme of the present investigation was on partial or complete removal of pollutants or their transformation into less toxic and more biodegradable products by heterogeneous Fenton oxidation process using mesoporous activated carbon (MAC) as the catalyst. Materials and methods Ferrous sulfate (FeSO4·7H2O), sulfuric acid (36 N, specific gravity 1.81, 98% purity), hydrogen peroxide (50% v/v) and all other chemicals used in this study were of analytical grade (Merck). Two reactors, each of height 50 cm and diameter 6 cm, were fabricated with PVC while one reactor was packed with MAC of mass 150 g and other without MAC served as control. Results and discussion The oxidation process was presented with kinetic and thermodynamic constants for the removal of COD, BOD, and TOC from the wastewater. The activation energy (Ea) for homogeneous and heterogeneous Fenton oxidation processes were 44.79 and 25.89 kJ/mol, respectively. The thermodynamic parameters ΔG, ΔH, and ΔS were calculated for the oxidation processes using Van’t Hoff equation. Furthermore, the degradation of organics was confirmed through FTIR and UV–visible spectroscopy, and cyclic voltammetry. Conclusions The heterocatalytic Fenton oxidation process efficiently increased the biodegradability index (BOD/COD) of the tannery effluent. The optimized conditions for the heterocatalytic Fenton oxidation of organics in tannery effluent were pH 3.5, reaction time–4 h, and H2O2/FeSO4·7H2O in the molar ratio of 2:1.
AU  - Karthikeyan, S.
AU  - Priya, M. Ezhil
AU  - Boopathy, R.
AU  - Velan, M.
AU  - Mandal, A. B.
AU  - Sekaran, G.
DA  - 2012/06/01/
DO  - 10.1007/s11356-011-0691-1
DP  - link.springer.com
J2  - Environ Sci Pollut Res
KW  - Atmospheric Protection/Air Quality Control/Air Pollution
Environment, general
Heterogeneous Fenton oxidation
Homogeneous Fenton oxidation
Industrial Pollution Prevention
Kinetic study
Mesoporous activated carbon
Tannery wastewater
Waste Water Technology / Water Pollution Control / Water Management / Aquatic Pollution
L1  - files/374/Karthikeyan et al. - 2012 - Heterocatalytic Fenton oxidation process for the t.pdf
LA  - en
M1  - 5
PY  - 2012
SN  - 0944-1344, 1614-7499
SP  - 1828-1840
ST  - Heterocatalytic Fenton oxidation process for the treatment of tannery effluent
T2  - Environmental Science and Pollution Research
TI  - Heterocatalytic Fenton oxidation process for the treatment of tannery effluent: kinetic and thermodynamic studies
UR  - http://link.springer.com/article/10.1007/s11356-011-0691-1
files/375/s11356-011-0691-1.html
VL  - 19
Y2  - 2013/01/15/05:24:06
ID  - 333
ER  - 


TY  - JOUR
AB  - An experiment was conducted in a batch reactor for a real printing and dyeing wastewater pretreatment using Fenton process in this study. The results showed that original pH, hydrogen peroxide concentration and ferrous sulfate concentration affected ORP value and pretreatment efficacy greatly. Under experimental conditions, the optimal original pH was 6.61, and the optimal hydrogen peroxide and ferrous sulfate concentrations were 1.50 and 0.75 g L−1, respectively. The relationship among ORP, original pH, hydrogen peroxide concentration, ferrous sulfate concentration, and color (COD or BOD5/COD) was established, which would be instructive in on-line monitoring and control of Fenton process using ORP. In addition, the effects of wastewater temperature and oxidation time on pretreatment efficacy were also investigated. With an increase of temperature, color and COD removal efficiencies and BOD5/COD ratio increased, and they were in proportion to the exponent of temperature reciprocal. Similarly, color and COD removal efficiencies increased with increasing oxidation time, and both color and COD removal obeyed the first-order kinetics. The BOD5/COD ratio could be expressed by a second-degree polynomial with respect to oxidation time, and the best biodegradability of wastewater was present at the oxidation time of 6.10 h.
AU  - Wu, Huifang
AU  - Wang, Shihe
DA  - 2012/12//
DO  - 10.1016/j.jhazmat.2012.10.030
DP  - ScienceDirect
J2  - Journal of Hazardous Materials
KW  - Efficacy
Fenton process
Oxidation–reduction potential
Pretreatment
Printing and dyeing wastewater
L1  - files/645/Wu and Wang - 2012 - Impacts of operating parameters on oxidation–reduc.pdf
M1  - 0
PY  - 2012
SN  - 0304-3894
SP  - 86-94
ST  - Impacts of operating parameters on oxidation–reduction potential and pretreatment efficacy in the pretreatment of printing and dyeing wastewater by Fenton process
T2  - Journal of Hazardous Materials
TI  - Impacts of operating parameters on oxidation–reduction potential and pretreatment efficacy in the pretreatment of printing and dyeing wastewater by Fenton process
UR  - http://www.sciencedirect.com/science/article/pii/S0304389412010357
files/644/S0304389412010357.html
VL  - 243
Y2  - 2013/01/15/14:41:51
ID  - 227
ER  - 


TY  - JOUR
AB  - The effectiveness of the Fenton's reagent (H2O2/Fe2+) in the treatment of carpet dyeing wastewater was investigated under different operational conditions, namely, H2O2 and FeSO4 concentrations, initial pH and temperature. Up to 95% COD removal efficiency was attained using 5.5 g/l FeSO4 and 385 g/l H2O2 at a pH of 3, temperature of 50 °C. The H2O2/Fe2+ ratio (g/g) was found to be between 95 and 290 for maximum COD removal. It was noteworthy that, keeping H2O2/Fe2+ ratio constant within the range of 95–290, it became possible to decrease FeSO4 concentration to 1.1 g/l and H2O2 concentration to 96.3 g/l, still achieving nearly the same COD removal efficiency. The relative efficiencies of Fenton's oxidation and coagulation stages revealed that Fenton's coagulation removed organic compounds which were not removed by Fenton's oxidation, indicating that the Fenton's coagulation acted as a polishing step.
AU  - Gulkaya, İpek
AU  - Surucu, Gulerman A.
AU  - Dilek, Filiz B.
DA  - 2006/08/25/
DO  - 10.1016/j.jhazmat.2006.01.006
DP  - ScienceDirect
J2  - Journal of Hazardous Materials
KW  - Carpet dyeing wastewater
Fenton's coagulation
Fenton's oxidation
H2O2/Fe2+ ratio
L1  - files/140/Gulkaya et al. - 2006 - Importance of H2O2Fe2+ ratio in Fenton's treatmen.pdf
M1  - 3
PY  - 2006
SN  - 0304-3894
SP  - 763-769
ST  - Importance of H2O2/Fe2+ ratio in Fenton's treatment of a carpet dyeing wastewater
T2  - Journal of Hazardous Materials
TI  - Importance of H2O2/Fe2+ ratio in Fenton's treatment of a carpet dyeing wastewater
UR  - http://www.sciencedirect.com/science/article/pii/S0304389406000367
files/139/S0304389406000367.html
VL  - 136
Y2  - 2013/01/14/04:09:22
ID  - 228
ER  - 


TY  - JOUR
AB  - The applicability of Fenton's oxidation as an advanced treatment for chemical oxygen demand (COD) and color removal from anaerobically treated poultry manure wastewater was investigated. The raw poultry manure wastewater, having a pH of 7.30 (±0.2) and a total COD of 12,100 (±910) mg/L was first treated in a 15.7 L of pilot-scale up-flow anaerobic sludge blanket (UASB) reactor. The UASB reactor was operated for 72 days at mesophilic conditions (32 ± 2 °C) in a temperature-controlled environment with three different hydraulic retention times (HRT) of 15.7, 12 and 8.0 days, and with organic loading rates (OLR) between 0.650 and 1.783 kg COD/(m3 day). Under 8.0 days of HRT, the UASB process showed a remarkable performance on total COD removal with a treatment efficiency of 90.7% at the day of 63. The anaerobically treated poultry manure wastewater was further treated by Fenton's oxidation process using Fe2+ and H2O2 solutions. Batch tests were conducted on the UASB effluent samples to determine the optimum operating conditions including initial pH, effects of H2O2 and Fe2+ dosages, and the ratio of H2O2/Fe2+. Preliminary tests conducted with the dosages of 100 mg Fe2+/L and 200 mg H2O2/L showed that optimal initial pH was 3.0 for both COD and color removal from the UASB effluent. On the basis of preliminary test results, effects of increasing dosages of Fe2+ and H2O2 were investigated. Under the condition of 400 mg Fe2+/L and 200 mg H2O2/L, removal efficiencies of residual COD and color were 88.7% and 80.9%, respectively. Under the subsequent condition of 100 mg Fe2+/L and 1200 mg H2O2/L, 95% of residual COD and 95.7% of residual color were removed from the UASB effluent. Results of this experimental study obviously indicated that nearly 99.3% of COD of raw poultry manure wastewater could be effectively removed by a UASB process followed by Fenton's oxidation technology used as a post-treatment unit.
AU  - Yetilmezsoy, Kaan
AU  - Sakar, Suleyman
DA  - 2008/03/01/
DO  - 10.1016/j.jhazmat.2007.06.013
DP  - ScienceDirect
J2  - Journal of Hazardous Materials
KW  - COD removal
Fenton's oxidation
pH
Poultry manure wastewater
L1  - files/244/Yetilmezsoy and Sakar - 2008 - Improvement of COD and color removal from UASB tre.pdf
M1  - 2–3
PY  - 2008
SN  - 0304-3894
SP  - 547-558
ST  - Improvement of COD and color removal from UASB treated poultry manure wastewater using Fenton's oxidation
T2  - Journal of Hazardous Materials
TI  - Improvement of COD and color removal from UASB treated poultry manure wastewater using Fenton's oxidation
UR  - http://www.sciencedirect.com/science/article/pii/S030438940700859X
files/243/S030438940700859X.html
VL  - 151
Y2  - 2013/01/14/10:03:29
ID  - 229
ER  - 


TY  - JOUR
AB  - A combination of hydrodynamic cavitation and heterogeneous advanced Fenton process (AFP) based on the use of zero valent iron as the catalyst has been investigated for the treatment of real industrial wastewater. The effect of various operating parameters such as inlet pressure, temperature, and the presence of copper windings on the extent of mineralization as measured by total organic carbon (TOC) content have been studied with the aim of maximizing the extent of degradation. It has been observed that increased pressures, higher operating temperature and the absence of copper windings are more favourable for a rapid TOC mineralization. A new approach of latent remediation has also been investigated where hydrodynamic cavitation is only used as a pre-treatment with an aim of reducing the overall cost of pollutant degradation. It has been observed that approach of latent remediation works quite well with about 50–60% removal of TOC using only minimal initial treatment by hydrodynamic cavitation.
AU  - Chakinala, Anand G.
AU  - Gogate, Parag R.
AU  - Burgess, Arthur E.
AU  - Bremner, David H.
DA  - 2009/10/15/
DO  - 10.1016/j.cej.2009.05.018
DP  - ScienceDirect
J2  - Chemical Engineering Journal
KW  - Advanced Fenton process
Hydrodynamic cavitation
Industrial wastewater treatment
Iron metal catalyst
Latent remediation
L1  - files/639/Chakinala et al. - 2009 - Industrial wastewater treatment using hydrodynamic.pdf
M1  - 2–3
PY  - 2009
SN  - 1385-8947
SP  - 498-502
ST  - Industrial wastewater treatment using hydrodynamic cavitation and heterogeneous advanced Fenton processing
T2  - Chemical Engineering Journal
TI  - Industrial wastewater treatment using hydrodynamic cavitation and heterogeneous advanced Fenton processing
UR  - http://www.sciencedirect.com/science/article/pii/S1385894709003908
files/638/S1385894709003908.html
VL  - 152
Y2  - 2013/01/15/14:30:01
ID  - 230
ER  - 


TY  - JOUR
AB  - This study evaluated the effectiveness of Fenton's technique for the treatment of semi-aerobic landfill leachate collected from Pulau Burung Landfill Site (PBLS), Penang, Malaysia. The Fe2 + or Fe3 + as catalyst and H2O2 as oxidizing agent are commonly used for the classical Fenton's reaction. In present study, the effect of operating conditions such as pH, reaction time, molar ratio, agitation rate, feeding mode and Fenton reagent concentrations which are important parameters that affect the removal efficiencies of Fenton method were investigated. Under the most favorable conditions, the highest removals of 58.1 and 78.3% were observed for COD and color, respectively. In general, the best operating conditions were pH = 3, Fe = 560 mg L?1, H2O2 = 1020 mg L?1, H2O2/Fe2 + molar ratio = 3, agitation rate = 400 rpm and reaction time = 120 minutes. The results highlighted that stepwise addition of Fenton's reagent was more effective than adding the entire volume in a single step. Excessive hydrogen peroxide and iron have shown scavenging effects on hydroxyl radicals and reduced degradation of refractory organics in the landfill leachate.
AU  - Mohajeri, Soraya
AU  - Aziz, Hamidi Abdul
AU  - Isa, Mohamed Hasnain
AU  - Bashir, Mohammed J. K.
AU  - Mohajeri, Leila
AU  - Adlan, Mohd Nordin
DA  - 2010/03/17/
DO  - 10.1080/10934521003648883
J2  - Journal of Environmental Science and Health, Part A
L1  - files/456/10934521003648883.pdf
M1  - 6
N1  - <p>doi: 10.1080/10934521003648883</p>
The following values have no corresponding Zotero field:<br/>date: April 14, 2010<br/>DOI: doi: 10.1080/10934521003648883<br/>PB - Taylor & Francis<br/>
PY  - 2010
SN  - 1093-4529
SP  - 692-698
ST  - Influence of Fenton reagent oxidation on mineralization and decolorization of municipal landfill leachate
T2  - Journal of Environmental Science and Health, Part A
TI  - Influence of Fenton reagent oxidation on mineralization and decolorization of municipal landfill leachate
UR  - http://www.tandfonline.com/doi/abs/10.1080/10934521003648883
VL  - 45
Y2  - 2013/01/14/
ID  - 315
ER  - 


TY  - JOUR
AB  - In this work, an indirect method for estimating the total amount and concentration of oxidative radicals in aqueous and slurry-phase Fenton's systems was developed. This method, based on the use of benzoic acid as probe compound, was applied for evaluating the effect of the operating conditions on the radicals amount produced, their production efficiency (i.e. moles of radicals generated per mole H2O2) and their concentration. A Rotatable Central Composite design (RCC) was used to select the operating conditions in order to get a statistically meaningful data set. Hydrogen peroxide and ferrous ion concentrations ranged between 0.2–1 mM and 0.2–0.5 mM, respectively; humic acid concentration between 0 and 15 mg/L, whereas the soil/water weight ratio in slurry-phase systems between 1:10 and 9:10. The probe compound concentration was 9 or 0.1 mM in experiments aimed to evaluate the total amount or concentration of oxidative radicals, respectively. The obtained results indicated that the amount of radicals generated in both aqueous and soil slurry Fenton's system increased with higher H2O2 concentration and, more specifically, that their production efficiency increased with increasing Fe(II):H2O2 molar ratio. Addition of dissolved organic compounds as humic acid did not notably affect the oxidative radicals amount and concentration. On the contrary, a one order of magnitude reduction in both radicals amount generated and concentration was observed when soil was added to the reaction environment.
AU  - Ciotti, Cesare
AU  - Baciocchi, Renato
AU  - Tuhkanen, Tuula
DA  - 2009/01/15/
DO  - 10.1016/j.jhazmat.2008.03.137
DP  - ScienceDirect
J2  - Journal of Hazardous Materials
KW  - Fenton's system
Oxidative radicals
Rotatable Central Composite
Soil
L1  - files/325/Ciotti et al. - 2009 - Influence of the operating conditions on highly ox.pdf
M1  - 1
PY  - 2009
SN  - 0304-3894
SP  - 402-408
ST  - Influence of the operating conditions on highly oxidative radicals generation in Fenton's systems
T2  - Journal of Hazardous Materials
TI  - Influence of the operating conditions on highly oxidative radicals generation in Fenton's systems
UR  - http://www.sciencedirect.com/science/article/pii/S0304389408004986
files/324/S0304389408004986.html
VL  - 161
Y2  - 2013/01/15/04:38:31
ID  - 231
ER  - 


TY  - JOUR
AB  - The use of an integrated treatment scheme consisting of wet hydrogen peroxide catalytic oxidation (WHPCO) followed by two-stage upflow anaerobic sludge blanket (UASB) reactor (10 l each) for the treatment of olive mill wastewater was the subject of this study. The diluted wastewater (1:1) was pre-treated using Fenton's reaction. Optimum operating conditions namely, pH, H2O2 dose, Fe+2, COD:H2O2 ratio and Fe+2:H2O2 ratio were determined. The UASB reactor was fed continuously with the pre-treated wastewater. The hydraulic retention time was kept constant at 48 h (24 h for each stage). The conventional parameters such as COD, BOD, TOC, TKN, TP, TSS, oil and grease, and total phenols were determined. The concentrations of polyphenolic compounds in raw wastewater and effluents of each treatment step were measured using HPLC. The results indicated a good quality final effluent. Residual concentrations of individual organic compounds ranged from 0.432 mg l−1 for ρ-hydroxy-benzaldhyde to 3.273 mg l−1 for cinnamic acid.
AU  - El-Gohary, F. A.
AU  - Badawy, M. I.
AU  - El-Khateeb, M. A.
AU  - El-Kalliny, A. S.
DA  - 2009/03/15/
DO  - 10.1016/j.jhazmat.2008.06.098
DP  - ScienceDirect
J2  - Journal of Hazardous Materials
KW  - Anaerobic treatment
Biological treatment
Characterization
Chemical treatment
Olive mill waste
Wet hydrogen peroxide catalytic oxidation
L1  - files/621/El-Gohary et al. - 2009 - Integrated treatment of olive mill wastewater (OMW.pdf
M1  - 2–3
PY  - 2009
SN  - 0304-3894
SP  - 1536-1541
ST  - Integrated treatment of olive mill wastewater (OMW) by the combination of Fenton's reaction and anaerobic treatment
T2  - Journal of Hazardous Materials
TI  - Integrated treatment of olive mill wastewater (OMW) by the combination of Fenton's reaction and anaerobic treatment
UR  - http://www.sciencedirect.com/science/article/pii/S0304389408009308
files/620/S0304389408009308.html
VL  - 162
Y2  - 2013/01/15/14:19:09
ID  - 232
ER  - 


TY  - JOUR
AB  - The determination of atrazine in real samples (commercial pesticide preparations and water matrices) shows how the Fenton's reagent can be used with analytical purposes when kinetic methodology and multivariate calibration methods are applied. Also, binary mixtures of atrazine–alachlor and atrazine–bentazone in pesticide preparations have been resolved. The work shows the way in which interferences and the matrix effect can be modelled. Experimental design has been used to optimize experimental conditions, including the effect of solvent (methanol) used for extraction of atrazine from the sample. The determination of pesticides in commercial preparations was accomplished without any pre-treatment of sample apart from evaporation of solvent; the calibration model was developed for concentration ranges between 0.46 and 11.6 × 10−5 mol L−1 with mean relative errors under 4%. Solid-phase extraction is used for pre-concentration of atrazine in water samples through C18 disks, and the concentration range for determination was established between 4 and 115 μg L−1approximately. Satisfactory results for recuperation of atrazine were always obtained.
AU  - Ostra, Miren
AU  - Ubide, Carlos
AU  - Zuriarrain, Juan
DA  - 2007/02/12/
DO  - 10.1016/j.aca.2006.11.028
DP  - ScienceDirect
J2  - Analytica Chimica Acta
KW  - Atrazine
Experimental design
Fenton's reagent
Interference modelling
Pesticide binary mixtures
Solid-phase extraction
L1  - files/528/Ostra et al. - 2007 - Interference modelling, experimental design and pr.pdf
M1  - 1
PY  - 2007
SN  - 0003-2670
SP  - 228-235
ST  - Interference modelling, experimental design and pre-concentration steps in validation of the Fenton's reagent for pesticides determination
T2  - Analytica Chimica Acta
TI  - Interference modelling, experimental design and pre-concentration steps in validation of the Fenton's reagent for pesticides determination
UR  - http://www.sciencedirect.com/science/article/pii/S0003267006021611
files/527/S0003267006021611.html
VL  - 584
Y2  - 2013/01/15/09:46:34
ID  - 233
ER  - 


TY  - JOUR
AB  - In the Fenton reaction, degradation and dechlorination are directly affected by the concentrations of hydrogen peroxide and Fe3+. Although there is considerable research on the biodegradation of chlorinated compounds combined with the Fenton reaction, the kinetics of degradation and dechlorination of the reaction, with various concentrations of hydrogen peroxide and Fe3+, have been rarely investigated. Therefore, we investigated the degradation and dechlorination of PCE with various concentrations of hydrogen peroxide and Fe3+. The initial concentration of PCE (10 μM) decreased from a value of 8.9 μM (with 0.1 mM of hydrogen peroxide and 5 mM of Fe3+) to 1.1 μM (with 10 mM of hydrogen peroxide and 5 mM of Fe3+); the respective values for chloride ions produced were 0.9 and 21.6 μM. Also, the initial 10 μM of PCE decreased from 8.9 (with 0.1 mM of Fe3+ and 5 mM of hydrogen peroxide) to 2.2 μM (with 10mM of Fe3+ and 5 mM of hydrogen peroxide); the respective chloride ions produced were 0.7 and 14.5 μM. The logarithmic correlations between the degradation and dechlorination coefficients were 0.7682 and 0.7834 for concentrations of hydrogen peroxide and Fe3+, respectively. Both coefficients were used, from all possible cases, to derive six models which displayed both the ratio of degradation and dechlorination and the hydrogen peroxide and Fe3+ concentrations. The dechlorination of PCE could then be predicted with the model obtained by the coefficient with the concentration of hydrogen peroxide and Fe3+. The models could be applied to various Fenton reactions for optimization of degradation or dechlorination, such as biodegradation of PCE which is scarcely degraded by aerobic bacteria.
AU  - Kim, Hee-Sik
AU  - Lee, Wan-Suk
AU  - Ahn, Chi-Yong
AU  - Kim, Byung-Hyuk
AU  - Kim, Jang-Eok
AU  - Oh, Hee-Mock
DA  - 2010/11/01/
DO  - 10.1007/s11814-010-0304-6
DP  - link.springer.com
J2  - Korean J. Chem. Eng.
KW  - Biotechnology
Catalysis
Dechlorination Value
Degradation
Fenton reaction
Industrial Chemistry/Chemical Engineering
Kinetic Correlation
Materials Science, general
Perchloroethylene (PCE)
L1  - files/380/Kim et al. - 2010 - Kinetic correlation between degradation and dechlo.pdf
LA  - en
M1  - 6
PY  - 2010
SN  - 0256-1115, 1975-7220
SP  - 1750-1754
ST  - Kinetic correlation between degradation and dechlorination of perchloroethylene in the Fenton reaction
T2  - Korean Journal of Chemical Engineering
TI  - Kinetic correlation between degradation and dechlorination of perchloroethylene in the Fenton reaction
UR  - http://link.springer.com/article/10.1007/s11814-010-0304-6
files/381/s11814-010-0304-6.html
VL  - 27
Y2  - 2013/01/15/05:27:13
ID  - 334
ER  - 


TY  - JOUR
AB  - This work is first intended to optimize the experimental conditions for the maximum degradation of guaiacol (2-methoxyphenol) by Fenton’s reagent, and second, to improve the process efficiency through the use of solar radiation. Guaiacol is considered as a model compound of pulp and paper mill effluent. The experiments were carried out in a laboratory-scale reactor subjected or not to solar radiation. Hydrogen peroxide solution was continuously introduced into the reactor at a constant flow rate. The kinetics of organic matter decay was evaluated by means of the chemical oxygen demand (COD) and the absorbance measurements. The experimental results showed that the Fenton and solar photo-Fenton systems lead successfully to 90% elimination of COD and absorbance at 604 nm from a guaiacol solution under particular experimental conditions. The COD removal always obeyed a pseudo-first-order kinetics. The effect of pH, temperature, H2O2 dosing rate, initial concentration of Fe2+, and initial COD was investigated using the Fenton process. The solar photo-Fenton system needed less time and consequently less quantity of H2O2. Under the optimum experimental conditions, the solar photo-Fenton process needs a dose of H2O2 40% lower than that used in the Fenton process to remove 90% of COD.
AU  - Samet, Youssef
AU  - Wali, Ines
AU  - Abdelhédi, Ridha
DA  - 2011/11/01/
DO  - 10.1007/s11356-011-0514-4
DP  - link.springer.com
J2  - Environ Sci Pollut Res
KW  - Atmospheric Protection/Air Quality Control/Air Pollution
COD removal
Degradation kinetics
Environment, general
Fenton
Guaiacol
Industrial Pollution Prevention
Solar photo-Fenton
Waste Water Technology / Water Pollution Control / Water Management / Aquatic Pollution
L1  - files/348/Samet et al. - 2011 - Kinetic degradation of the pollutant guaiacol by d.pdf
LA  - en
M1  - 9
PY  - 2011
SN  - 0944-1344, 1614-7499
SP  - 1497-1507
ST  - Kinetic degradation of the pollutant guaiacol by dark Fenton and solar photo-Fenton processes
T2  - Environmental Science and Pollution Research
TI  - Kinetic degradation of the pollutant guaiacol by dark Fenton and solar photo-Fenton processes
UR  - http://link.springer.com/article/10.1007/s11356-011-0514-4
files/349/s11356-011-0514-4.html
VL  - 18
Y2  - 2013/01/15/05:06:16
ID  - 335
ER  - 


TY  - JOUR
AB  - A kinetic model is developed for the oxidation of phenolic compounds by Fenton's reagent. In the first stage a rigorous kinetic model is applied to calculate the different kinetic rate constants for the oxidation process of p-hydroxybenzoic acid. In a second phase a competitive method is applied to calculate these kinetic constants for another 10 phenolic compounds present in agroindustrial and pulp paper wastewaters. These 10 phenolic compounds were: β-resorcylic acid, 3-(4-hydroxyphenyl)-propionic acid, ferulic acid, protocatechuic acid, caffeic acid, p-coumaric acid, vanillic acid, syringic acid, veratric acid and 3,4,5-trimethoxybenzoic acid.
AU  - Beltran De Heredia, Jesus
AU  - Torregrosa, Joaquin
AU  - Dominguez, Joaquin R.
AU  - Peres, Jose A.
DA  - 2001/10//
DO  - 10.1016/s0045-6535(01)00056-x
DP  - ScienceDirect
J2  - Chemosphere
KW  - AOPs
Fenton's reagent
Kinetics
Phenolic compounds
p-hydroxybenzoic acid
L1  - files/525/Beltran De Heredia et al. - 2001 - Kinetic model for phenolic compound oxidation by F.pdf
M1  - 1
PY  - 2001
SN  - 0045-6535
SP  - 85-90
ST  - Kinetic model for phenolic compound oxidation by Fenton's reagent
T2  - Chemosphere
TI  - Kinetic model for phenolic compound oxidation by Fenton's reagent
UR  - http://www.sciencedirect.com/science/article/pii/S004565350100056X
files/524/S004565350100056X.html
VL  - 45
Y2  - 2013/01/15/09:46:34
ID  - 234
ER  - 


TY  - JOUR
AB  - In this paper, experimental data are presented to test and to validate a kinetic model for the oxidation of organic compound in dilute aqueous solution by the Fe(III)/H2O2 process in a batch reactor (NaClO4/HClO4 solutions, Ionic strength: I=0.1 M, pH≤3.0, 25.0°C). Atrazine was used as a model compound. Under the conditions employed in this study ([Atrazine]o&lt;1 μM), the OH radical was the unique species responsible for the oxidation of atrazine. Propagation and termination reactions involving organic radicals were assumed to be of little importance and were not incorporated in the model. The data showed that the effects of pH (pH range: 1–3) and of the concentrations of reactants ([H2O2]o and [Fe(III)]o) on the rates of oxidation of atrazine and of decomposition of hydrogen peroxide were in good agreement with model predictions. The concentration-time profiles for transient species (Fe(II), HO2/O−2 and OH radicals) obtained by computer calculations were also useful to explain the lag period and the pseudo-first order decay which were observed on the experimental kinetic curves of degradation of atrazine
AU  - Gallard, H.
AU  - De Laat, J.
DA  - 2000/08/15/
DO  - 10.1016/s0043-1354(00)00074-9
DP  - ScienceDirect
J2  - Water Research
KW  - aqueous solution
Atrazine
Fenton’s reagent
ferric ion
Hydrogen peroxide
Hydroxyl radical
Kinetics
L1  - files/134/Gallard and De Laat - 2000 - Kinetic modelling of Fe(III)H2O2 oxidation reacti.pdf
M1  - 12
PY  - 2000
SN  - 0043-1354
SP  - 3107-3116
ST  - Kinetic modelling of Fe(III)/H2O2 oxidation reactions in dilute aqueous solution using atrazine as a model organic compound
T2  - Water Research
TI  - Kinetic modelling of Fe(III)/H2O2 oxidation reactions in dilute aqueous solution using atrazine as a model organic compound
UR  - http://www.sciencedirect.com/science/article/pii/S0043135400000749
files/133/S0043135400000749.html
VL  - 34
Y2  - 2013/01/14/03:57:30
ID  - 235
ER  - 


TY  - JOUR
AU  - Wu, H.
AU  - Fan, M. M.
AU  - Li, C. F.
AU  - Peng, M.
AU  - Sheng, L. J.
AU  - Pan, Q.
AU  - Song, G. W.
DA  - 2010/07//
DO  - 10.2166/wst.2010.170
DP  - CrossRef
L1  - files/404/062010001.pdf
M1  - 1
PY  - 2010
SN  - 0273-1223
ST  - Kinetic studies on the degradation of crystal violet by the Fenton oxidation process
T2  - Water Science & Technology
TI  - Kinetic studies on the degradation of crystal violet by the Fenton oxidation process
UR  - http://login.oaresciences.org/whalecomwww.iwaponline.com/whalecom0/scripts/dtSearch/dtisapi6.dll?cmd=getdoc&DocId=17196&Index=E%3a%5cdtIndex%5cIW%5fWST&HitCount=4&hits=15e+16d+191+192+&SearchForm=D%3a%5ciwaponline%5csearch%5csearch%2ehtm
files/403/dtisapi6.html
VL  - 62
Y2  - 2013/01/15/06:19:25
ID  - 347
ER  - 


TY  - JOUR
AB  - Synthetic solutions of phenol, o-, m- and p-cresol were oxidised by using Fenton’s reagent. The application of substoichiometric dosage of H2O2 led to the formation of intermediate compounds, continuing later the oxidation to complete oxidation. An important objective was to analyze the effect of hydrogen peroxide dosage applied and the reaction pH together with the iron oxidation state on the degradation level. A kinetic model was derived from a reaction mechanism postulated which was used to analyze the results of the experiments. Another aim was to analyze the hydrogen peroxide consumption. Noteworthy results include an increase in oxidant consumption to intensify phenol removal. Furthermore, oxidant consumption was analyzed through the ratio H2O2 to phenol removed and the average specific rate of removal (ASRR). By analyzing these two parameters it has been possible to ascertain the most favorable strategy for an efficient application of H2O2.
AU  - Luis, Ana de
AU  - Lombraña, José Ignacio
AU  - Varona, Fernando
AU  - Menéndez, Amaia
DA  - 2009/01/01/
DO  - 10.1007/s11814-009-0009-x
DP  - link.springer.com
J2  - Korean J. Chem. Eng.
KW  - Biotechnology
Catalysis
Cresols
Fenton
Hydrogen peroxide
Industrial Chemistry/Chemical Engineering
Materials Science, general
Phenol
L1  - files/377/Luis et al. - 2009 - Kinetic study and hydrogen peroxide consumption of.pdf
LA  - en
M1  - 1
PY  - 2009
SN  - 0256-1115, 1975-7220
SP  - 48-56
ST  - Kinetic study and hydrogen peroxide consumption of phenolic compounds oxidation by Fenton’s reagent
T2  - Korean Journal of Chemical Engineering
TI  - Kinetic study and hydrogen peroxide consumption of phenolic compounds oxidation by Fenton’s reagent
UR  - http://link.springer.com/article/10.1007/s11814-009-0009-x
files/378/s11814-009-0009-x.html
VL  - 26
Y2  - 2013/01/15/05:25:23
ID  - 336
ER  - 


TY  - JOUR
AU  - Banerjee, P.
AU  - DasGupta, S.
AU  - De, S.
DA  - 2008
L1  - files/750/71017038-Kinetic-Study-of-Advanced-Oxidation-of-Eosin-Dye.pdf
M1  - 1
PY  - 2008
ST  - Kinetic Study of Advanced Oxidation of Eosin Dye by Fenton's Reagent
T2  - International Journal of Chemical Reactor Engineering
TI  - Kinetic Study of Advanced Oxidation of Eosin Dye by Fenton's Reagent
VL  - 6
ID  - 304
ER  - 


TY  - JOUR
AB  - The aim of this study is to provide fundamental knowledge of the treatment of wastewater containing a non-biodegradable reactive dye (C.I. Reactive Blue 19) and/or other anthraquinone dyes by catalytic effects of iron salt known as Fenton's reagent. As an advanced oxidation method, Fenton's reagent has an advantage that it combines both oxidation and coagulation processes. The influence of the main operating parameters such as iron sulfate and hydrogen peroxide doses, solution pH, temperature, initial dye concentration and presence of different concentrations of sodium chloride and sodium sulfate has been studied systematically at a laboratory scale. The obtained results showed that the best pH value for decolorization of dye solution is 3. An increase in temperature resulted in higher removal rates. Results showed that chloride and sulfate ions have a negative impact on the decolorization of RB19 by Fenton oxidation. The increase of Fe2+ and H2O2 doses accelerated the color and COD removals until a point where further addition of Fe2+ or H2O2 became inefficient and unnecessary. A new empirical kinetic model for investigation of decolorization based on simultaneous first and second-order kinetics was derived and compared to individual first- and second-order kinetic models. The results of the mixed-order kinetics showed excellent correlation with experimental data.
AU  - Emami, F.
AU  - Tehrani-Bagha, A. R.
AU  - Gharanjig, K.
AU  - Menger, F. M.
DA  - 2010/07//
DO  - 10.1016/j.desal.2010.02.035
DP  - ScienceDirect
J2  - Desalination
KW  - Catalytic degradation
Empirical kinetic model
Iron salt
Reactive dye
L1  - files/612/Emami et al. - 2010 - Kinetic study of the factors controlling Fenton-pr.pdf
M1  - 1–3
PY  - 2010
SN  - 0011-9164
SP  - 124-128
ST  - Kinetic study of the factors controlling Fenton-promoted destruction of a non-biodegradable dye
T2  - Desalination
TI  - Kinetic study of the factors controlling Fenton-promoted destruction of a non-biodegradable dye
UR  - http://www.sciencedirect.com/science/article/pii/S0011916410001128
files/611/S0011916410001128.html
VL  - 257
Y2  - 2013/01/15/14:16:02
ID  - 236
ER  - 


TY  - JOUR
AB  - Kinetic study on COD removal from palm oil refinery effluent (PORE) has been studied by using UV-Fenton's reagent. The wastewater was collected from a refinery mill in Penang, Malaysia and treated using batch reactor with UV-lamp. The concentration of H2O2 was 2.125 g and ratio of H2O2:FeSO4·7H2O was 15:1. The results show that the reaction of the oxidation of COD in PORE by UV-Fenton's reagent is second order reaction and the reaction rate constant, k is 2.24, 1.92 and 1.60 dm3/mol·min for temperature 24 °C, 30 °C and 40 °C, respectively.
AU  - Leong, Soo Kwan
AU  - Bashah, Nur Alwani Ali
DA  - 2012
DO  - 10.1016/j.apcbee.2012.06.037
DP  - ScienceDirect
J2  - APCBEE Procedia
KW  - batch
COD
Kinetic study
PORE
UV-Fenton
L1  - files/588/Leong and Bashah - 2012 - Kinetic Study on COD Removal of Palm Oil Refinery .pdf
M1  - 0
PY  - 2012
SN  - 2212-6708
SP  - 6-10
ST  - 2nd International Conference on Chemistry and Chemical Process (ICCCP 2012) May 5-6, 2012
T2  - APCBEE Procedia
TI  - Kinetic Study on COD Removal of Palm Oil Refinery Effluent by UV-Fenton
UR  - http://www.sciencedirect.com/science/article/pii/S221267081200108X
files/587/S221267081200108X.html
VL  - 3
Y2  - 2013/01/15/13:53:19
ID  - 237
ER  - 


TY  - JOUR
AB  - A detailed kinetic model was developed for the degradation of p-nitroaniline (PNA) by Fenton oxidation. Batch experiments were carried out to investigate the role of pH, hydrogen peroxide and Fe2+ levels, PNA concentration and the temperature. The kinetic rate constants, kap, for PNA degradation at different reaction conditions were determined. The test results show that the decomposition of PNA proceeded rapidly only at pH value of 3.0. Increasing the dosage of H2O2 and Fe2+ enhanced the kap of PNA degradation. However, higher levels of H2O2 also inhibited the reaction kinetics. The kap of PNA degradation decreased with the increase of initial PNA concentration, but increased with the increase of temperature. Based on the rate constants obtained at different temperatures, the empirical Arrhenius expression of PNA degradation was derived. The derived activation energy for PNA degradation by Fenton oxidation is 53.96 kJ mol−1.
AU  - Sun, Jian-Hui
AU  - Sun, Sheng-Peng
AU  - Fan, Mao-Hong
AU  - Guo, Hui-Qin
AU  - Qiao, Li-Ping
AU  - Sun, Rui-Xia
DA  - 2007/09/05/
DO  - 10.1016/j.jhazmat.2007.02.022
DP  - ScienceDirect
J2  - Journal of Hazardous Materials
KW  - Advanced oxidation processes (AOPs)
Arrhenius expression
Fenton process
Hydroxyl radical
Kinetics
p-Nitroaniline
L1  - files/164/Sun et al. - 2007 - A kinetic study on the degradation of p-nitroanili.pdf
M1  - 1–2
PY  - 2007
SN  - 0304-3894
SP  - 172-177
ST  - A kinetic study on the degradation of p-nitroaniline by Fenton oxidation process
T2  - Journal of Hazardous Materials
TI  - A kinetic study on the degradation of p-nitroaniline by Fenton oxidation process
UR  - http://www.sciencedirect.com/science/article/pii/S0304389407002440
files/163/S0304389407002440.html
VL  - 148
Y2  - 2013/01/14/04:20:24
ID  - 174
ER  - 


TY  - JOUR
AB  - A kinetic model for the decolorization of C.I. Reactive Black 5 by the combination of hydrogen peroxide and UV radiation was developed based on experimental results and known chemical and photochemical reactions. The observed kinetic reaction coefficient was determined and correlated as a function of hydrogen peroxide concentration and UV intensity. The validity of the rate expression was tested experimentally in a parameterization study. The decolorization rate follows pseudo-first order kinetics with respect to dye concentration. The rate increases linearly with UV intensity and nonlinearly with increasing hydrogen peroxide concentration, going from a linear relationship at low H2O2 concentrations to a maximum as hydrogen peroxide concentration continues to increase. The decolorization rate expression derived from the proposed reaction mechanism was reconciled with that used for correlating the experimental data.
AU  - Mohey El-Dein, A.
AU  - Libra, J. A.
AU  - Wiesmann, U.
DA  - 2003/08//
DO  - 10.1016/s0045-6535(03)00226-1
DP  - ScienceDirect
J2  - Chemosphere
KW  - Advanced oxidation process
H2O2
Kinetic model
Reactive azo dye
UV intensity
L1  - files/715/Mohey El-Dein et al. - 2003 - Mechanism and kinetic model for the decolorization.pdf
M1  - 6
PY  - 2003
SN  - 0045-6535
SP  - 1069-1077
ST  - Mechanism and kinetic model for the decolorization of the azo dye Reactive Black 5 by hydrogen peroxide and UV radiation
T2  - Chemosphere
TI  - Mechanism and kinetic model for the decolorization of the azo dye Reactive Black 5 by hydrogen peroxide and UV radiation
UR  - http://www.sciencedirect.com/science/article/pii/S0045653503002261
files/714/S0045653503002261.html
VL  - 52
Y2  - 2013/01/15/16:11:36
ID  - 238
ER  - 


TY  - JOUR
AB  - We compared two H2O2 oxidation methods for the treatment of industrial wastewater: oxidation using Fenton's reagent [H2O2/Fe(II)] and microwave irradiation. Both methods were applied to the treatment of synthetic phenol solutions (100 mg L−1) and of an industrial effluent containing a mixture of ionic and non-ionic surfactants at high load (20 g L−1 of COD). The effects of initial pH, initial H2O2 concentration, Fenton catalyst amount and irradiation time were assessed. According to the oxidation of phenol, it has been found that the oxidation by Fenton's reagent is dependent on the pH, contrary to the microwave system, which is not influenced by this parameter. For both systems, a limiting amount of oxidant has been found; above this point the oxidation of phenol is not improved by a further addition of peroxide. The oxidation of the industrial surfactant effluent has only been successful with the Fenton's reagent. In this case, large amounts of ferrous ions are necessary for the precipitation of the ionic surfactants of the effluent, followed by the oxidation of the non-ionic constituents of the solution.
AU  - Sanz, J.
AU  - Lombraña, J. I.
AU  - Luis, A. M. De
AU  - Ortueta, M.
AU  - Varona, F.
DA  - 2003/03/01/
DO  - 10.1007/s10311-002-0007-2
DP  - link.springer.com
J2  - Environ Chem Lett
KW  - Advanced oxidation processes (AOPs)
Fenton's reagent
Hydrogen peroxide
Microwave irradiation
Oxidant efficiency
Phenol and surfactants
L1  - files/288/Sanz et al. - 2003 - Microwave and Fenton's reagent oxidation of wastew.pdf
LA  - en
M1  - 1
PY  - 2003
SN  - 1610-3653, 1610-3661
SP  - 45-50
ST  - Microwave and Fenton's reagent oxidation of wastewater
T2  - Environmental Chemistry Letters
TI  - Microwave and Fenton's reagent oxidation of wastewater
UR  - http://link.springer.com/article/10.1007/s10311-002-0007-2
files/289/s10311-002-0007-2.html
VL  - 1
Y2  - 2013/01/15/04:02:29
ID  - 337
ER  - 


TY  - JOUR
AB  - A simplified pseudokinetic model to predict the mineralization evolution of organic pollutants by Fenton's reagent (FR) has been developed. The model has been validated by fitting phenol oxidation data by using FR in a batch way but could be applied to other wastewaters. The proposed model can be applied to the whole range of hydrogen peroxide dosage, values lower than those theoretically required for total mineralization or excess. To do this the model takes into account the change in the hydrogen peroxide concentration. Moreover, the model is able to explain and predict the asymptotic value obtained for mineralization of the initial TOC due to the complexation of the catalyst (iron cation) with chelating oxidation intermediates. Finally, the model can optimize the dosage of hydrogen peroxide in order to avoid the loss of this reagent.
AU  - Santos, A.
AU  - Yustos, P.
AU  - Rodríguez, S.
AU  - Romero, A.
DA  - 2010/04/15/
DO  - 10.1016/j.cattod.2010.02.022
DP  - ScienceDirect
J2  - Catalysis Today
KW  - Fenton's reagent
Hydrogen peroxide
Kinetic model
Mineralization
L1  - files/64/Kinetic of fanton.pdf
files/63/Santos et al. - 2010 - Mineralization lumping kinetic model for abatement.pdf
M1  - 1–2
PY  - 2010
SN  - 0920-5861
SP  - 89-93
ST  - 2nd European Conference on Environmental Applications of Advanced Oxidation Processes(EAAOP-2).
T2  - Catalysis Today
TI  - Mineralization lumping kinetic model for abatement of organic pollutants using Fenton's reagent
UR  - http://www.sciencedirect.com/science/article/pii/S0920586110001070
files/62/S0920586110001070.html
VL  - 151
Y2  - 2013/01/09/09:07:00
ID  - 239
ER  - 


TY  - JOUR
AB  - Pre-treatment of simulated industrial wastewaters (SIM1, SIM2 and SIM3) containing organic and inorganic compounds (1,2-dichloroethane, sodium formate, sodium hydrogen carbonate, sodium carbonate and sodium chloride) by oxidative degradation using homogeneous Fenton type processes (Fe2+/H2O2 and Fe3+/H2O2) has been evaluated. The effects of initial Fe2+ and Fe3+ concentrations, [Fe2+/3+], type of iron salt (ferrous sulfate vs. ferric chloride), initial hydrogen peroxide concentration, [H2O2], on mineralization extent, i.e., total organic content (TOC) removal, were studied. Response surface methodology (RSM), particularly Box–Behnken design (BBD) was used as modelling tool, and obtained predictive function was used to optimize the overall process by the means of desirability function approach (DFA). Up to 94% of initial TOC was removed after 120 min. Ferrous sulfate was found to be the most appropriate reagent, and the optimal doses of Fe2+ and H2O2 for reducing the pollutant content, in terms of final TOC and sludge production were assessed.
AU  - Grčić, Ivana
AU  - Vujević, Dinko
AU  - Šepčić, Josip
AU  - Koprivanac, Natalija
DA  - 2009/10/30/
DO  - 10.1016/j.jhazmat.2009.05.060
DP  - ScienceDirect
J2  - Journal of Hazardous Materials
KW  - Advanced oxidation processes (AOPs)
Box–Behnken design (BBD)
Desirability function approach (DFA)
Fenton type processes
Industrial wastewater treatment
L1  - files/167/Grčić et al. - 2009 - Minimization of organic content in simulated indus.pdf
M1  - 2–3
PY  - 2009
SN  - 0304-3894
SP  - 954-961
ST  - Minimization of organic content in simulated industrial wastewater by Fenton type processes
T2  - Journal of Hazardous Materials
TI  - Minimization of organic content in simulated industrial wastewater by Fenton type processes: A case study
UR  - http://www.sciencedirect.com/science/article/pii/S0304389409008139
files/166/S0304389409008139.html
VL  - 170
Y2  - 2013/01/14/04:28:02
ID  - 240
ER  - 


TY  - JOUR
AB  - Atrazine (ATZ), 2-chloro-4-(ethylamino)-6-(isopropylamino)-s-triazine, was effectively degraded by hydroxyl radicals that were generated by FeII/H2O2 in the Fenton's process. Up to 98% ATZ removal can be achieved in the process if the doses of FeII and H2O2 are selected appropriately. Oxidation capacity of the process was successfully predicted through a kinetic approach with three simple and measurable parameters (i.e., two rate constants and a break point time), which makes the model useful in predicting, controlling and optimizing the degradation of ATZ. In addition, the transformation pathways of ATZ decay was successfully investigated by using a novel technology, liquid chromatography electrospray tandem mass spectrometry (LC/ESI-MS/MS). Ten intermediates were identified in the process. The alkylic-oxidation followed by dealkylation and/or dechlorination–hydroxylation were found to be the major pathways of the decay of ATZ in Fenton's process. All the detected intermediates were found to be dealkylated in different levels or positions. The dealkylated species may be further dechlorinated but generally at a lower fraction (&lt;10%) due to the depletion of oxidants.
AU  - Chan, K. H.
AU  - Chu, W.
DA  - 2005/02/14/
DO  - 10.1016/j.jhazmat.2004.11.008
DP  - ScienceDirect
J2  - Journal of Hazardous Materials
KW  - Atrazine
Catalyzed oxidation
Fenton
Ferrous
Hydrogen peroxide
Intermediates
Model
L1  - files/125/Chan and Chu - 2005 - Model applications and mechanism study on the degr.pdf
M1  - 1–3
PY  - 2005
SN  - 0304-3894
SP  - 227-237
ST  - Model applications and mechanism study on the degradation of atrazine by Fenton's system
T2  - Journal of Hazardous Materials
TI  - Model applications and mechanism study on the degradation of atrazine by Fenton's system
UR  - http://www.sciencedirect.com/science/article/pii/S0304389404005680
files/124/S0304389404005680.html
VL  - 118
Y2  - 2013/01/14/03:57:30
ID  - 241
ER  - 


TY  - JOUR
AB  - Anodic Fenton treatment (AFT) has been shown to be effective in removing pesticides from aqueous solution in batch reactors with the formation of less toxic and more biodegradable products. To facilitate practical application of AFT, carbaryl degradation in a continuously stirred tank reactor (CSTR) by AFT was investigated under different experimental conditions, such as carbaryl inlet concentration, Fenton reagent concentration/ratio, and carbaryl feeding flow rate. A higher Fe2+ delivery rate and H2O2 to Fe2+ ratio (H2O2:Fe2+) were found to favor the carbaryl degradation process, whereas flow rate was shown to be a much less significant factor to influence the degradation rate under the evaluated experimental conditions. A kinetic-based semiempirical model was developed to simulate the experimental data, and a very good fit between the model and the raw data was found (R2 > 0.99). A dimensionless parameter (k/q2) was found to be a good indicator of the degradation rate; that is, the higher the k/q2value is, the faster the degradation process is. The rate parameter (k) can be used to evaluate the degradation rate when the flow rate is invariant for a given pesticide. The shape parameter (?) is most likely related to the availability and reactivity of Fenton reagents and hydroxyl radicals. To compare the degradation rate of different pesticides, more information other than k/q2, k, and ? values, such as the instantaneous degradation rate vs time relationship, needs to be considered. Keywords: Carbaryl; pesticides; degradation; CSTR; Fenton reaction; kinetics
AU  - Kong, Lingjun
AU  - Lemley, Ann T.
DA  - 2006/12/01/
DO  - 10.1021/jf062110g
DP  - ACS Publications
J2  - J. Agric. Food Chem.
L1  - files/678/Kong and Lemley - 2006 - Modeling Evaluation of Carbaryl Degradation in a C.pdf
M1  - 26
PY  - 2006
SN  - 0021-8561
SP  - 10061-10069
ST  - Modeling Evaluation of Carbaryl Degradation in a Continuously Stirred Tank Reactor by Anodic Fenton Treatment
T2  - Journal of Agricultural and Food Chemistry
TI  - Modeling Evaluation of Carbaryl Degradation in a Continuously Stirred Tank Reactor by Anodic Fenton Treatment
UR  - http://dx.doi.org/10.1021/jf062110g
files/679/jf062110g.html
VL  - 54
Y2  - 2013/01/15/15:20:27
ID  - 305
ER  - 


TY  - JOUR
AB  - The degradation of humic acid (HA) was carried out in the presence of the Fenton reagent. The experiments demonstrated that HA was removed by oxidation and coagulation. Moreover, the oxidation occurred mainly at the first 60 min and predominated the HA removal efficiency. A new kinetic model was established according to the generally accepted mechanism of high active OH oxidation in order to well describe the Fenton oxidation reaction in HA aqueous solution. The model embraced two key operating factors affecting the HA degradation in Fenton process, including the dosages of hydrogen peroxide and ferrous ion. The experimental data were fitted by using the most commonly used first- and the second- order reaction models and the new model, respectively. The goodness of fittings demonstrated that the new model could better fit the experimental data than the other two models, which indicated that this analytical model could better describe the kinetics of Fenton reaction mathematically and chemically. Results indicated that the oxidation rate and removal efficiency were strongly dependent on initial pH, initial concentration of Fenton reagents, initial HA concentration and reaction temperature. The experiments demonstrated that hydrogen peroxide and ferrous ion would approach their saturated value with increasing dosage.
AU  - Wu, Yanyu
AU  - Zhou, Shaoqi
AU  - Qin, Fanghui
AU  - Zheng, Ke
AU  - Ye, Xiuya
DA  - 2010/07/15/
DO  - 10.1016/j.jhazmat.2010.03.036
DP  - ScienceDirect
J2  - Journal of Hazardous Materials
KW  - Fenton
Humic acid
Kinetic model
Oxdiation
L1  - files/128/Wu et al. - 2010 - Modeling the oxidation kinetics of Fenton's proces.pdf
M1  - 1–3
PY  - 2010
SN  - 0304-3894
SP  - 533-539
ST  - Modeling the oxidation kinetics of Fenton's process on the degradation of humic acid
T2  - Journal of Hazardous Materials
TI  - Modeling the oxidation kinetics of Fenton's process on the degradation of humic acid
UR  - http://www.sciencedirect.com/science/article/pii/S0304389410003420
files/127/S0304389410003420.html
VL  - 179
Y2  - 2013/01/14/03:57:30
ID  - 242
ER  - 


TY  - JOUR
AB  - The degradation of pesticide, atrazine (ATZ), 2-chloro-4-(ethylamino)-6-(isopropylamino)-s-triazine, by Fenton’s reagent (FR) was investigated as a function of reagents’ concentrations and ratios in a batch reactor. The degradation of ATZ was effectively achieved by hydroxyl radicals, which were generated in the FR process. The decay rates of ATZ and the oxidation capacities of FR were found to depend on the concentrations of hydrogen peroxide and ferrous ion. The removal kinetics of ATZ are initiated by a rapid decay and then followed by a much slower one. After an extended reaction time (5–10 min), the reactions ceased because the Fe(II) and H2O2 were consumed and would be deactivated in the process. A mathematical model was successfully developed to describe the two-stage reaction kinetics by using two simple but critical parameters: the initial ATZ decay rate and the final oxidation capacity of Fenton’s process. In general, higher [Fe(II)] or H2O2 concentrations result in faster initial decay rate and higher oxidation capacity. However, the oxidation capacity is more sensitive to the initial [Fe(II)] due to the presence of side reactions as discussed in the paper.
AU  - Chan, K. H.
AU  - Chu, W.
DA  - 2003/04//
DO  - 10.1016/s0045-6535(02)00812-3
DP  - ScienceDirect
J2  - Chemosphere
KW  - Atrazine
Fenton’s reagent
Ferrous
Hydrogen peroxide
Oxidation
L1  - files/131/Chan and Chu - 2003 - Modeling the reaction kinetics of Fenton’s process.pdf
M1  - 4
PY  - 2003
SN  - 0045-6535
SP  - 305-311
ST  - Modeling the reaction kinetics of Fenton’s process on the removal of atrazine
T2  - Chemosphere
TI  - Modeling the reaction kinetics of Fenton’s process on the removal of atrazine
UR  - http://www.sciencedirect.com/science/article/pii/S0045653502008123
files/130/S0045653502008123.html
VL  - 51
Y2  - 2013/01/14/03:57:30
ID  - 243
ER  - 


TY  - JOUR
AB  - In this work, a simple kinetic model was used to study the azo dye Orange II (O-II) degradation using Fenton’s reagent, in the Fenton-like stage. The effects of pH, temperature, Cl− concentration and initial concentrations of O-II, hydrogen peroxide (H2O2) and ferrous ion catalyst (Fe2+) on the degradation rate have been investigated in a batch reactor. The apparent kinetic constants, kap, for O-II degradation were determined in the following ranges of experimental conditions: 2.0 ≤ pH ≤ 4.0, 283 K ≤ T ≤ 323 K, 0   M ≤ C C l − ≤ 1 × 10 − 2   M , 3 × 10 − 5   M ≤ C OI I o ≤ 1 × 10 − 4   M , 1 × 10 − 4   M ≤ C H 2 O 2   o ≤ 1 × 10 − 3   M and 2.5 × 10 − 6   M ≤ C F e o 2 + ≤ 2 × 10 − 5   M . A pseudo first-order reaction rate with respect to O-II concentration was found to be adequate to fit the data in these experiments, in which kap depends on the initial conditions following a power-law dependency (at optimum pH of 3 and absence of chloride ions). This equation, without further fitting parameters, was successfully used to validate experiments performed in a continuous stirred tank reactor (CSTR). The ability of the model predictions was also checked by performing experiments in the CSTR out of the above-mentioned ranges (used for the kinetic study).
AU  - Ramirez, J. Herney
AU  - Duarte, Filipa M.
AU  - Martins, F. G.
AU  - Costa, Carlos A.
AU  - Madeira, Luis M.
DA  - 2009/05/15/
DO  - 10.1016/j.cej.2008.09.012
DP  - ScienceDirect
J2  - Chemical Engineering Journal
KW  - Fenton’s reagent
Hydrogen peroxide
Kinetics
Orange II
Oxidation
L1  - files/615/Ramirez et al. - 2009 - Modelling of the synthetic dye Orange II degradati.pdf
M1  - 2–3
PY  - 2009
SN  - 1385-8947
SP  - 394-404
ST  - Modelling of the synthetic dye Orange II degradation using Fenton’s reagent
T2  - Chemical Engineering Journal
TI  - Modelling of the synthetic dye Orange II degradation using Fenton’s reagent: From batch to continuous reactor operation
UR  - http://www.sciencedirect.com/science/article/pii/S1385894708005810
files/614/S1385894708005810.html
VL  - 148
Y2  - 2013/01/15/14:16:02
ID  - 244
ER  - 


TY  - JOUR
AB  - Physicochemical processes have been used to remove nonbiodegradable organic compounds in leachate generated from sanitary landfills. In this study, a coagulation process combined with Fenton oxidation was evaluated for the removal of refractory organics in leachate. Recycling of sludge generated from Fenton oxidation to a coagulation process was attempted to reduce operation cost and to improve organic removal rate. The addition mode of Fenton reagent was also modified to obtain a better organic removal rate and more cost-effective operation. With Fenton sludge recycling, 9% higher COD removal was obtained, and the sludge to be disposed could be reduced up to 50%. Also, the coagulant could be reduced by 50%. For Fenton oxidation process, stepwise addition of reagents gave a 5% higher COD removal, and a 25% reduction in chemical consumption.
AU  - Yoo, Hee-Chan
AU  - Cho, Soon-Haing
AU  - Ko, Seok-Oh
DA  - 2001/02/01/
DO  - 10.1081/ese-100000470
J2  - Journal of Environmental Science and Health, Part A
L1  - files/447/ese-100000470.pdf
M1  - 1
N1  - <p>doi: 10.1081/ESE-100000470</p>
The following values have no corresponding Zotero field:<br/>DOI: doi: 10.1081/ESE-100000470<br/>PB - Taylor & Francis<br/>
PY  - 2001
SN  - 1093-4529
SP  - 39-48
ST  - MODIFICATION OF COAGULATION AND FENTON OXIDATION PROCESSES FOR COST-EFFECTIVE LEACHATE TREATMENT
T2  - Journal of Environmental Science and Health, Part A
TI  - MODIFICATION OF COAGULATION AND FENTON OXIDATION PROCESSES FOR COST-EFFECTIVE LEACHATE TREATMENT
UR  - http://www.tandfonline.com/doi/abs/10.1081/ESE-100000470
VL  - 36
Y2  - 2013/01/14/
ID  - 317
ER  - 


TY  - JOUR
AU  - Chakinala, A. G.
AU  - Bremner, D. H.
AU  - Burgess, A. E.
AU  - Namkung, K. C.
DA  - 2007/06//
DO  - 10.2166/wst.2007.390
DP  - CrossRef
L1  - files/413/055120059.pdf
M1  - 12
PY  - 2007
SN  - 02731223
ST  - A modified advanced Fenton process for industrial wastewater treatment
T2  - Water Science & Technology
TI  - A modified advanced Fenton process for industrial wastewater treatment
UR  - http://login.oaresciences.org/whalecomwww.iwaponline.com/whalecom0/scripts/dtSearch/dtisapi6.dll?cmd=getdoc&DocId=15300&Index=E%3a%5cdtIndex%5cIW%5fWST&HitCount=4&hits=111+120+13d+13e+&SearchForm=D%3a%5ciwaponline%5csearch%5csearch%2ehtm
files/412/dtisapi6.html
VL  - 55
Y2  - 2013/01/15/06:29:19
ID  - 345
ER  - 


TY  - JOUR
AB  - Phenolic compounds in wastewaters are difficult to treat using the conventional biological techniques such as activated sludge processes because of their bio-toxic and recalcitrant properties and the high volumes released from various chemical, pharmaceutical and other industries. In the current work, a modified heterogeneous advanced Fenton process (AFP) is presented as a novel methodology for the treatment of phenolic wastewater. The modified AFP, which is a combination of hydrodynamic cavitation generated using a liquid whistle reactor and the AFP is a promising technology for wastewaters containing high organic content. The presence of hydrodynamic cavitation in the treatment scheme intensifies the Fenton process by generation of additional free radicals. Also, the turbulence produced during the hydrodynamic cavitation process increases the mass transfer rates as well as providing better contact between the pseudo-catalyst surfaces and the reactants. A multivariate design of experiments has been used to ascertain the influence of hydrogen peroxide dosage and iron catalyst loadings on the oxidation performance of the modified AFP. Higher TOC removal rates were achieved with increased concentrations of hydrogen peroxide. In contrast, the effect of catalyst loadings was less important on the TOC removal rate under conditions used in this work although there is an optimum value of this parameter. The concentration of iron species in the reaction solution was measured at 105 min and its relationship with the catalyst loadings and hydrogen peroxide level is presented.
AU  - Chakinala, Anand G.
AU  - Bremner, David H.
AU  - Gogate, Parag R.
AU  - Namkung, Kyu-Cheol
AU  - Burgess, Arthur E.
DA  - 2008/01/17/
DO  - 10.1016/j.apcatb.2007.08.012
DP  - ScienceDirect
J2  - Applied Catalysis B: Environmental
KW  - Advanced Fenton process (AFP)
Hydrodynamic cavitation
Multivariate analysis
Phenol
Wastewater treatment
L1  - files/636/Chakinala et al. - 2008 - Multivariate analysis of phenol mineralisation by .pdf
M1  - 1–2
PY  - 2008
SN  - 0926-3373
SP  - 11-18
ST  - Multivariate analysis of phenol mineralisation by combined hydrodynamic cavitation and heterogeneous advanced Fenton processing
T2  - Applied Catalysis B: Environmental
TI  - Multivariate analysis of phenol mineralisation by combined hydrodynamic cavitation and heterogeneous advanced Fenton processing
UR  - http://www.sciencedirect.com/science/article/pii/S0926337307002585
files/635/S0926337307002585.html
VL  - 78
Y2  - 2013/01/15/14:30:01
ID  - 245
ER  - 


TY  - JOUR
AB  - Fenton process has been widely used to treat landfill leachate. The “design of experiments” methodology was used to study the main variables affecting the Fenton process as well as their most relevant interactions. Results of two-level-factorial-design indicated that pH, COD, and the interaction of pH and COD gave negative effects, but Fe(II) dosage and H2O2/Fe(II) mole ratio showed positive effect, respectively. The quadratic model was derived based on the results of both two-level-factorial-design experiment and further runs of star points and center points. The response surface plots of quadratic model were obtained accordingly and the optimal conditions were derived from the quadratic model.
AU  - Zhang, Hui
AU  - Choi, Heung Jin
AU  - Canazo, Pat
AU  - Huang, Chin-Pao
DA  - 2009/01/30/
DO  - 10.1016/j.jhazmat.2008.04.126
DP  - ScienceDirect
J2  - Journal of Hazardous Materials
KW  - Advanced oxidation process
Fenton's reagent
landfill leachate
Response surface methodology
L1  - files/564/Zhang et al. - 2009 - Multivariate approach to the Fenton process for th.pdf
M1  - 2–3
PY  - 2009
SN  - 0304-3894
SP  - 1306-1312
ST  - Multivariate approach to the Fenton process for the treatment of landfill leachate
T2  - Journal of Hazardous Materials
TI  - Multivariate approach to the Fenton process for the treatment of landfill leachate
UR  - http://www.sciencedirect.com/science/article/pii/S0304389408006468
files/563/S0304389408006468.html
VL  - 161
Y2  - 2013/01/15/13:04:02
ID  - 246
ER  - 


TY  - JOUR
AB  - The degradation of olive mill wastewater (OMW) with hydroxyl radicals generated from zero-valent iron and hydrogen peroxide has been investigated by means of chemical oxygen demand (COD) and phenolic compounds analyses. The effects of the H2O2 dose, the pH and the organic matter concentration have been studied. The optimal experimental conditions were found to have continuous presence of iron metal, acid pH (2.0–4.0), and relatively concentrated hydrogen peroxide (9.5 M). Coloration of OMW disappeared and phenolic compound decreased to 50% of initial concentration after 3 h reaction time. The application of zero-valent Fe/H2O2 procedure permitted high removal efficiencies of pollutants from olive mill wastewater. The results show that zero-valent Fe/H2O2 could be considered as an effective alternative solution for the treatment of OMW or may be combined with a classical biological process to achieve high quality of effluent water.
AU  - Kallel, Monem
AU  - Belaid, Chokri
AU  - Boussahel, Rachdi
AU  - Ksibi, Mohamed
AU  - Montiel, Antoine
AU  - Elleuch, Boubaker
DA  - 2009/04/30/
DO  - 10.1016/j.jhazmat.2008.07.006
DP  - ScienceDirect
J2  - Journal of Hazardous Materials
KW  - Fenton reaction
Hydrogen peroxide
Olive mill wastewater
Wastewater decontamination
Zero-valent iron
L1  - files/606/Kallel et al. - 2009 - Olive mill wastewater degradation by Fenton oxidat.pdf
M1  - 2–3
PY  - 2009
SN  - 0304-3894
SP  - 550-554
ST  - Olive mill wastewater degradation by Fenton oxidation with zero-valent iron and hydrogen peroxide
T2  - Journal of Hazardous Materials
TI  - Olive mill wastewater degradation by Fenton oxidation with zero-valent iron and hydrogen peroxide
UR  - http://www.sciencedirect.com/science/article/pii/S0304389408010224
files/605/S0304389408010224.html
VL  - 163
Y2  - 2013/01/15/14:08:40
ID  - 247
ER  - 


TY  - JOUR
AB  - The present study is to investigate the treatment of surfactant wastewater by the Fenton process. The surfactants considered here were anionic alkylbenzene sulfonate (ABS) and linear alkylbenzene sulfonate (LAS), both being widely used in the household and industrial detergents. Experiments were conducted to examine the effects of pH, amounts of ferrous sulfate (FeSO4) and hydrogen peroxide (H2O2) and temperature on the surfactant removal. Chemical coagulation was also considered as an addition in improving the turbidity and dissolved Fe removal after the Fenton process. A first-order kinetic model was adopted to represent the Fenton oxidation of surfactant wastewater. The relation between the reaction rate coefficient and the ferrous sulfate and hydrogen peroxide concentrations and operating temperature was experimentally established using the test data.
AU  - Lin, Sheng H.
AU  - Lin, chi M.
AU  - Leu, Horng G.
DA  - 1999/05//
DO  - 10.1016/s0043-1354(98)00403-5
DP  - ScienceDirect
J2  - Water Research
KW  - chemical coagulation
Fenton oxidation
Kinetics
surfactant wastewater
L1  - files/363/Lin et al. - 1999 - Operating characteristics and kinetic studies of s.pdf
M1  - 7
PY  - 1999
SN  - 0043-1354
SP  - 1735-1741
ST  - Operating characteristics and kinetic studies of surfactant wastewater treatment by Fenton oxidation
T2  - Water Research
TI  - Operating characteristics and kinetic studies of surfactant wastewater treatment by Fenton oxidation
UR  - http://www.sciencedirect.com/science/article/pii/S0043135498004035
files/362/S0043135498004035.html
VL  - 33
Y2  - 2013/01/15/05:13:56
ID  - 248
ER  - 


TY  - JOUR
AU  - Wang, Meizhen
AU  - Yang, Guiqin
AU  - Feng, Huajun
AU  - Lv, Zhenmei
AU  - Min, Hang
DA  - 2011/06//
DO  - 10.2166/wst.2011.466
DP  - CrossRef
L1  - files/407/063112471.pdf
M1  - 11
PY  - 2011
SN  - 0273-1223
ST  - Optimization of Fenton process for decoloration and COD removal in tobacco wastewater and toxicological evaluation of the effluent
T2  - Water Science & Technology
TI  - Optimization of Fenton process for decoloration and COD removal in tobacco wastewater and toxicological evaluation of the effluent
UR  - http://login.oaresciences.org/whalecomwww.iwaponline.com/whalecom0/scripts/dtSearch/dtisapi6.dll?cmd=getdoc&DocId=17889&Index=E%3a%5cdtIndex%5cIW%5fWST&HitCount=4&hits=1a9+1b8+1d4+1d5+&SearchForm=D%3a%5ciwaponline%5csearch%5csearch%2ehtm
files/406/dtisapi6.html
VL  - 63
Y2  - 2013/01/15/06:24:32
ID  - 348
ER  - 


TY  - JOUR
AB  - The treatment of landfill leachate by Fenton process was carried out in a batch reactor. The effect of operating conditions such as reaction time, pH, H2O2 to Fe(II) molar ratio, Fenton's reagent dosage, initial COD strength, feeding mode, the type of polymer, and temperature on the efficacy of Fenton process was investigated. It is demonstrated that Fenton's reagent can effectively degrade leachate organics. Fenton process was so fast that it was complete in 30 min. The oxidation of organic materials in the leachate was pH dependent and the optimal pH was 2.5. The favorable H2O2 to Fe(II) molar ratio was 1.5, and organic removal increased as dosage increased at the favorable H2O2 to Fe(II) molar ratio. The efficacy of Fenton process was improved by adding Fenton's reagent in multiple steps than that in a single step. Furthermore, the stepwise addition of both hydrogen peroxide and ferrous iron was more effective than that of hydrogen peroxide only. Sludge settling characteristics were much improved with the addition of the proper polymer. Temperature gave a positive effect on organic removal.
AU  - Zhang, Hui
AU  - Choi, Heung Jin
AU  - Huang, Chin-Pao
DA  - 2005/10/17/
DO  - 10.1016/j.jhazmat.2005.05.025
DP  - ScienceDirect
J2  - Journal of Hazardous Materials
KW  - Batch mode
Chemical oxidation
Fenton's reagent
landfill leachate
L1  - files/471/Zhang et al. - 2005 - Optimization of Fenton process for the treatment o.pdf
M1  - 1–3
PY  - 2005
SN  - 0304-3894
SP  - 166-174
ST  - Optimization of Fenton process for the treatment of landfill leachate
T2  - Journal of Hazardous Materials
TI  - Optimization of Fenton process for the treatment of landfill leachate
UR  - http://www.sciencedirect.com/science/article/pii/S0304389405002645
files/470/S0304389405002645.html
VL  - 125
Y2  - 2013/01/15/09:05:15
ID  - 249
ER  - 


TY  - JOUR
AB  - The study examined the effect of operating conditions of the Fenton process on biodegradability improvement and mineralization of amoxicillin, ampicillin and cloxacillin antibiotics in aqueous solution. In addition, degradation of amoxicillin, ampicillin and cloxacillin under optimum operating conditions were evaluated. The optimum operating conditions for an aqueous solution containing 104, 105 and 103 mg/L amoxicillin, ampicillin, and cloxacillin, respectively were observed to be COD/H2O2/Fe2+ molar ratio 1:3:0.30 and pH 3. Under optimum operating conditions, complete degradation of amoxicillin, ampicillin and cloxacillin occurred in 2 min. In addition, biodegradability improved from ∼0 to 0.37 in 10 min, and COD and DOC degradation were 81.4% and 54.3%, respectively in 60 min. Maximum biodegradability (BOD5/COD ratio) improvement was achieved in 10, 20 and 40 min at antibiotics concentration 100, 250 and 500 mg/L, respectively for each antibiotic in aqueous solution. Increase in nitrate and ammonia concentration were observed due to mineralization of organic nitrogen, concentration of nitrate increased from 0.3 to 10 mg/L and concentration of ammonia increased from 8 to 13 mg/L in 60 min. The study indicated that Fenton process can be used for pretreatment of amoxicillin, ampicillin and cloxacillin wastewater for biological treatment.
AU  - Elmolla, Emad
AU  - Chaudhuri, Malay
DA  - 2009/10/30/
DO  - 10.1016/j.jhazmat.2009.05.013
DP  - ScienceDirect
J2  - Journal of Hazardous Materials
KW  - Amoxicillin
Ampicillin
Antibiotics
Cloxacillin
Fenton process
L1  - files/313/Elmolla and Chaudhuri - 2009 - Optimization of Fenton process for treatment of am.pdf
M1  - 2–3
PY  - 2009
SN  - 0304-3894
SP  - 666-672
ST  - Optimization of Fenton process for treatment of amoxicillin, ampicillin and cloxacillin antibiotics in aqueous solution
T2  - Journal of Hazardous Materials
TI  - Optimization of Fenton process for treatment of amoxicillin, ampicillin and cloxacillin antibiotics in aqueous solution
UR  - http://www.sciencedirect.com/science/article/pii/S0304389409007559
files/312/S0304389409007559.html
VL  - 170
Y2  - 2013/01/15/04:30:29
ID  - 250
ER  - 


TY  - JOUR
AB  - Establishing a treatment process for practical and economic disposal of laboratory wastewaters has become an urgent environmental concern of the Department of Chemical Engineering of the Universidade Estadual de Maringá (State University of Maringá), Brazil. Fenton and related reactions are potentially useful oxidation processes for destroying toxic organic compounds in water. In these reactions, hydrogen peroxide is combined with ferrous or ferric iron in the presence or absence of light to generate hydroxyl radicals (OH). The feasibility of Fenton's reagent to treat waste chemicals from an academic research laboratory was investigated in this study. A response surface methodology was applied to optimize the Fenton oxidation process conditions using chemical oxygen demand (COD) removal as the target parameter to optimize, and the reagent concentrations, as related to the initial concentration of organic matter in the effluent, and pH as the control factors to be optimized. Maximal COD removal (92.3%) was achieved when wastewater samples were treated at pH 4 in the presence of hydrogen peroxide and iron in the ratios [COD]:[H2O2]=1:9 and [H2O2]:[Fe2+]=4.5:1. Under these conditions, it was possible to obtain simultaneously maximal COD removal and minimal chemical sludge after treatment, which is a residue that needs further processing.
AU  - Benatti, Cláudia Telles
AU  - Tavares, Célia Regina Granhen
AU  - Guedes, Terezinha Aparecida
DA  - 2006/07//
DO  - 10.1016/j.jenvman.2005.08.014
DP  - ScienceDirect
J2  - Journal of Environmental Management
KW  - Fenton's reagent
Laboratory wastewater
Optimization
Oxidation
Surface response technique
L1  - files/137/Benatti et al. - 2006 - Optimization of Fenton's oxidation of chemical lab.pdf
M1  - 1
PY  - 2006
SN  - 0301-4797
SP  - 66-74
ST  - Optimization of Fenton's oxidation of chemical laboratory wastewaters using the response surface methodology
T2  - Journal of Environmental Management
TI  - Optimization of Fenton's oxidation of chemical laboratory wastewaters using the response surface methodology
UR  - http://www.sciencedirect.com/science/article/pii/S0301479705002719
files/136/S0301479705002719.html
VL  - 80
Y2  - 2013/01/14/04:06:14
ID  - 251
ER  - 


TY  - JOUR
AU  - Barbusiński, Krzysztof
AU  - Fajkis, Sławomir
DA  - 2011/12//
DO  - 10.1002/ep.10525
DP  - CrossRef
L1  - files/428/10525_ftp.pdf
M1  - 4
PY  - 2011
SN  - 19447442
SP  - 620-631
ST  - Optimization of the fenton oxidation of wastewater generated by rape oil soapstock splitting
T2  - Environmental Progress & Sustainable Energy
TI  - Optimization of the fenton oxidation of wastewater generated by rape oil soapstock splitting
UR  - http://doi.wiley.com/10.1002/ep.10525
VL  - 30
Y2  - 2012/12/25/09:23:05
ID  - 306
ER  - 


TY  - JOUR
AU  - Vilar, Almudena
AU  - Eiroa, Marta
AU  - Kennes, Christian
AU  - Veiga, Maria C.
DA  - 2012/09//
DO  - 10.1111/j.1747-6593.2012.00333.x
DP  - CrossRef
L1  - files/437/wej333.pdf
PY  - 2012
SN  - 17476585
SP  - n/a-n/a
ST  - Optimization of the landfill leachate treatment by the Fenton process
T2  - Water and Environment Journal
TI  - Optimization of the landfill leachate treatment by the Fenton process
UR  - http://doi.wiley.com/10.1111/j.1747-6593.2012.00333.x
Y2  - 2013/01/15/07:25:59
ID  - 307
ER  - 


TY  - JOUR
AU  - Kabdaşlı, I.
AU  - Arslan, T.
AU  - Arslan-Alaton, I.
AU  - Ölmez-Hancı, T.
AU  - Tünay, O.
DA  - 2010/05//
DO  - 10.2166/wst.2010.202
DP  - CrossRef
L1  - files/410/061102617.pdf
M1  - 10
PY  - 2010
SN  - 0273-1223
ST  - Organic matter and heavy metal removals from complexed metal plating effluent by the combined electrocoagulation/Fenton process
T2  - Water Science & Technology
TI  - Organic matter and heavy metal removals from complexed metal plating effluent by the combined electrocoagulation/Fenton process
UR  - http://login.oaresciences.org/whalecomwww.iwaponline.com/whalecom0/scripts/dtSearch/dtisapi6.dll?cmd=getdoc&DocId=17128&Index=E%3a%5cdtIndex%5cIW%5fWST&HitCount=4&hits=1a7+1b6+1df+1e0+&SearchForm=D%3a%5ciwaponline%5csearch%5csearch%2ehtm
files/409/dtisapi6.html
VL  - 61
Y2  - 2013/01/15/06:28:15
ID  - 349
ER  - 


TY  - JOUR
AU  - Bautista, P.
AU  - Mohedano, A. F.
AU  - Casas, J. A.
AU  - Zazo, J. A.
AU  - Rodriguez, J. J.
DA  - 2008/10//
DO  - 10.1002/jctb.1988
DP  - CrossRef
L1  - files/435/1988_ftp.pdf
M1  - 10
PY  - 2008
SN  - 02682575, 10974660
SP  - 1323-1338
ST  - An overview of the application of Fenton oxidation to industrial wastewaters treatment
T2  - Journal of Chemical Technology & Biotechnology
TI  - An overview of the application of Fenton oxidation to industrial wastewaters treatment
UR  - http://doi.wiley.com/10.1002/jctb.1988
VL  - 83
Y2  - 2013/01/15/07:25:59
ID  - 294
ER  - 


TY  - JOUR
AB  - COD removal by oxidation as well as by coagulation during Fered–Fenton treatment of landfill leachate was quantitatively determined in this study. The effects of operating conditions such as H2O2 to Fe2+ mole ratio, Fenton’s reagent dosage, initial pH, current density, inter-electrode gap and hydrogen peroxide feeding mode on COD removal was investigated. The results showed that COD removal by oxidation is dominant due to the high H2O2/Fe2+ mole ratio employed and the overall COD removal showed the same behavior as oxidation removal. The coagulation removal of COD increased with initial pH and ferrous iron dosage, but it was independent of current density and the inter-electrode gap at a fixed initial pH value and ferrous iron dose. Increasing Fenton’s reagent dosage or decreasing the initial pH is likely to promote COD removal by oxidation. There existed an optimal H2O2/Fe2+ mole ratio, current density or inter-electrode gap to reach the highest COD removal efficiency by oxidation. The stepwise or continuous addition of hydrogen peroxide was more effective to oxidize organics than a single dose of hydrogen peroxide. Nearly all the organic compounds (&gt;4 kDa) were degraded into smaller ones after Fered–Fenton treatment. GC–MS analysis was used to determine the organic compounds before and after the treatment.
AU  - Zhang, Hui
AU  - Wu, Xiaogang
AU  - Li, Xianwang
DA  - 2012/11/01/
DO  - 10.1016/j.cej.2012.08.094
DP  - ScienceDirect
J2  - Chemical Engineering Journal
KW  - Coagulation
COD removal
Fered–Fenton
GC–MS
landfill leachate
Oxidation
L1  - files/468/Zhang et al. - 2012 - Oxidation and coagulation removal of COD from land.pdf
M1  - 0
PY  - 2012
SN  - 1385-8947
SP  - 188-194
ST  - Oxidation and coagulation removal of COD from landfill leachate by Fered–Fenton process
T2  - Chemical Engineering Journal
TI  - Oxidation and coagulation removal of COD from landfill leachate by Fered–Fenton process
UR  - http://www.sciencedirect.com/science/article/pii/S1385894712011680
files/467/S1385894712011680.html
VL  - 210
Y2  - 2013/01/15/09:05:15
ID  - 252
ER  - 


TY  - JOUR
AB  - The treatment of humic acid (HA) in water with Fenton reagents was carried out and the roles of oxidation and coagulation in removing HA during treatment were investigated. The removal efficiencies of HA by oxidation and coagulation were tested under various operating conditions: reaction time, initial pH, dosages of Fenton reagents, [H2O2]/[Fe2+] molar ratio, initial HA concentration and reaction temperature. It is demonstrated that Fenton process can effectively remove HA. The values of 27.6% mineralization of HA and 78.9% reduction of UV absorbance at 254 nm (UV254) by oxidation after 120 min reaction time indicated that HA was not completely oxidized to carbon dioxide but rather transformed to some organic intermediates. Moreover, the oxidation occurred mainly at the first 60 min and predominated the HA removal efficiency. Under the most favorable conditions (initial pH 4.0, H2O2 160 mM, Fe2+ 40 mM, reaction time 120 min, reaction temperature 30 °C), 93.3% of UV254 was reduced, the reduction of UV254 by oxidation and coagulation were 78.9% and 14.4%, respectively. Results highlighted the synergistic roles of oxidation and coagulation in Fenton treatment of HA.
AU  - Wu, Yanyu
AU  - Zhou, Shaoqi
AU  - Ye, Xiuya
AU  - Zhao, Rong
AU  - Chen, Dongyu
DA  - 2011/04/20/
DO  - 10.1016/j.colsurfa.2010.11.057
DP  - ScienceDirect
J2  - Colloids and Surfaces A: Physicochemical and Engineering Aspects
KW  - Coagulation
Fenton process
Humic acid
Oxidation
L1  - files/657/Wu et al. - 2011 - Oxidation and coagulation removal of humic acid us.pdf
M1  - 1–3
PY  - 2011
SN  - 0927-7757
SP  - 151-156
ST  - 6th International Conference on Interfaces Against Pollution Selected papers from the International Conference
T2  - Colloids and Surfaces A: Physicochemical and Engineering Aspects
TI  - Oxidation and coagulation removal of humic acid using Fenton process
UR  - http://www.sciencedirect.com/science/article/pii/S0927775710006886
files/656/S0927775710006886.html
VL  - 379
Y2  - 2013/01/15/14:46:36
ID  - 253
ER  - 


TY  - JOUR
AB  - The fundamentals of the Fenton reagent-based degradation of low concentrations of methyl tert-butyl ether (MTBE) in batch reactors under initially anaerobic conditions are discussed in this work. The objective of the study was to quantitatively verify the feasibility of MTBE degradation with Fenton reagent under such conditions. The conclusions may be potentially helpful to further develop an effective in situ treatment of MTBE-contaminated groundwater. Initial MTBE concentrations ([MTBE]0) of 11.4 and 22.7 μM (approximately 1.0 and 2.0 mg/L, respectively) were treated with Fenton reagent (FR) using a [FR]0:[MTBE]0 molar ratio of 10:1. FR was used in equimolar mixture of Fe2+and H2O2 (i.e., [Fe2+]0:[H2O2]0=1:1). This analysis considers the hydroxyl radicals (OH) produced by FR as the main species responsible for the degradation processes. The effects of [MTBE]0 and pH on the oxidation kinetics were investigated. Under these conditions it was observed that: (i) MTBE was degraded at high extent (90–99%) after 1 h of reaction time, (ii) MTBE mineralization was low in all cases and reached only 31.7% at the best conditions, and (iii) In all cases, most of MTBE degradation occurred during the initial 3–5 min of reaction. During this brief initial phase, MTBE transformation followed pseudo-first order kinetics, while the subsequent phase exhibited a sharp drop in degradation rate and had almost negligible contribution to the overall degradation. Experiments performed at acidic pH exhibited the best degradation results, while at neutral pH the degradation rates dropped significantly. Other parameters included in this analysis were: TOC reduction and total concentration of compounds containing the tert-butyl group in their structure (tBC). These compounds were analyzed because of the concerns related to their potential toxicity. Tert-butyl formate (TBF), Tert-butyl alcohol (TBA), acetone and methyl acetate were identified and quantified as major reaction intermediates.
AU  - Burbano, Arturo A.
AU  - Dionysiou, Dionysios D.
AU  - Suidan, Makram T.
AU  - Richardson, Teri L.
DA  - 2005/01//
DO  - 10.1016/j.watres.2004.09.008
DP  - ScienceDirect
J2  - Water Research
KW  - Advanced oxidation processes (AOPs)
AOTs
Fenton reagent
Groundwater contamination
Hydrogen peroxide
Hydroxyl radical
Iron
MTBE
TBA
TBF
L1  - files/474/Burbano et al. - 2005 - Oxidation kinetics and effect of pH on the degrada.pdf
M1  - 1
PY  - 2005
SN  - 0043-1354
SP  - 107-118
ST  - Oxidation kinetics and effect of pH on the degradation of MTBE with Fenton reagent
T2  - Water Research
TI  - Oxidation kinetics and effect of pH on the degradation of MTBE with Fenton reagent
UR  - http://www.sciencedirect.com/science/article/pii/S0043135404004634
files/473/S0043135404004634.html
VL  - 39
Y2  - 2013/01/15/09:05:15
ID  - 254
ER  - 


TY  - JOUR
AB  - The oxidative degradation of two direct dyes, Blue 2B (B54) and Red 12B (R31) in aqueous solution has been studied using Fenton's reagent (Fe2+ and H2O2). Results show that dyes are decomposed in a two-stage reaction. In the first stage, dyes are decomposed rapidly, and somewhat less rapidly in the second stage. The effects of different system variables like initial pH of the medium, initial concentrations of the dye, Fe2+ and H2O2, reaction temperature, and added Cl− and SO4−2 ions have been investigated. The degradation rate is strongly dependent on the initial concentrations of the dye, Fe2+ and H2O2. The results indicate that the B54 and R31 can be most effectively oxidised in an aqueous medium of pH 3 at an initial [Fe2+]:[H2O2]:[dye] ratio of 1:32.9:2.4 and 1:16.5:1.8 (mM), respectively. At the optimum initial ratio of [Fe2+]:[H2O2]:[dye], 97% degradation can be achieved in 30 min at a temperature of 30 °C, and 70% removal of initial chemical oxygen demand (COD) is achieved after 60 min. The degradation of both the dyes obeys first order rate kinetics with respect to the concentration of the dye in the second stage of oxidation. The results will be useful in designing wastewater treatment plants.
AU  - Malik, P. K.
AU  - Saha, S. K.
DA  - 2003/06/01/
DO  - 10.1016/s1383-5866(02)00200-9
DP  - ScienceDirect
J2  - Separation and Purification Technology
KW  - Direct dye
Fenton's reagent
Ferrous ion
Hydrogen peroxide
Oxidation
Wastewater
L1  - files/627/Malik and Saha - 2003 - Oxidation of direct dyes with hydrogen peroxide us.pdf
M1  - 3
PY  - 2003
SN  - 1383-5866
SP  - 241-250
ST  - Oxidation of direct dyes with hydrogen peroxide using ferrous ion as catalyst
T2  - Separation and Purification Technology
TI  - Oxidation of direct dyes with hydrogen peroxide using ferrous ion as catalyst
UR  - http://www.sciencedirect.com/science/article/pii/S1383586602002009
files/626/S1383586602002009.html
VL  - 31
Y2  - 2013/01/15/14:25:50
ID  - 255
ER  - 


TY  - JOUR
AB  - The effectiveness of Fenton oxidation of tannery wastewater was investigated under different operational conditions such as pH, time and dosages of Fenton reagent (H2O2 and FeSO4·7H2O). Different mass ratios of Fe2+/H2O2 recorded the percentage COD reduction from 54 to 80 % in 4 h at pH 3.5. The batch study has established COD reduction by 82 % with mesoporous activated carbon (MAC800) catalyst and the percentage reduction of COD was 94 % under integrated homo- and hetero-Fenton oxidations of tannery wastewater. Fenton reagent was efficient enough to oxidize most of the organic compounds present in the tannery wastewater. This was confirmed through UV–visible spectroscopy, FT-IR spectroscopy, cyclic voltammetry and NMR spectroscopy.
AU  - Sekaran, G.
AU  - Karthikeyan, S.
AU  - Evvie, C.
AU  - Boopathy, R.
AU  - Maharaja, P.
DO  - 10.1007/s10098-012-0502-5
DP  - link.springer.com
J2  - Clean Techn Environ Policy
KW  - Environmental Economics
Environmental Engineering/Biotechnology
Heterogeneous Fenton oxidation
Industrial and Production Engineering
Industrial Chemistry/Chemical Engineering
Mesoporous activated carbon
Refractory organics
Sustainable Development
Tannery wastewater
L1  - files/368/Sekaran et al. - Oxidation of refractory organics by heterogeneous .pdf
LA  - en
SN  - 1618-954X, 1618-9558
SP  - 1-9
ST  - Oxidation of refractory organics by heterogeneous Fenton to reduce organic load in tannery wastewater
T2  - Clean Technologies and Environmental Policy
TI  - Oxidation of refractory organics by heterogeneous Fenton to reduce organic load in tannery wastewater
UR  - http://link.springer.com/article/10.1007/s10098-012-0502-5
files/369/s10098-012-0502-5.html
Y2  - 2013/01/15/05:19:45
ID  - 338
ER  - 


TY  - JOUR
AB  - Advanced chemical, photochemical and electrochemical oxidation processes based on catalytic generation of hydroxyl radicals through Fenton's reagent are applied to remove herbicide diuron from aqueous medium. To enhance the oxidation power of Fenton's reagent, it was assisted photochemically (photo-Fenton) or electrochemically (electro-Fenton). Kinetic analysis showed that the oxidation of diuron by hydroxyl radicals follows a reaction kinetic of pseudo-first order. The apparent rate constants values and mineralization degree of different photochemical processes revealed the superiority of the photo-Fenton process in degradation rate (kinetics) and that of electro-Fenton process in cost effectiveness and process efficiency. The absolute rate constant for diuron oxidation by hydroxyl radical was determined as (4.75 ± 0.20) × 109 L mol−1 s−1 by competition kinetics method taking benzoic acid as reference compound. Electro-Fenton process exhibits a very fast degradation kinetics achieving complete removal of 0.17 mM diuron in less than 6 min. The apparent current efficiency was determined; its maximum value of 28% at 0.6 h decreases with the treatment time to 11% at 3 h, i.e., when 89% of mineralization is achieved. When 300 mA was applied, higher mineralization efficiency of 96% was achieved. The photo-Fenton process exhibits also high mineralization efficiency reaching 97% TOC removal at 5 h under optimal operating conditions. Several oxidation by-products such as 3,[3,4-dichlorohydroxyphenyl]-1,1-methylurea, 3,[3-hydroxy 4-chlorohydroxyphenyl]-1,1-methylurea, 3-[trihydroxyphenyl]-1,1-dimethylurea, 3,[3-hydoxy-4-chlorophenyl]-1,1-methylurea, 3,[3-hydroxy-4-chlorophenyl]-1,1-dimethylurea, and dichloroaniline were identified by HPLC and LC–MS analyses evidencing two sites of attack of hydroxyl radical, the first being located on the aromatic ring and the second on the dimethylurea group. Based on the identification of aromatic intermediates, carboxylic acids and chloride ion released; a plausible diuron mineralization pathway is proposed.
AU  - Oturan, Mehmet A.
AU  - Oturan, Nihal
AU  - Edelahi, Mohamed C.
AU  - Podvorica, Fetah I.
AU  - Kacemi, Kacem El
DA  - 2011/06/15/
DO  - 10.1016/j.cej.2011.03.072
DP  - ScienceDirect
J2  - Chemical Engineering Journal
KW  - AOPs
Electro-Fenton
Fenton's reagent
Hydroxyl radicals
Mineralization
Phenylurea herbicides
L1  - files/191/Oturan et al. - 2011 - Oxidative degradation of herbicide diuron in aqueo.pdf
M1  - 1
PY  - 2011
SN  - 1385-8947
SP  - 127-135
ST  - Oxidative degradation of herbicide diuron in aqueous medium by Fenton's reaction based advanced oxidation processes
T2  - Chemical Engineering Journal
TI  - Oxidative degradation of herbicide diuron in aqueous medium by Fenton's reaction based advanced oxidation processes
UR  - http://www.sciencedirect.com/science/article/pii/S1385894711003779
files/190/S1385894711003779.html
VL  - 171
Y2  - 2013/01/14/04:55:26
ID  - 256
ER  - 


TY  - JOUR
AB  - The influence of inorganic salts on the kinetics of oxidation of 2,4-and 2,6-dinitrophenols by Fenton’s reagent, hydrogen peroxide, in the presence of iron(II) ions was studied.
AU  - Solov’ev, A. A.
AU  - Pashina, M. A.
AU  - Lebedeva, O. E.
DA  - 2007/02/01/
DO  - 10.1134/s1070427207020218
DP  - link.springer.com
J2  - Russ J Appl Chem
KW  - Chemistry/Food Science, general
Industrial Chemistry/Chemical Engineering
L1  - files/389/Solov’ev et al. - 2007 - Oxidative destruction of dinitrophenols by Fenton’.pdf
LA  - en
M1  - 2
PY  - 2007
SN  - 1070-4272, 1608-3296
SP  - 275-278
ST  - Oxidative destruction of dinitrophenols by Fenton’s reagent in the presence of inorganic salts
T2  - Russian Journal of Applied Chemistry
TI  - Oxidative destruction of dinitrophenols by Fenton’s reagent in the presence of inorganic salts
UR  - http://link.springer.com/article/10.1134/S1070427207020218
files/390/S1070427207020218.html
VL  - 80
Y2  - 2013/01/15/05:33:47
ID  - 339
ER  - 


TY  - JOUR
AB  - Homogeneous Fenton reaction (H2O2/Fe2+ system) using significantly substoichiometric concentrations of H2O2 oxidant to oxidize phenol was characterized focusing on the formation of stable aromatic intermediates. Beyond the most abundant benzenediols, the pattern of aromatic intermediates was chiefly characterized by hydroxylated biphenyls and diphenyl ethers with different degrees of hydroxylation. Hydroxylated dibenzofurans (DBF), p,p′-dioxins, as well as highly condensed aromatic intermediates including polyols of polycyclic aromatic hydrocarbons (PAHs), could also be detected, but in lower concentrations. The formation of aromatic intermediates could be predicted on the basis of oxidative coupling reactions of resonance-stabilized radicals generated by the attack of the highly reactive hydroxyl radicals (OH*) on phenol. GC/MS identification of oxidative coupling intermediates was performed after derivatization of the solvent extracts. Derivatization reactions included silylation to give TMS (trimethylsilyl) ethers, as well as single-step extractive acetylation using acetic anhydride in alkaline aqueous solutions (pH 10.5) to give acetates. Solvent extraction of aqueous solutions, a prerequisite to generate TMS ethers, caused strong discrimination of polyols due to their low distribution coefficients in non-polar solvents. This discrimination could be overcome by extracting the in-situ formed acetates of the intermediates. Extractive acetylation allowed the detection of tri-, tetra-, and penta-hydroxylated aromatic intermediates generated by Fenton oxidation processes, which have been overlooked upto now. Thus, extractive acetylation to detect stable aromatic intermediates covering a wide range of hydroxylation degrees can foster the understanding, monitoring, and management of advanced oxidation processes, especially in the field of wastewater treatment.
AU  - Poerschmann, Juergen
AU  - Trommler, Ulf
DA  - 2009/07/17/
DO  - 10.1016/j.chroma.2009.05.075
DP  - ScienceDirect
J2  - Journal of Chromatography A
KW  - Acetic anhydride
Fenton oxidation
Oxidative coupling reactions
Phenol
L1  - files/703/Poerschmann and Trommler - 2009 - Pathways of advanced oxidation of phenol by Fenton.pdf
M1  - 29
PY  - 2009
SN  - 0021-9673
SP  - 5570-5579
ST  - Pathways of advanced oxidation of phenol by Fenton's reagent—Identification of oxidative coupling intermediates by extractive acetylation
T2  - Journal of Chromatography A
TI  - Pathways of advanced oxidation of phenol by Fenton's reagent—Identification of oxidative coupling intermediates by extractive acetylation
UR  - http://www.sciencedirect.com/science/article/pii/S0021967309008188
files/702/S0021967309008188.html
VL  - 1216
Y2  - 2013/01/15/15:45:17
ID  - 257
ER  - 


TY  - JOUR
AB  - The extent of hemoglobin peroxidation under the action of mixtures of ferrous salts and hydrogen peroxide has been investigated. The rate of accumulation of carbonyl-containing products of the protein fragmentation, detected as 2,4-dinitrophenylhydrazones, is independent of the pH of the reaction medium and proportional to the concentrations of hydrogen peroxide, ferrous ion, and hemoglobin. A chain radical mechanism of the peroxide fragmentation of the polypeptide chains of hemoglobin has been proposed, involving reactions of the alkoxyl radical of hemoglobin with ferrous ion and of the carbon-centered radical of the protein with dissolved oxygen as rate-limiting steps. Chain termination is therewith effected through cross recombination of the above radicals.
AU  - Lukogorskaya, S. A.
AU  - Shugalei, I. V.
AU  - Tselinskii, I. V.
DA  - 2002/03/01/
DO  - 10.1023/a:1015424524330
DP  - link.springer.com
J2  - Russian Journal of General Chemistry
KW  - Chemistry/Food Science, general
L1  - files/383/Lukogorskaya et al. - 2002 - Peroxide Damage of Hemoglobin by the Fenton System.pdf
LA  - en
M1  - 3
PY  - 2002
SN  - 1070-3632, 1608-3350
SP  - 480-483
ST  - Peroxide Damage of Hemoglobin by the Fenton System
T2  - Russian Journal of General Chemistry
TI  - Peroxide Damage of Hemoglobin by the Fenton System
UR  - http://link.springer.com/article/10.1023/A%3A1015424524330
files/384/A1015424524330.html
VL  - 72
Y2  - 2013/01/15/05:30:15
ID  - 340
ER  - 


TY  - JOUR
AB  - Background Chlorophenols (CPs) constitute a group of organic pollutants that are introduced into the environment as a result of several man-made activities, such as uncontrolled use of pesticides and herbicides, and as byproducts in the paper pulp bleaching. Promising removal technologies of chlorinated aromatics consist in the application of advanced oxidation processes (AOPs) that can provide an almost total degradation of a variety of contaminants. Among these, wide application find Fenton systems based on generation of reactive species having a high oxidizing power, such as hydroxyl radical HO•. Our objective was that of determining the overall degradation efficiency of the model compound 2,4-dichlorophenol (DCP) by thermal Fenton-type oxidation systems with a view toward defining in more details relevant process parameters, the effect of reaction temperature and of co-catalyst Cu2+. Methods Reaction conditions were similar to those generally adopted as optimal in many practical applications, i.e. pollutant /Fe2+ (as FeSO4) ratio ca. 20, Fe2+/Cu2+ (co-catalyst) 2:1, pH adjusted and controlled at pH 3, and H2O2 in excess (up to four-fold over the stoichiometric amount required for complete mineralization). Results and Discussion The results demonstrate that it is advantageous to carry out the reaction at a temperature markedly higher (70°C) than ambient. The stepwise addition of H2O2 in aliquots yields an efficient transformation, while allowing a convenient control of the reaction exothermicity. Under these conditions, the essentially complete removal of the initial DCP is accomplished using just one equiv of H2O2 during 15 min; excess H2O2 (5 equivalents) yields extensive substrate mineralization. Also relevant, at 70°C dechlorination of the initial DCP (and of derived reaction intermediates) is remarkably extensive (3-5% residual TOX), already with the addition of 1 equiv of H2O2. At the end of the reaction, IC and IC-MS analyses of the solution reveal that only low-molecular weight carboxylic acid (acetic, formic, oxalic, malonic, tartaric, etc.) contribute to the residual TOC. Conclusions The whole of the results herein point to the advantage of performing the process at temperatures substantially higher than ambient (70°C). Under the conditions adopted, almost complete degradation of the initial toxic compound can be achieved using hydrogen peroxide in fair excess (e.g., 3.5 equiv H2O2). Recommendations and Outlook In applying practical Fenton-type degradation systems to heavily polluted wastes, either for the pre-treatment of waters with a high COD value prior to biodegradation or for complete mineralization of pollutants, the set up of appropriate reaction conditions appears to be a key factor. Also, it is desirable to keep the concentration of iron salts within the lower limits in order to minimize the production and disposal of iron oxide sludges.
AU  - Detomaso, Antonia
AU  - Lopez, Antonio
AU  - Lovecchio, Giangiuseppe
AU  - Mascolo, Giuseppe
AU  - Curci, Ruggero
DA  - 2003/11/01/
DO  - 10.1065/espr2003.06.155
DP  - link.springer.com
J2  - Environ Sci & Pollut Res
KW  - 2,4-dichlorophenol
aromatic dechlorination
Atmospheric Protection/Air Quality Control/Air Pollution
chlorinated aromatic pollutants
Environment, general
Fenton reaction
Fenton-type oxidations
Hydrogen peroxide
Hydroxyl radical
Industrial Pollution Prevention
Waste Water Technology / Water Pollution Control / Water Management / Aquatic Pollution
L1  - files/339/Detomaso et al. - 2003 - Practical applications of the fenton reaction to t.pdf
LA  - en
M1  - 6
PY  - 2003
SN  - 0944-1344, 1614-7499
SP  - 379-384
ST  - Practical applications of the fenton reaction to the removal of chlorinated aromatic pollutants
T2  - Environmental Science and Pollution Research
TI  - Practical applications of the fenton reaction to the removal of chlorinated aromatic pollutants
UR  - http://link.springer.com/article/10.1065/espr2003.06.155
files/340/espr2003.06.html
VL  - 10
Y2  - 2013/01/15/04:49:55
ID  - 341
ER  - 


TY  - JOUR
AB  - This paper evaluates the Fenton process, involving oxidation and coagulation, for the removal of color and chemical oxygen demand (COD) from synthetic textile wastewater containing polyvinyl alcohol and a reactive dyestuff, R94H. The experimental variables studied include dosages of iron salts and hydrogen peroxide, oxidation time, mixing speed and organic content. The results show that color was removed mainly by Fenton oxidation. The color removal reached a maximum of 90% at a reaction time of 5 min under low dosages of H2O2 and Fe2+. In contrast, the COD was removed primarily by Fenton coagulation, rather than by Fenton oxidation. The ratio of removal efficiency between Fenton process and ferric coagulation was 5.6 for color removal and 1.2 for COD removal. It is concluded that Fenton process for the treatment of textile wastewater favors the removal of color rather than COD.
AU  - Kang, Shyh-Fang
AU  - Liao, Chih-Hsaing
AU  - Chen, Mon-Chun
DA  - 2002/02//
DO  - 10.1016/s0045-6535(01)00159-x
DP  - ScienceDirect
J2  - Chemosphere
KW  - Coagulation
Decolorization
Fenton process
Textile wastewater
L1  - files/122/Kang et al. - 2002 - Pre-oxidation and coagulation of textile wastewate.pdf
M1  - 6
PY  - 2002
SN  - 0045-6535
SP  - 923-928
ST  - Pre-oxidation and coagulation of textile wastewater by the Fenton process
T2  - Chemosphere
TI  - Pre-oxidation and coagulation of textile wastewater by the Fenton process
UR  - http://www.sciencedirect.com/science/article/pii/S004565350100159X
files/121/S004565350100159X.html
VL  - 46
Y2  - 2013/01/14/03:50:19
ID  - 258
ER  - 


TY  - JOUR
AB  - The pre-oxidation of an extremely polluted pharmaceutical wastewater (chemical oxygen demand (COD) value of 362,000 mg/l) using the Fenton’s reagent has been systematically studied using an experimental design technique. The parameters influencing the COD removal of the wastewater, namely temperature, ferrous ion and hydrogen peroxide concentrations have been optimized to achieve a COD global reduction of 56.4%. The total range of the proposed experimental design, however, could not be tested because under some conditions (hydrogen peroxide concentration over 5 M) the Fenton’s reaction became violent and could not be controlled, probably due to the high exothermic effect associated with COD oxidation. For the tested conditions, the optimal values of hydrogen peroxide and ferrous ion concentration were 3 and 0.3 M, respectively, whereas temperature only showed a mild positive effect on COD removal. In addition, during the first 10 min of Fenton’s reaction, more than 90% of the total COD removal can be achieved. Fenton’s reaction has proved to be a feasible technique for the pre-oxidation of the wastewater under study, and can be considered a suitable pre-treatment for this type of wastewaters.
AU  - San Sebastián, Martı
AU  - x
AU  - nez, Nora
AU  - Fernández, Josep Fı
AU  - guls
AU  - Segura, Xavier Font
AU  - Ferrer, Antoni Sánchez
DA  - 2003/08/01/
DO  - 10.1016/s0304-3894(03)00207-3
DP  - ScienceDirect
J2  - Journal of Hazardous Materials
KW  - Advanced process oxidation
COD removal
Experimental design
Fenton’s reagent
Industrial wastewater
L1  - files/462/San Sebastián Martı&#x0301
nez et al. - 2003 - Pre-oxidation of an extremely polluted industrial .pdf
M1  - 3
PY  - 2003
SN  - 0304-3894
SP  - 315-322
ST  - Pre-oxidation of an extremely polluted industrial wastewater by the Fenton’s reagent
T2  - Journal of Hazardous Materials
TI  - Pre-oxidation of an extremely polluted industrial wastewater by the Fenton’s reagent
UR  - http://www.sciencedirect.com/science/article/pii/S0304389403002073
files/461/S0304389403002073.html
VL  - 101
Y2  - 2013/01/15/09:01:16
ID  - 259
ER  - 


TY  - JOUR
AB  - Fenton process was employed to pretreat the acrylic fiber manufacturing wastewater. The operation conditions were as follows: H2O2 and ferrous dosages were 100–800 mg/L; pH value was 1–7; reaction time was 0.5–4.0 h. In terms of COD removal and biodegradability improvement, the optimal conditions were as follows: ferrous content was 300 mg/L; hydrogen peroxide was 500 mg/L; pH value was 3.0; reaction time was 2 h. With these conditions, the overall COD removal and effluent B/C could arrive at 65.5% and 0.529 respectively. The biodegradability of the acrylic fiber manufacturing wastewater was increased by 429%. It was unnecessary to achieve complete mineralization of the organic compounds into carbon dioxide and water. Partial oxidation of intermediate compounds could minimize the consumption of chemical reagents and result in substantial reduction of COD and toxicity. The further biological treatment was favored by acquiring degradable low molecular weight components.
AU  - Li, Jin
AU  - Luan, Zhaokun
AU  - Yu, Lian
AU  - Ji, Zhongguang
DA  - 2012/01/04/
DO  - 10.1016/j.desal.2011.08.037
DP  - ScienceDirect
J2  - Desalination
KW  - Acrylic fiber manufacturing wastewater
Biodegradability
Fenton process
Hydroxyl
L1  - files/495/Li et al. - 2012 - Pretreatment of acrylic fiber manufacturing wastew.pdf
M1  - 0
PY  - 2012
SN  - 0011-9164
SP  - 62-65
ST  - Pretreatment of acrylic fiber manufacturing wastewater by the Fenton process
T2  - Desalination
TI  - Pretreatment of acrylic fiber manufacturing wastewater by the Fenton process
UR  - http://www.sciencedirect.com/science/article/pii/S0011916411007399
files/494/S0011916411007399.html
VL  - 284
Y2  - 2013/01/15/09:25:35
ID  - 260
ER  - 


TY  - JOUR
AB  - Fenton process was applied to the pretreatment of wastewater from dry-spun acrylic fiber (DAF) manufacturing. The effects of operating parameters including the Fenton reagent dosage, the initial pH value, and the reaction time on the treatment efficiencies of the Fenton oxidation process were observed. About 47.0% of the chemical oxygen demand (COD) removal efficiency was reached under the optimum conditions: hydrogen peroxide of 90.0 mM, ferrous ions of 20.0 mM, pH value of 3.0, and reaction time of 120 min. The COD degradation of the Fenton process followed the pseudo first-order reaction kinetics, and the apparent activation energy E, was determined to be 41.6 kJ mol-1. After the Fenton pretreatment under the optimum reaction conditions, the BOD5/COD ratio of wastewater increased from 0.32 to 0.69, which was suitable for further biological treatment. The improvement of biodegradability was attributed to the removals of aromatics and some other bio-refractory compounds from the wastewater, as confirmed by gas chromatography-mass spectrometry (GC-MS), Fourier transform infrared spectroscopy (FTIR) and fluorescence excitation-emission matrix (EEM) spectroscopy analyses. Fenton process was proven to be an effective method for the pretreatment of DAF manufacturing wastewater prior to biological treatment.
AU  - Wei, Jian
AU  - Song, Yonghui
AU  - Tu, Xiang
AU  - Zhao, Le
AU  - Zhi, Erquan
DA  - 2012/12/22/
DO  - 10.1016/j.cej.2012.12.060
DP  - ScienceDirect
J2  - Chemical Engineering Journal
KW  - Acrylic fiber manufacturing wastewater
Fenton
GC-MS
Kinetic study
Spectrum analysis
L1  - files/492/Wei et al. - Pretreatment of dry-spun acrylic fiber manufacturi.pdf
M1  - 0
PY  - 2012
SN  - 1385-8947
ST  - Pretreatment of dry-spun acrylic fiber manufacturing wastewater by Fenton process
T2  - Chemical Engineering Journal
TI  - Pretreatment of dry-spun acrylic fiber manufacturing wastewater by Fenton process: optimization, kinetics and mechanisms
UR  - http://www.sciencedirect.com/science/article/pii/S138589471201710X
files/491/S138589471201710X.html
Y2  - 2013/01/15/09:25:35
ID  - 261
ER  - 


TY  - JOUR
AB  - Kinetics and efficiency of Fenton’s and ozonation processes for the pretreatment of two landfill leachates (fresh and mature) resulting from municipal waste disposal were studied. Both samples presented high organic load, high toxicity and low biodegradability. These were the reasons why oxidative treatment was proposed. Fresh and mature leachate showed different behaviors in the oxidation experiments. The final extents of removal were attained in comparable time intervals in both oxidation systems. Maximal removal of organics by the Fenton’s oxidation reached more than 50 % according to COD. Zero or first order kinetics were found the best to describe the organic components (in terms of COD and DOC) removal by the Fenton’s oxidation for both landfill leachates. Higher reaction rate values of the Fenton’s oxidation were achieved with fresh leachate samples. The efficiency of initial organics removal with ozone was about 70 % for mature leachate, while in case of the fresh one only 41 % of COD were removed. The best fits of COD and DOC experimental data from oxidation of fresh and mature leachates were obtained by a combined kinetic model. No significant improvement of the biodegradability of landfill leachates was achieved using these treatment procedures. Regarding toxicity, ozonation showed to be more effective than the Fenton’s oxidation. Advanced oxidation experiments confirmed that the Fenton’s oxidation and ozonation are comparable oxidative treatment techniques for the reduction of organic pollution in the investigated municipal landfill leachates. However, neither of them is effective enough to be used as a pretreatment method followed by biological treatment.
AU  - Derco, Ján
AU  - Gotvajn, Andreja Žgajnar
AU  - Zagorc-Končan, Jana
AU  - Almásiová, Beáta
AU  - Kassai, Angelika
DA  - 2010/04/01/
DO  - 10.2478/s11696-009-0116-5
DP  - link.springer.com
J2  - Chem. Pap.
KW  - Biochemistry, general
Biodegradability
Biotechnology
Chemistry/Food Science, general
Fenton’s reaction
Industrial Chemistry/Chemical Engineering
Kinetics
landfill leachate
Materials Science, general
Medicinal Chemistry
ozonation
Toxicity
L1  - files/336/Derco et al. - 2010 - Pretreatment of landfill leachate by chemical oxid.pdf
LA  - en
M1  - 2
PY  - 2010
SN  - 0366-6352, 1336-9075
SP  - 237-245
ST  - Pretreatment of landfill leachate by chemical oxidation processes
T2  - Chemical Papers
TI  - Pretreatment of landfill leachate by chemical oxidation processes
UR  - http://link.springer.com/article/10.2478/s11696-009-0116-5
files/337/s11696-009-0116-5.html
VL  - 64
Y2  - 2013/01/15/04:47:47
ID  - 342
ER  - 


TY  - JOUR
AB  - In the present work the combined pre-treatment of actual olive mill wastewaters by coagulation with natural organic coagulant, such as chitosan, and the advanced oxidation processes, specifically photocatalysis (PC), Fenton (F) and photo-Fenton (PF), was investigated. The optimum removal of total suspended solids (TSSs, 81%) by chitosan coagulation was achieved at actual pH (4.3) for 400 mg L−1 coagulant dose. The maximum organic matter removals by F (85%) and PF (95%) processes were achieved after 2.0 and 1.0 h, respectively by using 15,000/1852 (w/w) ratio of H2O2/FeSO4. On the opposite, in PC experiments, after an initial decrease in the early minutes of the treatment, a subsequent increase versus irradiation time was observed for both UV absorbance at 280 nm and chemical oxygen demand (COD); probably a partial oxidation made some organics detectable only after treatment.
AU  - Rizzo, Luigi
AU  - Lofrano, Giusy
AU  - Grassi, Mariangela
AU  - Belgiorno, Vincenzo
DA  - 2008/11/03/
DO  - 10.1016/j.seppur.2008.07.003
DP  - ScienceDirect
J2  - Separation and Purification Technology
KW  - Fenton
Natural organic coagulants
Organic sludge
Photocatalysis
Photo-Fenton
L1  - files/624/Rizzo et al. - 2008 - Pre-treatment of olive mill wastewater by chitosan.pdf
M1  - 3
PY  - 2008
SN  - 1383-5866
SP  - 648-653
ST  - Pre-treatment of olive mill wastewater by chitosan coagulation and advanced oxidation processes
T2  - Separation and Purification Technology
TI  - Pre-treatment of olive mill wastewater by chitosan coagulation and advanced oxidation processes
UR  - http://www.sciencedirect.com/science/article/pii/S1383586608002761
files/623/S1383586608002761.html
VL  - 63
Y2  - 2013/01/15/14:21:45
ID  - 262
ER  - 


TY  - JOUR
AU  - Özdemir, Celalettin
AU  - Tezcan, Hayrunnisa
AU  - Sahinkaya, Serkan
AU  - Kalipci, Erkan
DA  - 2010/12//
DO  - 10.1002/clen.201000222
DP  - CrossRef
L1  - files/429/1152_ftp.pdf
M1  - 12
PY  - 2010
SN  - 18630650
SP  - 1152-1158
ST  - Pretreatment of Olive Oil Mill Wastewater by Two Different Applications of Fenton Oxidation Processes
T2  - CLEAN - Soil, Air, Water
TI  - Pretreatment of Olive Oil Mill Wastewater by Two Different Applications of Fenton Oxidation Processes
UR  - http://doi.wiley.com/10.1002/clen.201000222
VL  - 38
Y2  - 2012/12/25/09:08:50
ID  - 308
ER  - 


TY  - JOUR
AB  - In this paper, the results of olive oil mill wastewater (OOMW) using physicochemical pre-treatment and Fenton and Fenton-like processes are presented. On the other hand, acute toxicities of raw, physicochemical pre-treated, and Fenton and Fenton-like oxidations applied samples of OOMW on activated sludge microorganisms using respiration inhibition test (ISO 8192) are presented. Chemical pre-treatment (acid cracking and coagulation–flocculation) positively affected the biodegradability and inhibition on activated sludge was considerably removed (&gt;67% COD and &gt;72% total-phenol removal). Fenton and Fenton-like processes showed high COD (&gt;80%) and total-phenol (&gt;85%) removal performance on evaluated effluents. Inhibitory effect of Fenton-like reagents applied samples on activated sludge mixture was considerably removed. In addition to the toxicity, total-phenol and COD removal efficiencies of applied processes, their associated operating costs were also determined in this paper.
AU  - Kiril Mert, Berna
AU  - Yonar, Taner
AU  - Yalili Kiliç, Melike
AU  - Kestioğlu, Kadir
DA  - 2010/02/15/
DO  - 10.1016/j.jhazmat.2009.09.025
DP  - ScienceDirect
J2  - Journal of Hazardous Materials
KW  - Activated sludge inhibition
Advanced oxidation processes (AOPs)
Chemical pre-treatment
Olive oil mill effluent
L1  - files/666/Kiril Mert et al. - 2010 - Pre-treatment studies on olive oil mill effluent u.pdf
M1  - 1–3
PY  - 2010
SN  - 0304-3894
SP  - 122-128
ST  - Pre-treatment studies on olive oil mill effluent using physicochemical, Fenton and Fenton-like oxidations processes
T2  - Journal of Hazardous Materials
TI  - Pre-treatment studies on olive oil mill effluent using physicochemical, Fenton and Fenton-like oxidations processes
UR  - http://www.sciencedirect.com/science/article/pii/S030438940901471X
files/665/S030438940901471X.html
VL  - 174
Y2  - 2013/01/15/14:53:28
ID  - 263
ER  - 


TY  - JOUR
AB  - Chemical probes were used to study the formation of hydroxyl radical in aqueous iron–hydrogen peroxide reaction. Hydroxyl radical formation rate and time dependent concentration were determined in pure water, in aqueous fulvic acid (FA) and humic acid (HA) solutions, and in natural surface waters. Indirect determinations of hydroxyl radical were made by quantitating hydroxyl radical reactions with probe compounds under controlled conditions. High probe concentrations were used to determine radical formation rates and low probe concentrations were used to determine time dependent radical concentration. Two independent probes were used for intercomparison: benzoic acid and 1-propanol. Good agreement between the two probes was observed. Natural water matrices resulted in lower radical formation rates and lower hydroxyl radical concentrations, with observed formation rate and yield in natural waters up to four times lower than in pure water. HA and FA also reduced hydroxyl radical formation under most conditions, although increased radical formation was observed with FA at certain pH values. Hydroxyl radical formation increased linearly with hydrogen peroxide concentration.
AU  - Lindsey, Michele E.
AU  - Tarr, Matthew A.
DA  - 2000/08//
DO  - 10.1016/s0045-6535(99)00296-9
DP  - ScienceDirect
J2  - Chemosphere
KW  - Degradation
Fenton oxidation
Hydrogen peroxide
Hydroxyl radical
Iron
Natural water
L1  - files/331/Lindsey and Tarr - 2000 - Quantitation of hydroxyl radical during Fenton oxi.pdf
M1  - 3
PY  - 2000
SN  - 0045-6535
SP  - 409-417
ST  - Quantitation of hydroxyl radical during Fenton oxidation following a single addition of iron and peroxide
T2  - Chemosphere
TI  - Quantitation of hydroxyl radical during Fenton oxidation following a single addition of iron and peroxide
UR  - http://www.sciencedirect.com/science/article/pii/S0045653599002969
files/330/S0045653599002969.html
VL  - 41
Y2  - 2013/01/15/04:38:31
ID  - 264
ER  - 


TY  - JOUR
AB  - Photochemical and chemical oxidation methods, belonging to a wide group of advanced oxidation processes (AOPs), are extensively studied but still under constant development. The aim of this study was to review the recent developments mainly in UV/H2O2 process and Fenton’s reactions. Ultraviolet (UV) radiation is an essential factor in photochemical oxidation. In the development of UV radiation sources the energy efficiency and the use of toxicant free materials have become major objectives. Also the emitted wavelength plays a significant role. Besides, there are alternatives for UV radiation sources, such as radio frequency (RF) plasmas, which can operate in water without additional chemicals. A remarkable development in the field of chemical oxidation has been novel catalyst materials for Fenton’s reaction enabling the efficient reaction in neutral or almost neutral conditions, instead of pH below 3. In addition, varieties of method integrations, e.g., combinations of AOPs or AOPs integrated to biological processes, and other enhancements such as combining ultrasound (US) with AOP have led to improved water treatment efficiencies.
AU  - Vilhunen, Sari
AU  - Sillanpää, Mika
DA  - 2010/12/01/
DO  - 10.1007/s11157-010-9216-5
DP  - link.springer.com
J2  - Rev Environ Sci Biotechnol
KW  - Advanced oxidation processes
Atmospheric Protection/Air Quality Control/Air Pollution
Environmental Engineering/Biotechnology
Fenton
H2O2
Microbiology
UV radiation
Waste water
Water treatment
L1  - files/285/Vilhunen and Sillanpää - 2010 - Recent developments in photochemical and chemical .pdf
LA  - en
M1  - 4
PY  - 2010
SN  - 1569-1705, 1572-9826
SP  - 323-330
ST  - Recent developments in photochemical and chemical AOPs in water treatment
T2  - Reviews in Environmental Science and Bio/Technology
TI  - Recent developments in photochemical and chemical AOPs in water treatment: a mini-review
UR  - http://link.springer.com/article/10.1007/s11157-010-9216-5
files/286/s11157-010-9216-5.html
VL  - 9
Y2  - 2013/01/15/04:02:29
ID  - 343
ER  - 


TY  - JOUR
AB  - Advanced oxidation processes (AOPs) have led the way in the treatment of aqueous waste and are rapidly becoming the chosen technology for many applications. In this paper, COD reduction potential of leather tanning industry wastewaters by Electro-Fenton (EF) oxidation, as one of the AOPs, was experimentally evaluated. The wastewater sample was taken from an outlet of an equalization basin in a common treatment plant of an organized tannery industrial region in Istanbul, Turkey. Treatment of the wastewater was carried out by an electrochemical batch reactor equipped with two iron electrodes, which were connected parallel to each other. The oxidation process was studied for optimization of H2O2 and the electricity consumptions were observed at different contact times under different pH conditions (3.0, 5.0 and 7.2). In each case, electricity consumption for decreased COD mass was estimated. In this process, COD was reduced by 60–70% within 10 min. By taking into consideration the local sewerage discharge limit, applicability of EF process for the tannery wastewaters was evaluated.
AU  - Kurt, Ugur
AU  - Apaydin, Omer
AU  - Gonullu, M. Talha
DA  - 2007/05/08/
DO  - 10.1016/j.jhazmat.2006.08.065
DP  - ScienceDirect
J2  - Journal of Hazardous Materials
KW  - Advanced oxidation processes
COD
Electro-Fenton
Iron electrodes
Tannery wastewater
L1  - files/648/Kurt et al. - 2007 - Reduction of COD in wastewater from an organized t.pdf
M1  - 1–2
PY  - 2007
SN  - 0304-3894
SP  - 33-40
ST  - Reduction of COD in wastewater from an organized tannery industrial region by Electro-Fenton process
T2  - Journal of Hazardous Materials
TI  - Reduction of COD in wastewater from an organized tannery industrial region by Electro-Fenton process
UR  - http://www.sciencedirect.com/science/article/pii/S0304389406010077
files/647/S0304389406010077.html
VL  - 143
Y2  - 2013/01/15/14:43:50
ID  - 265
ER  - 


TY  - JOUR
AB  - Regeneration studies of wastewater effluent from an organized industrial district (OID) for possible reuse in textile industry as process water was investigated. Advanced treatment methods including Fenton process, polyaluminium chloride (PAC) coagulation and ion exchange were applied on OID effluent. In Fenton process removal efficiencies for suspended solids (SS), chemical oxygen demand (COD), SAC436 (spectral absorption coefficient), SAC525 and SAC620 were determined 61%, 36%, 35%, 49% and 67%, respectively. After Fenton process, wastewater samples were coagulated with PAC. Optimum removal efficiencies for SS, COD, Fe ion, SAC436, SAC525 and SAC620 were determined 83%, 18%, 93%, 32%, 36% and 58%, respectively. Ion exchange experiments were conducted on chemically coagulated wastewater samples to improve the quality of wastewater. Optimum dosage of resins was determined. The experiments revealed that 1:1 resin ratio (20 mL H-type resin:20 mL OH-type resin) gave the best removal rates for the parameters considered in this study. Study results indicated that quality of the wastewater was suitable for the process water characteristics of textile industry and unit wastewater treatment cost was determined as 2.54 €/m3.
AU  - Üstün, Gökhan Ekrem
AU  - Solmaz, Seval Kutlu Akal
AU  - Birgül, Aşkın
DA  - 2007/12//
DO  - 10.1016/j.resconrec.2007.05.006
DP  - ScienceDirect
J2  - Resources, Conservation and Recycling
KW  - Fenton process
Ion exchange
OID wastewater
Process water characteristic
Reuse
Textile industry
L1  - files/357/Üstün et al. - 2007 - Regeneration of industrial district wastewater usi.pdf
M1  - 2
PY  - 2007
SN  - 0921-3449
SP  - 425-440
ST  - Regeneration of industrial district wastewater using a combination of Fenton process and ion exchange—A case study
T2  - Resources, Conservation and Recycling
TI  - Regeneration of industrial district wastewater using a combination of Fenton process and ion exchange—A case study
UR  - http://www.sciencedirect.com/science/article/pii/S0921344907001425
files/356/S0921344907001425.html
VL  - 52
Y2  - 2013/01/15/05:13:56
ID  - 266
ER  - 


TY  - JOUR
AB  - The Fenton method was applied to the removal of chemical oxygen demand using chromate (CODcr) and color from high-strength livestock wastewater in which the initial CODcr was 5000–5700 mg/L. The optimum ratio of H2O2 (mg/L) to the initial CODcr was 1.05 and the optimum molar ratio of H2O2/Fe2+ was 2. The optimum initial pH and the optimum reaction time were 3.5–4 and 30 min, respectively. Under optimal conditions, the removal ratios of CODcr and color of the supernatant after static precipitation of the produced sludge were 88 and 95.4%, respectively. Addition of Fenton's reagents in several aliquots did not affect the efficiencies of CODcr and color removal.
AU  - Lee, Hyunhee
AU  - Shoda, Makoto
DA  - 2008/05/30/
DO  - 10.1016/j.jhazmat.2007.09.097
DP  - ScienceDirect
J2  - Journal of Hazardous Materials
KW  - CODcr removal
Color removal
Fenton method
Livestock wastewater
L1  - files/483/Lee and Shoda - 2008 - Removal of COD and color from livestock wastewater.pdf
M1  - 3
PY  - 2008
SN  - 0304-3894
SP  - 1314-1319
ST  - Removal of COD and color from livestock wastewater by the Fenton method
T2  - Journal of Hazardous Materials
TI  - Removal of COD and color from livestock wastewater by the Fenton method
UR  - http://www.sciencedirect.com/science/article/pii/S030438940701391X
files/482/S030438940701391X.html
VL  - 153
Y2  - 2013/01/15/09:11:11
ID  - 267
ER  - 


TY  - JOUR
AB  - Fenton's reagent was now being used as a post-treatment procedure to eliminate the intractable pollutants in the bleaching effluents from pulp mills. To establish cost-efficient operating conditions for the application of Fenton's reagent, the effects of operating conditions such as the dosages of H2O2, the molar ratio of [Fe2+]/[H2O2], the value of solution pH and the system temperature on the removal of COD were evaluated systematically. The results showed a suitable operating condition that yields 88.7% of COD removal was obtained at [H2O2] = 4COD(mM L−1), [Fe2+]/[H2O2] = 20:1, pH3, 90°C, reaction time 120 min. A kinetic study was carried out using a modified pseudo-first-order model. The results showed the COD removal for bleaching effluents by Fenton's reagent followed the first-order reaction kinetics, and the activation energy Ea was detected to be 1.68 kJ mol−1 based on the experiments performed at different temperatures. In addition, the results of GC/MS analysis showed organic pollutants in effluents were degraded into organic acids of lower molecular weight under the attack of hydroxyl radicals generated in Fenton's reaction. The results of biodegradability assay indicated the bio-toxic substances in the bleaching effluents were eliminated. © 2010 American Institute of Chemical Engineers Environ Prog, 2011
AU  - Wang, Zhaojiang
AU  - Chen, Kefu
AU  - Li, Jun
AU  - Mo, Lihuan
AU  - Wang, Qiang
DA  - 2011
DO  - 10.1002/ep.10458
J2  - Environmental Progress & Sustainable Energy
KW  - chemical oxygen demand
Fenton's Reagent
kinetics
the bleaching effluents
L1  - files/425/Wiley_fenton for wastewater.pdf
M1  - 2
N1  - The following values have no corresponding Zotero field:<br/>journalAbbreviation: Environ. Prog. Sustainable Energy<br/>PB - John Wiley & Sons, Inc.<br/>
PY  - 2011
SN  - 1944-7450
SP  - 168-176
ST  - The removal of COD from bleaching effluents by Fenton's reagent: Effect of system parameters and kinetic study
T2  - Environmental Progress & Sustainable Energy
TI  - The removal of COD from bleaching effluents by Fenton's reagent: Effect of system parameters and kinetic study
UR  - http://dx.doi.org/10.1002/ep.10458
VL  - 30
ID  - 309
ER  - 


TY  - JOUR
AB  - This work describes the application of Fenton's reagent (H2O2/Fe2+) to the removal of chemical oxygen demand (COD) from olive mill wastewater (OMW) in a laboratory-scale batch reactor. The effect of different operational conditions, namely, hydrogen peroxide and ferrous ion concentrations, temperature and initial pH were evaluated. ORP, pH and dissolved oxygen were on-line monitored. Working with an initial pH equal to 3.5, a temperature of 30 °C, a molar ratio H2O2/Fe2+ = 15 and a weight ratio R = H2O2/COD = 1.75 makes possible a COD conversion of 70%. A kinetic study was carried out using a modified pseudo-first-order model. The experiments performed at different temperatures allowed the calculation of the Arrhenius equation parameters and the global activation energy for the pseudo-first-order reaction (28.2 kJ/mol).
AU  - Lucas, Marco S.
AU  - Peres, José A.
DA  - 2009/09/15/
DO  - 10.1016/j.jhazmat.2009.03.002
DP  - ScienceDirect
J2  - Journal of Hazardous Materials
KW  - COD removal
Effluent treatment
Fenton reagent
Kinetic study
Olive mill wastewater
L1  - files/247/Lucas and Peres - 2009 - Removal of COD from olive mill wastewater by Fento.pdf
M1  - 2–3
PY  - 2009
SN  - 0304-3894
SP  - 1253-1259
ST  - Removal of COD from olive mill wastewater by Fenton's reagent
T2  - Journal of Hazardous Materials
TI  - Removal of COD from olive mill wastewater by Fenton's reagent: Kinetic study
UR  - http://www.sciencedirect.com/science/article/pii/S0304389409003847
files/246/S0304389409003847.html
VL  - 168
Y2  - 2013/01/14/10:03:29
ID  - 268
ER  - 


TY  - JOUR
AB  - Abstract This study was designed to decolorize and to reduce COD content in a mixture of four reactive dyes, i.e., Remazol Black 5 (RB5), Remazol Red RB (RR), Remazol Yellow 84 (RY), Remazol Brilliant Blue (RB) using Fenton Oxidation Process (FOP). Optimum pH, temperature, and the doses of FeSO4 and H2O2 were determined. Experiments were conducted on the samples containing a total concentration of 100 mg L?1 (RB + RY), 200 mg L?1 (RB5 + RR), 300 mg L?1 (RB5 + RR + RB + RY), and 400 mg L?1 (RR + RB + RY) dyes considering their actual application doses in dyehouses. Optimum pH was observed as 2.5 at 30°C using 400 mg L?1 FeSO4 and 800 mg L?1 of H2O2 resulting in more than 96% COD and 99% Pt-Co unit of color removal for the mixture of RB5 and RR. The optimum conditions determined were 4.0 pH, 50°C, and 500 mg L?1 FeSO4 applying 1000 mg L?1 H2O2 for the mixture of (RB5 + RR + RB + RY). A 100 mg L?1 solution of a mixture of RB and RY at equal amounts was oxidized using 200 mg L?1 FeSO4 and 300 mg L?1 H2O2 at 3.0 pH and 50°C.
AU  - Meriç, Sureyya
AU  - Kaptan, Deniz
AU  - Tünay, Olcay
DA  - 2003/10/01/
DO  - 10.1081/ese-120023371
J2  - Journal of Environmental Science and Health, Part A
L1  - files/455/ese-120023371.pdf
M1  - 10
N1  - <p>doi: 10.1081/ESE-120023371</p>
The following values have no corresponding Zotero field:<br/>DOI: doi: 10.1081/ESE-120023371<br/>PB - Taylor & Francis<br/>
PY  - 2003
SN  - 1093-4529
SP  - 2241-2250
ST  - Removal of Color and COD from a Mixture of Four Reactive Azo Dyes Using Fenton Oxidation Process
T2  - Journal of Environmental Science and Health, Part A
TI  - Removal of Color and COD from a Mixture of Four Reactive Azo Dyes Using Fenton Oxidation Process
UR  - http://www.tandfonline.com/doi/abs/10.1081/ESE-120023371
VL  - 38
Y2  - 2013/01/14/
ID  - 318
ER  - 


TY  - JOUR
AB  - Pre-treatment of olive mill wastewater (OMW) by Fenton Oxidation with zero-valent iron and hydrogen peroxide was investigated to improve phenolic compounds degradation and the chemical oxygen demand (COD) removal. Experimental procedure is performed with diluted OMW with COD 19 g/L and pH 5.2. The application of zero-valent Fe/H2O2 procedure allows high removal efficiency of pollutants from OMW. The optimal experimental conditions were found to be continuous presence of iron metal, acidic pH (2–4) and 1 M hydrogen peroxide solution. The experimental results show that the removal of 1 g of COD need 0.06 M of H2O2. At pH 1, the maximum COD removal (78%) is achieved after 1 h. Therefore, with a pH value within 2 and 4 the maximum COD removal reached 92%. Phenolic compounds are identified in treated and untreated OMW by gas chromatography coupled to mass spectrometry (GC–MS). The result shows a total degradation of phenolic compounds and an increasing biodegradability of treated OMW.
AU  - Kallel, M.
AU  - Belaid, C.
AU  - Mechichi, T.
AU  - Ksibi, M.
AU  - Elleuch, B.
DA  - 2009/08/01/
DO  - 10.1016/j.cej.2009.01.017
DP  - ScienceDirect
J2  - Chemical Engineering Journal
KW  - Fenton reaction
Olive mill wastewater
Phenolic compounds
Zero-valent iron
L1  - files/609/Kallel et al. - 2009 - Removal of organic load and phenolic compounds fro.pdf
M1  - 2–3
PY  - 2009
SN  - 1385-8947
SP  - 391-395
ST  - Removal of organic load and phenolic compounds from olive mill wastewater by Fenton oxidation with zero-valent iron
T2  - Chemical Engineering Journal
TI  - Removal of organic load and phenolic compounds from olive mill wastewater by Fenton oxidation with zero-valent iron
UR  - http://www.sciencedirect.com/science/article/pii/S1385894709000199
files/608/S1385894709000199.html
VL  - 150
Y2  - 2013/01/15/14:08:40
ID  - 269
ER  - 


TY  - JOUR
AB  - Hydrogen peroxide (H2O2) is a strong oxidant and its application in the treatment of various inorganic and organic pollutants is well established. Still H2O2 alone is not effective for high concentrations of certain refractory contaminants because of low rates of reaction at reasonable H2O2 concentrations. Improvements can be achieved by using transition metal salts (e.g. iron salts) or ozone and UV-light can activate H2O2 to form hydroxyl radicals, which are strong oxidants. Oxidation processes utilising activation of H2O2 by iron salts, classically referred to as Fenton’s reagent is known to be very effective in the destruction of many hazardous organic pollutants in water. The first part of our paper presents a literature review of the various Fenton reagent reactions which constitute the overall kinetic scheme with all possible side reactions. It also summarises previous publications on the relationships between the dominant parameters (e.g. [H2O2], [Fe2+], …). The second part of our review discusses the possibility of improving sludge dewaterability using Fenton’s reagent.
AU  - Neyens, E.
AU  - Baeyens, J.
DA  - 2003/03/17/
DO  - 10.1016/s0304-3894(02)00282-0
DP  - ScienceDirect
J2  - Journal of Hazardous Materials
KW  - Dewatering
Fenton’s reagent
Peroxidation
Sludge
Wastewater treatment
L1  - files/158/Neyens and Baeyens - 2003 - A review of classic Fenton’s peroxidation as an ad.pdf
M1  - 1–3
PY  - 2003
SN  - 0304-3894
SP  - 33-50
ST  - A review of classic Fenton’s peroxidation as an advanced oxidation technique
T2  - Journal of Hazardous Materials
TI  - A review of classic Fenton’s peroxidation as an advanced oxidation technique
UR  - http://www.sciencedirect.com/science/article/pii/S0304389402002820
files/157/S0304389402002820.html
VL  - 98
Y2  - 2013/01/14/04:20:24
ID  - 175
ER  - 


TY  - JOUR
AB  - In the first part of this two article series on the imperative technologies for wastewater treatment, a review of oxidation processes operating at ambient conditions was presented. It has been observed that none of the methods can be used individually in wastewater treatment applications with good economics and high degree of energy efficiency. Moreover, the knowledge required for the large-scale design and application is perhaps lacking. In the present work, an overview of hybrid methods (the majority are a combination of advanced oxidation processes) has been presented. Hybrid methods viz Ultrasound/H2O2 or ozone, UV/H2O2 or ozone, Ozone/H2O2, Sono-photochemical oxidation, Photo–Fenton processes, catalytic advanced oxidation processes, use of advanced oxidation processes in conjunction with biological oxidation, SONIWO (sonochemical degradation followed by wet air oxidation), and CAV-OX have been discussed with specific reference to the principles behind the expected synergism, different reactor configurations used and optimum considerations for the operating and geometric parameters. An overview of different chemicals degraded has been presented. Some of the important works evaluating the application of these processes to real effluents have been described in detail. Some guidelines for the future work required to facilitate efficient large-scale operation have been given. A model effluent treatment scheme based on the various techniques discussed in the present work has been presented.
AU  - Gogate, Parag R.
AU  - Pandit, Aniruddha B.
DA  - 2004/03//
DO  - 10.1016/s1093-0191(03)00031-5
DP  - ScienceDirect
J2  - Advances in Environmental Research
KW  - Catalytic advanced oxidation processes
Cavitation oxidation process (CAV–OX)
Hybrid methods
Ozone/H2O2
Photo–Fenton processes
Sonication followed by wet air oxidation (SNIWO)
Sono-photochemical oxidation
Ultrasound/H2O2 or ozone
Use of advanced oxidation processes in conjunction with biological oxidation
UV/H2O2 or ozone
Wastewater treatment
L1  - files/570/Gogate and Pandit - 2004 - A review of imperative technologies for wastewater.pdf
M1  - 3–4
PY  - 2004
SN  - 1093-0191
SP  - 553-597
ST  - A review of imperative technologies for wastewater treatment II
T2  - Advances in Environmental Research
TI  - A review of imperative technologies for wastewater treatment II: hybrid methods
UR  - http://www.sciencedirect.com/science/article/pii/S1093019103000315
files/569/S1093019103000315.html
VL  - 8
Y2  - 2013/01/15/13:31:11
ID  - 312
ER  - 


TY  - JOUR
AB  - The removal of the herbicide simazine (2-chloro-4,6-bis(ethylamino)-s-triazine) in aqueous phase has been carried out continuously by means of Fenton’s reagent (Fe(II)+H2O2). The influence of the main operating parameters, Fe(II) concentration (5.0×10−5 to 4.0×10−4 M), pH (2–6) and temperature (10–30 °C) has been studied. Based on HPLC analysis, the main route of simazine removal has been proposed to be the dechlorination reaction to generate 2-hydroxy-4,6-bis(ethylamino)-s-triazine. Nevertheless the dealkylated first intermediate of the herbicide was also identified by chromatography techniques. By means of a pseudoempirical model based on the classic Fenton’s chemistry and the mass balances for a continuos perfectly mixed reactor, the theoretical evolution profiles of the species involved in the process have been calculated.
AU  - Rivas, F. J.
AU  - Navarrete, V.
AU  - Beltrán, F. J.
AU  - Garcı́a-Araya, J. F.
DA  - 2004/04/08/
DO  - 10.1016/j.apcatb.2003.11.009
DP  - ScienceDirect
J2  - Applied Catalysis B: Environmental
KW  - Fenton
Herbicides
Hydrogen peroxide
Kinetic modelling
Simazine
Water treatment
L1  - files/519/Rivas et al. - 2004 - Simazine Fenton’s oxidation in a continuous reacto.pdf
M1  - 4
PY  - 2004
SN  - 0926-3373
SP  - 249-258
ST  - Simazine Fenton’s oxidation in a continuous reactor
T2  - Applied Catalysis B: Environmental
TI  - Simazine Fenton’s oxidation in a continuous reactor
UR  - http://www.sciencedirect.com/science/article/pii/S0926337303005393
files/518/S0926337303005393.html
VL  - 48
Y2  - 2013/01/15/09:43:56
ID  - 270
ER  - 


TY  - JOUR
AB  - Simple measurements of H2O2 concentration or CO2 evolution were used to evaluate the effectiveness of the use of Fenton's reagent to mineralize organic compounds in water and soil contaminated by crude petroleum. This methodology is suitable for application in small treatment and remediation facilities. Reagent concentrations of H2O2 and Fe2+ were found to influence the reaction time and temperature, as well as the degree of mineralization and biodegradability of the sample contaminants. Some H2O2/Fe2+ combinations (H2O2 greater than 10% and Fe2+ greater than 50 mM) resulted in a strong exothermic reaction, which causes peroxide degradation and violent gas liberation. Up to 75% TOC removal efficiency was attained in water and 70% in soil when high H2O2 (20%) and low Fe2+ (1 mM) concentrations were used. Besides increasing the degree of mineralization, the Fenton's reaction enhances the biodegradability of petroleum compounds (BOD5/COD ratios) by a factor of up to 3.8 for contaminated samples of both water and soil. Our experiments showed that low reagent concentrations (1% H2O2 and 1 mM Fe2+) were sufficient to start the degradation process, which could be continued using microorganisms. This leads to a decrease in reagent costs in the treatment of petroleum-contaminated water and soil samples. The simple measurements of H2O2 concentration or CO2 evolution were effective to evaluate the Fenton's reaction efficiency.
AU  - Mater, L.
AU  - Rosa, E. V. C.
AU  - Berto, J.
AU  - Corrêa, A. X. R.
AU  - Schwingel, P. R.
AU  - Radetski, C. M.
DA  - 2007/10/22/
DO  - 10.1016/j.jhazmat.2007.04.005
DP  - ScienceDirect
J2  - Journal of Hazardous Materials
KW  - Crude petroleum mineralization
Fenton's reagent
Petroleum-contaminated water and soil
L1  - files/266/Mater et al. - 2007 - A simple methodology to evaluate influence of H2O2.pdf
M1  - 2
PY  - 2007
SN  - 0304-3894
SP  - 379-386
ST  - A simple methodology to evaluate influence of H2O2 and Fe2+ concentrations on the mineralization and biodegradability of organic compounds in water and soil contaminated with crude petroleum
T2  - Journal of Hazardous Materials
TI  - A simple methodology to evaluate influence of H2O2 and Fe2+ concentrations on the mineralization and biodegradability of organic compounds in water and soil contaminated with crude petroleum
UR  - http://www.sciencedirect.com/science/article/pii/S0304389407004591
files/265/S0304389407004591.html
VL  - 149
Y2  - 2013/01/15/03:44:34
ID  - 176
ER  - 


TY  - JOUR
AU  - Pikaev, A. K.
DA  - 2001/01/01/
DO  - 10.1023/a:1026708604843
DP  - link.springer.com
J2  - High Energy Chemistry
KW  - Physical Chemistry
L1  - files/282/Pikaev - 2001 - Sixth International Conference on Advanced Oxidati.pdf
LA  - en
M1  - 1
PY  - 2001
SN  - 0018-1439, 1608-3148
SP  - 50-54
ST  - Sixth International Conference on Advanced Oxidation Technologies for Water and Air Remediation
T2  - High Energy Chemistry
TI  - Sixth International Conference on Advanced Oxidation Technologies for Water and Air Remediation
UR  - http://link.springer.com/article/10.1023/A%3A1026708604843
files/283/A1026708604843.html
VL  - 35
Y2  - 2013/01/15/04:02:29
ID  - 344
ER  - 


TY  - JOUR
AB  - The decolourization and mineralization of two reactive azo dyes, Procion Red H-E7B (CI Reactive Red 141) and Cibacron Red FN-R (CI Reactive Red 238), under Fenton's and photo-Fenton's conditions have been investigated. Some parameters, like temperature, initial concentrations of Fe(II) and H2O2 and the use of natural or artificial light were evaluated aiming to find the optimal conditions to promote the efficient degradation of the dyes. The experimental results showed that the Fenton's process run under solar light was the most effective. Pseudo-first order degradation rate constants were obtained from batch experimental data. It is suggested that Fenton's and photo-Fenton's type reactions are viable techniques for the treatment of such types of reactive dyes, according to the high levels of colour, aromatic content (UV254) and DOC removal.
AU  - Núñez, Lluís
AU  - García-Hortal, José Antonio
AU  - Torrades, Francesc
DA  - 2007
DO  - 10.1016/j.dyepig.2006.07.014
DP  - ScienceDirect
J2  - Dyes and Pigments
KW  - Decolourization and mineralization
Fenton's process
Kinetics
Photo-Fenton's process
Reactive azo dyes
Solar light
L1  - files/540/Núñez et al. - 2007 - Study of kinetic parameters related to the decolou.pdf
M1  - 3
PY  - 2007
SN  - 0143-7208
SP  - 647-652
ST  - Study of kinetic parameters related to the decolourization and mineralization of reactive dyes from textile dyeing using Fenton and photo-Fenton processes
T2  - Dyes and Pigments
TI  - Study of kinetic parameters related to the decolourization and mineralization of reactive dyes from textile dyeing using Fenton and photo-Fenton processes
UR  - http://www.sciencedirect.com/science/article/pii/S0143720806002981
files/539/S0143720806002981.html
VL  - 75
Y2  - 2013/01/15/09:51:52
ID  - 271
ER  - 


TY  - JOUR
AB  - In this paper, the removal of phenol from simulated wastewater was studied using gas–liquid fluidized bed with the Fenton reagent. The factors that affect the removal rate of phenol were investigated, including the initial concentrations of hydrogen peroxide [H2O2] and [Fe2+], the molar ratio of [Fe2+]/[H2O2], pH value, temperatures, reaction time, and the ventilation volume. It was found that the optimal operating conditions existed as: [H2O2] = 12 mmol/L, [H2O2]/[Fe2+] = 4:1, pH = 4, T = 60 °C, reaction time of 30 min, and a ventilation volume of 0.12 m3/h. Under these conditions, the phenol removal rate of about 96% was obtained.
AU  - Zhou, Li
AU  - Hu, Jianxun
AU  - Zhong, Hong
AU  - Li, Xueping
DA  - 2012/03//
DO  - 10.1016/j.cherd.2011.07.015
DP  - ScienceDirect
J2  - Chemical Engineering Research and Design
KW  - Fenton reagent
Fluidized-bed
Phenol removal rate
Phenol wastewater
L1  - files/188/Zhou et al. - 2012 - Study of phenol removal using fluidized-bed Fenton.pdf
M1  - 3
PY  - 2012
SN  - 0263-8762
SP  - 377-382
ST  - Study of phenol removal using fluidized-bed Fenton process
T2  - Chemical Engineering Research and Design
TI  - Study of phenol removal using fluidized-bed Fenton process
UR  - http://www.sciencedirect.com/science/article/pii/S0263876211002681
files/187/S0263876211002681.html
VL  - 90
Y2  - 2013/01/14/04:51:18
ID  - 272
ER  - 


TY  - JOUR
AB  - The feasibility of treating acrylonitrile–butadiene–styrene (ABS) resin manufacturing wastewater by Fenton oxidation treatment was investigated. The experiments were conducted in six different operating modes. For all tests, total dosage of ferrous (Fe2+) salt and hydrogen peroxide (H2O2) was kept at 2000 mg L− 1 and 4000 mg L− 1, respectively and the total reaction time was maintained at 160 min. The kinetics of the decomposition of organic matter in terms of dissolved chemical oxygen demand (DCOD) by H2O2 followed the pseudo-first order reaction. For DCOD decomposition, the removal rate constant equation of DCOD, k1 = 2.95 × 10− 6[H2O2]00.17[Fe2+]01.60 was obtained, where k1 is the reaction rate coefficient of DOCD decomposition. The consumption rate constant equation of H2O2, k2 = 1.85 × 10− 3[H2O2]0− 1.70[Fe2+]02.90 was obtained, where k2 is the reaction rate coefficient of hydrogen peroxide consumption. Batch and semi-batch studies indicated that oxidation with Fenton's reagent is feasible for treating ABS wastewater.
AU  - Popuri, Srinivasa R.
AU  - Chang, Chia-Yuan
AU  - Xu, Jia
DA  - 2011/08/15/
DO  - 10.1016/j.desal.2011.04.017
DP  - ScienceDirect
J2  - Desalination
KW  - ABS resin wastewater
Fenton reaction
Kinetic study
Residual hydrogen peroxide
L1  - files/354/Popuri et al. - 2011 - A study on different addition approach of Fenton's.pdf
M1  - 1–3
PY  - 2011
SN  - 0011-9164
SP  - 141-146
ST  - A study on different addition approach of Fenton's reagent for DCOD removal from ABS wastewater
T2  - Desalination
TI  - A study on different addition approach of Fenton's reagent for DCOD removal from ABS wastewater
UR  - http://www.sciencedirect.com/science/article/pii/S0011916411003407
files/353/S0011916411003407.html
VL  - 277
Y2  - 2013/01/15/05:13:56
ID  - 177
ER  - 


TY  - JOUR
AB  - The thermal enhancement of the formation of OH by the hv/Fe(III)/H2O2 system (including the Fe(III)/H2O2 system) was quantitatively investigated with reaction temperatures ranging from 25 to 50 °C. A temperature dependent kinetic model for the hv/Fe(III)/H2O2 system, incorporating 12 major reactions with no fitted rate constants or activation energies, was developed, and successfully explained the experimental measurements. Particularly, the thermal enhancement of Fe(OH)2+ photolysis which is the most significant step in the hv/Fe(III)/H2O2 system was effectively explained by two factors; (1) the variation of the Fe(OH)2+ concentration with temperature, and (2) the temperature dependence of the quantum yield for Fe(OH)2+ photolysis (measured activation energy=11.4 kJ mol−1). Although in both the hv/Fe(III)/H2O2 and Fe(III)/H2O2 systems, elevated temperatures enhanced the formation of OH, the thermal enhancement was much higher in the dark Fe(III)/H2O2 system than the hv/Fe(III)/H2O2 system. Furthermore, it was found that the relative thermal enhancement of the formation of OH in the presence of OH scavengers (tert-butyl alcohol) was magnified in the Fe(III)/H2O2 system but was not in the hv/Fe(III)/H2O2 system.
AU  - Lee, Changha
AU  - Yoon, Jeyong
DA  - 2004/09//
DO  - 10.1016/j.chemosphere.2004.04.047
DP  - ScienceDirect
J2  - Chemosphere
KW  - Advanced oxidation process
Fenton and photo-Fenton reactions
Hydroxyl radical
Reaction temperature
L1  - files/603/Lee and Yoon - 2004 - Temperature dependence of hydroxyl radical formati.pdf
M1  - 10
PY  - 2004
SN  - 0045-6535
SP  - 923-934
ST  - Temperature dependence of hydroxyl radical formation in the hv/Fe3+/H2O2 and Fe3+/H2O2 systems
T2  - Chemosphere
TI  - Temperature dependence of hydroxyl radical formation in the hv/Fe3+/H2O2 and Fe3+/H2O2 systems
UR  - http://www.sciencedirect.com/science/article/pii/S0045653504003157
files/602/S0045653504003157.html
VL  - 56
Y2  - 2013/01/15/14:04:53
ID  - 273
ER  - 


TY  - JOUR
AB  - Water-based paint wastewater which is formed during the coating step of metal surfaces performed with various spray processes include binders, pigments and additives. Binders and other additives may also affect the toxicity of the paint depending on the specific characteristics of the paint. This study deals with Water-based paint wastewater, which is hard to treat. Fenton oxidation process was principally used to treat the wastewater. Treatability runs were carried out by using rust (oxidized iron) particles obtained as a waste of the metal rolling process, as the Fenton’s catalyst. In order to change the variables such as dimensions of the column, packing material size, reactive dosage, pH value and reaction time, the experiments on the basis of packed columns and mixed reactors were carried out to increase the COD removal. COD eliminations with pH adjustment were about 20%. With the contribution of Fenton process in both column and mixed-reactor studies, the COD removal was improved by about 80%.
AU  - Kurt, Ugur
AU  - Avsar, Yasar
AU  - Talha Gonullu, M.
DA  - 2006/08//
DO  - 10.1016/j.chemosphere.2005.11.026
DP  - ScienceDirect
J2  - Chemosphere
KW  - COD removal
Fenton
Rust particles
Water-based paint wastewater
L1  - files/718/Kurt et al. - 2006 - Treatability of water-based paint wastewater with .pdf
M1  - 9
PY  - 2006
SN  - 0045-6535
SP  - 1536-1540
ST  - Treatability of water-based paint wastewater with Fenton process in different reactor types
T2  - Chemosphere
TI  - Treatability of water-based paint wastewater with Fenton process in different reactor types
UR  - http://www.sciencedirect.com/science/article/pii/S0045653505013809
files/717/S0045653505013809.html
VL  - 64
Y2  - 2013/01/15/16:15:33
ID  - 274
ER  - 


TY  - JOUR
AB  - In this study the treatment of coking wastewater was investigated by an advanced Fenton oxidation process using iron powder and hydrogen peroxide. Particular attention was paid to the effect of initial pH, dosage of H2O2 and to improvement in biodegradation. The results showed that higher COD and total phenol removal rates were achieved with a decrease in initial pH and an increase in H2O2 dosage. At an initial pH of less than 6.5 and H2O2 concentration of 0.3 M, COD removal reached 44–50% and approximately 95% of total phenol removal was achieved at a reaction time of 1 h. The oxygen uptake rate of the effluent measured at a reaction time of 1 h increased by approximately 65% compared to that of the raw coking wastewater. This indicated that biodegradation of the coking wastewater was significantly improved. Several organic compounds, including bifuran, quinoline, resorcinol and benzofuranol were removed completely as determined by GC–MS analysis. The advanced Fenton oxidation process is an effective pretreatment method for the removal of organic pollutants from coking wastewater. This process increases biodegradation, and may be combined with a classical biological process to achieve effluent of high quality.
AU  - Chu, Libing
AU  - Wang, Jianlong
AU  - Dong, Jing
AU  - Liu, Haiyang
AU  - Sun, Xulin
DA  - 2012/01//
DO  - 10.1016/j.chemosphere.2011.09.007
DP  - ScienceDirect
J2  - Chemosphere
KW  - Advanced oxidation process
Coking wastewater
Fenton oxidation
Hydrogen peroxide
Iron powder
L1  - files/67/Chu et al. - 2012 - Treatment of coking wastewater by an advanced Fent.pdf
M1  - 4
PY  - 2012
SN  - 0045-6535
SP  - 409-414
ST  - Treatment of coking wastewater by an advanced Fenton oxidation process using iron powder and hydrogen peroxide
T2  - Chemosphere
TI  - Treatment of coking wastewater by an advanced Fenton oxidation process using iron powder and hydrogen peroxide
UR  - http://www.sciencedirect.com/science/article/pii/S0045653511010393
files/66/S0045653511010393.html
VL  - 86
Y2  - 2013/01/13/13:54:18
ID  - 275
ER  - 


TY  - JOUR
AB  - For the first time, hydrodynamic cavitation induced by a liquid whistle reactor (LWR) has been used in conjunction with the advanced Fenton process (AFP) for the treatment of real industrial wastewater. Semi-batch experiments in the LWR were designed to investigate the performance of the process for two different industrial wastewater samples. The effect of various operating parameters such as pressure, H2O2 concentration and the initial concentration of industrial wastewater samples on the extent of mineralization as measured by total organic carbon (TOC) content have been studied with the aim of maximizing the extent of degradation. It has been observed that higher pressures, sequential addition of hydrogen peroxide at higher loadings and lower concentration of the effluent are more favourable for a rapid TOC mineralization. In general, the novel combination of hydrodynamic cavitation with AFP results in about 60–80% removal of TOC under optimized conditions depending on the type of industrial effluent samples. The combination described herein is most useful for treatment of bio-refractory materials where the diminution in toxicity can be achieved up to a certain level and then conventional biological oxidation can be employed for final treatment. The present work is the first to report the use of a hydrodynamic cavitation technique for real industrial wastewater treatment.
AU  - Chakinala, Anand G.
AU  - Gogate, Parag R.
AU  - Burgess, Arthur E.
AU  - Bremner, David H.
DA  - 2008/01//
DO  - 10.1016/j.ultsonch.2007.01.003
DP  - ScienceDirect
J2  - Ultrasonics Sonochemistry
KW  - Advanced Fenton process
Hydrodynamic cavitation
Industrial wastewater treatment
Optimization
L1  - files/633/Chakinala et al. - 2008 - Treatment of industrial wastewater effluents using.pdf
M1  - 1
PY  - 2008
SN  - 1350-4177
SP  - 49-54
ST  - Treatment of industrial wastewater effluents using hydrodynamic cavitation and the advanced Fenton process
T2  - Ultrasonics Sonochemistry
TI  - Treatment of industrial wastewater effluents using hydrodynamic cavitation and the advanced Fenton process
UR  - http://www.sciencedirect.com/science/article/pii/S1350417707000089
files/632/S1350417707000089.html
VL  - 15
Y2  - 2013/01/15/14:30:01
ID  - 276
ER  - 


TY  - JOUR
AB  - Performance of a full-scale combined treatment plant for jean-wash wastewater (JWW) was investigated. The combined process consisted of chemical coagulation, hydrolysis/acidification and Fenton oxidation. Chemical coagulation treatment with polymeric ferric sulfate (PFS)/lime alone proved to be effective in removing the COD (&gt;70%) and part of the color (&gt;50%) from the JWW. Fenton oxidation combined with hydrolysis/acidification as pretreatment offered a noticeable BOD removal efficiency. The average removal efficiencies for COD, BOD, SS, color and aromatic compounds of the combined process were about 95%, 94%, 97%, 95% and 90%, respectively, with the average effluent quality of COD 58 mg/L, BOD 19 mg/L, SS 4 mg/L and color 15(multiple), consistent with the national discharge limits for textile wastewater. The result indicated that the combined procedure could offer an attractive solution for JWW treatment with considerable synergistic advantages.
AU  - Wang, Xiangying
AU  - Zeng, Guangming
AU  - Zhu, Jianlin
DA  - 2008/05/01/
DO  - 10.1016/j.jhazmat.2007.09.030
DP  - ScienceDirect
J2  - Journal of Hazardous Materials
KW  - chemical coagulation
Fenton oxidation
Hydrolysis/acidification
Jean-wash wastewater
L1  - files/663/Wang et al. - 2008 - Treatment of jean-wash wastewater by combined coag.pdf
M1  - 1–2
PY  - 2008
SN  - 0304-3894
SP  - 810-816
ST  - Treatment of jean-wash wastewater by combined coagulation, hydrolysis/acidification and Fenton oxidation
T2  - Journal of Hazardous Materials
TI  - Treatment of jean-wash wastewater by combined coagulation, hydrolysis/acidification and Fenton oxidation
UR  - http://www.sciencedirect.com/science/article/pii/S0304389407013143
files/662/S0304389407013143.html
VL  - 153
Y2  - 2013/01/15/14:53:28
ID  - 277
ER  - 


TY  - JOUR
AB  - In recent years, studies of leachate treatment by conventional Fenton, photo-Fenton and electro-Fenton processes have indicated that these methods can effectively reduce concentrations of organic contaminants and color. In addition, the process can increase the biodegradable fraction of organic constituents in leachate, particularly in mature or biologically recalcitrant leachate. Oxidation and coagulation both play important roles in the removal of organics. Initial pH, dosages of Fenton reagents, aeration, final pH, reagent addition mode, temperature, and UV irradiation may influence final treatment efficiency. In this paper, current knowledge of performance and economics of Fenton processes for treatment of landfill leachate as reported for laboratory, pilot and full-scale studies is reviewed, with the conclusion that the Fenton process is an important and competitive technology for the treatment or pretreatment of landfill leachate.
AU  - Deng, Yang
AU  - Englehardt, James D.
DA  - 2006/12//
DO  - 10.1016/j.watres.2006.08.009
DP  - ScienceDirect
J2  - Water Research
KW  - Coagulation
Fenton treatment
landfill leachate
Oxidation
L1  - files/558/Deng and Englehardt - 2006 - Treatment of landfill leachate by the Fenton proce.pdf
M1  - 20
PY  - 2006
SN  - 0043-1354
SP  - 3683-3694
ST  - Treatment of landfill leachate by the Fenton process
T2  - Water Research
TI  - Treatment of landfill leachate by the Fenton process
UR  - http://www.sciencedirect.com/science/article/pii/S0043135406004726
files/557/S0043135406004726.html
VL  - 40
Y2  - 2013/01/15/13:04:02
ID  - 278
ER  - 


TY  - JOUR
AB  - Degradation of leather industry wastewater by sole aerobic treatment incorporating Thiobacillus ferrooxidans, Fenton's reagents, and combined treatment was investigated in this study. The sole treatment by Fenton's oxidation involving the introduction of 6 g FeSO4 and 266 g H2O2 in a liter of wastewater at pH of 3.5 and 30 °C for 30 min at batch conditions reduced COD, BOD5, sulfide, total chromium and color up to 69%, 72%, 88%, 5%, 100% and T. ferrooxidans alone showed maximum reduction to an extent of 77, 80, 85, 52, 89, respectively, in 21 d treatment at pH 2.5, FeSO4 16 g/L and temperature of 30 °C. The combined treatment at batch conditions involving 30 min chemical treatment by Fenton's oxidation followed by 72 h biochemical treatment by T. ferrooxidans at batch conditions gave rise up to 93%, 98%, 72%, 62% and 100% removal efficiencies of COD, BOD, sulfide, chromium and color at pH of 2.5 and 30 °C. Decrease in photo absorption of the Fenton's reagent treated samples, as compared to the banks, at 280, 350 and 470 nm wave lengths was observed. This may be the key factor for stimulating the biodegradation by T. ferrooxidans.
AU  - Mandal, Tamal
AU  - Dasgupta, Dalia
AU  - Mandal, Subhasis
AU  - Datta, Siddhartha
DA  - 2010/08/15/
DO  - 10.1016/j.jhazmat.2010.04.014
DP  - ScienceDirect
J2  - Journal of Hazardous Materials
KW  - Chromium
COD
Fenton's reagents
Leather industrial wastewater
Sulfide
T. ferrooxidans
L1  - files/651/Mandal et al. - 2010 - Treatment of leather industry wastewater by aerobi.pdf
M1  - 1–3
PY  - 2010
SN  - 0304-3894
SP  - 204-211
ST  - Treatment of leather industry wastewater by aerobic biological and Fenton oxidation process
T2  - Journal of Hazardous Materials
TI  - Treatment of leather industry wastewater by aerobic biological and Fenton oxidation process
UR  - http://www.sciencedirect.com/science/article/pii/S0304389410004607
files/650/S0304389410004607.html
VL  - 180
Y2  - 2013/01/15/14:43:50
ID  - 279
ER  - 


TY  - JOUR
AU  - Lucas, Marco
AU  - Peres, Jose
DA  - 2009/01//
DO  - 10.1080/10934520802539889
DP  - CrossRef
L1  - files/444/10934520802539889.pdf
M1  - 2
PY  - 2009
SN  - 1093-4529
SP  - 198-205
ST  - Treatment of olive mill wastewater by a combined process
T2  - Journal of Environmental Science and Health, Part A
TI  - Treatment of olive mill wastewater by a combined process: Fenton's reagent and chemical coagulation
UR  - http://login.oaresciences.org/whalecomwww.tandfonline.com/whalecom0/doi/full/10.1080/10934520802539889
files/263/10934520802539889.html
VL  - 44
Y2  - 2013/01/14/10:40:11
ID  - 319
ER  - 


TY  - JOUR
AB  - Wastewater from olive oil mills has been treated by means of the Fe(II)/H2O2 system (Fenton's reagent). Typical operating variables such as reagent concentration (CH2O2 = 1.0?0.2 M; CFe(II) = 0.01?0.1 M) and temperature (T = 293?323 K) exerted a positive influence on the chemical oxygen demand and total carbon removal. The optimum working pH was found to be in the range 2.5?3.0. The exothermic nature of the process involved a significant increase of the temperature of the reaction media. The process was well simulated by a semiempirical reaction mechanism based on the classic Fenton chemistry. From the model, the reaction between ferric iron and hydrogen peroxide [k = 1.8 ? 1015 exp((?12577 ± 1248)/T)] was suggested to be the controlling step of the system. Also, the simultaneous inefficient decomposition of hydrogen peroxide [k = 6.3 ? 1012 exp((?11987 ± 2414)/T)] into water and oxygen was believed to play an important role in the process. On the basis of stoichiometric calculations for hydrogen peroxide consumption, an estimation of the process economy has been completed. Keywords: Fenton's reagent; olive oil mill wastewater; kinetics; iron; hydrogen peroxide; environmental remediation
AU  - Rivas, Francisco J.
AU  - Beltrán, Fernando J.
AU  - Gimeno, Olga
AU  - Frades, Jesus
DA  - 2001/04/01/
DO  - 10.1021/jf001223b
DP  - ACS Publications
J2  - J. Agric. Food Chem.
L1  - files/671/Rivas et al. - 2001 - Treatment of Olive Oil Mill Wastewater by Fenton's.pdf
M1  - 4
PY  - 2001
SN  - 0021-8561
SP  - 1873-1880
ST  - Treatment of Olive Oil Mill Wastewater by Fenton's Reagent
T2  - Journal of Agricultural and Food Chemistry
TI  - Treatment of Olive Oil Mill Wastewater by Fenton's Reagent
UR  - http://dx.doi.org/10.1021/jf001223b
files/672/jf001223b.html
VL  - 49
Y2  - 2013/01/15/15:04:40
ID  - 310
ER  - 


TY  - JOUR
AB  - The study reported the application of the photo-Fenton process for the treatment of simulated industrial wastewater upon pretreatment by the dark-Fenton process. The process efficiency which depends on several important process parameters such as initial pH, iron catalyst and oxidant concentration, and the UV irradiation type, was investigated. To consider the combined effects of studied process parameters, three-factor three-level Box–Behnken experimental design combined with response surface modeling was applied. The quadratic models predicting the mineralization of simulated industrial wastewater by the applied photo-Fenton processes were developed. ANOVA was applied to evaluate the significance of models and models’ components. The obtained results indicated that both models can be characterized as highly accurate and predictive for the mineralization of simulated industrial wastewater. Our results show that both photo-Fenton processes can be successfully applied for the treatment of the studied simulated industrial wastewater. The presence of oxalates in simulated industrial wastewater strongly influenced the conditions for the maximal efficiency of applied photo-Fenton processes regarding the type of UV irradiation. The optimal conditions were determined to be: initial pH 3.88, [Fe2+] = 5.01 mM (along with [Fe3+] = 8.0 mM) and [H2O2] = 30 mM in the case of photo-Fenton process operated with UV-C irradiation; and pH 1.9, [Fe2+] = 8.39 mM (along with [Fe3+] = 8.0 mM) and [H2O2] = 30 mM in the case of UV-A light application. The “pseudo”-second order mineralization kinetic of simulated industrial wastewater was determined in both cases with the calculated rate constants at determined optimal conditions: k1obs = 12.94 × 10−2 M−1 s−1 and k2obs = 9.71 × 10−2 M−1 s−1 for UV-C/Fe/H2O2 and UV-A/Fe/H2O2 processes, respectively.
AU  - Dopar, Marina
AU  - Kusic, Hrvoje
AU  - Koprivanac, Natalija
DA  - 2011/09/15/
DO  - 10.1016/j.cej.2010.09.070
DP  - ScienceDirect
J2  - Chemical Engineering Journal
KW  - Design of experiments
Ferrioxalate
Industrial wastewater
Photo-Fenton
Process optimization
Statistical analysis
L1  - files/182/Dopar et al. - 2011 - Treatment of simulated industrial wastewater by ph.pdf
M1  - 2
PY  - 2011
SN  - 1385-8947
SP  - 267-279
ST  - Treatment of simulated industrial wastewater by photo-Fenton process. Part I
T2  - Chemical Engineering Journal
TI  - Treatment of simulated industrial wastewater by photo-Fenton process. Part I: The optimization of process parameters using design of experiments (DOE)
UR  - http://www.sciencedirect.com/science/article/pii/S1385894710009009
files/181/S1385894710009009.html
VL  - 173
Y2  - 2013/01/14/04:46:48
ID  - 280
ER  - 


TY  - JOUR
AB  - The aim of the study was to develop the mechanistic model describing the behavior of photo-Fenton process treating the simulated industrial wastewater containing oxalates and formates. In Part I of the study, the optimal conditions for each of applied photo-Fenton processes (UV-C/Fe/H2O2 and UV-A/Fe/H2O2) were determined and used in this study for model development and verification. The mechanistic model simulates the influence of various factors: the type of UV irradiation, the changes in concentrations of pollutants, catalysts and oxidant, on photo-Fenton process performance. pH dependent equilibrium of ferrous, ferric, oxalate and formate species was simulated as well. The model was tested to evaluate its accuracy in predicting the system behavior at different pollutant concentrations. Good agreement of the data predicted by model and the empirically obtained values was confirmed by calculated standard deviation for each experimentally monitored parameter. The developed mechanistic model describing the behavior of photo-Fenton process treating simulated wastewater can be characterized as interpretable, transparent, flexible and accurate. The comparison of electrical energy costs for each of the studied processes was performed. The obtained results indicate that the process using UV-C source is more efficient and cheaper. However, the simulation of process effectiveness using the solar UV-A irradiation recorded at annual basis for the location of proposed wastewater treatment plant speaks in the favor of solar UV-A/Fe/H2O2 process application instead of artificial UV irradiation.
AU  - Simunovic, Marina
AU  - Kusic, Hrvoje
AU  - Koprivanac, Natalija
AU  - Bozic, Ana Loncaric
DA  - 2011/09/15/
DO  - 10.1016/j.cej.2010.09.030
DP  - ScienceDirect
J2  - Chemical Engineering Journal
KW  - Cost evaluation
Ferrioxalate
Mechanistic model
Photo-Fenton
Simulated industrial wastewater
Solar irradiation
L1  - files/176/Simunovic et al. - 2011 - Treatment of simulated industrial wastewater by ph.pdf
M1  - 2
PY  - 2011
SN  - 1385-8947
SP  - 280-289
ST  - Treatment of simulated industrial wastewater by photo-Fenton process
T2  - Chemical Engineering Journal
TI  - Treatment of simulated industrial wastewater by photo-Fenton process: Part II. The development of mechanistic model
UR  - http://www.sciencedirect.com/science/article/pii/S1385894710008600
files/175/S1385894710008600.html
VL  - 173
Y2  - 2013/01/14/04:28:02
ID  - 281
ER  - 


TY  - JOUR
AB  - The efficiencies of homogeneous and heterogeneous photo-Fenton oxidation were compared for treatment of azo dye containing synthetic textile wastewater. The influence of parameters such as the presence of NaCl and starch was evaluated and optimal iron and H2O2 dosage determined. Complete decolorization of Remazol Red RR was achieved at all investigated NaCl and starch concentration. Mineralization, in terms of COD reduction, was 96% in the homogeneous and 93% in the heterogeneous reaction, but decreased with increasing NaCl and starch concentrations. The homogeneous oxidation showed the highest efficiency in treating synthetic wastewater containing Remazol Blue RR or a mixture of Remazol Red RR and Remazol Blue RR. Nevertheless, the mineralization was significantly lower than for Remazol Red RR, which shows the dependence on dye structure. Similar amounts of iron-containing sludge were produced in the two processes, while the release of iron ions was reduced by 50% when using heterogeneous photo-Fenton. Promising results were obtained when reusing the iron powder as catalyst; complete decolorization was achieved during 20 batches.
AU  - Punzi, M.
AU  - Mattiasson, B.
AU  - Jonstrup, M.
DA  - 2012/11/15/
DO  - 10.1016/j.jphotochem.2012.07.017
DP  - ScienceDirect
J2  - Journal of Photochemistry and Photobiology A: Chemistry
KW  - Azo dye
Photo-Fenton
Sludge
Textile wastewater
Zero valent iron
L1  - files/642/Punzi et al. - 2012 - Treatment of synthetic textile wastewater by homog.pdf
M1  - 0
PY  - 2012
SN  - 1010-6030
SP  - 30-35
ST  - Treatment of synthetic textile wastewater by homogeneous and heterogeneous photo-Fenton oxidation
T2  - Journal of Photochemistry and Photobiology A: Chemistry
TI  - Treatment of synthetic textile wastewater by homogeneous and heterogeneous photo-Fenton oxidation
UR  - http://www.sciencedirect.com/science/article/pii/S1010603012004091
files/641/S1010603012004091.html
VL  - 248
Y2  - 2013/01/15/14:34:50
ID  - 282
ER  - 


TY  - JOUR
AB  - The removal of organic compounds and colour from a synthetic effluent simulating a cotton dyeing wastewater was evaluated by using a combined process of Fenton's Reagent oxidation and biological degradation in a sequencing batch reactor (SBR). The experimental design methodology was first applied to the chemical oxidation process in order to determine the values of temperature, ferrous ion concentration and hydrogen peroxide concentration that maximize dissolved organic carbon (DOC) and colour removals and increase the effluent's biodegradability. Additional studies on the biological oxidation (SBR) of the raw and previously submitted to Fenton's oxidation effluent had been performed during 15 cycles (i.e., up to steady-state conditions), each one with the duration of 11.5 h; Fenton's oxidation was performed either in conditions that maximize the colour removal or the increase in the biodegradability. The obtained results allowed concluding that the combination of the two treatment processes provides much better removals of DOC, BOD5 and colour than the biological or chemical treatment alone. Moreover, the removal of organic matter in the integrated process is particularly effective when Fenton's pre-oxidation is carried out under conditions that promote the maximum increase in wastewater biodegradability.
AU  - Rodrigues, Carmen S. D.
AU  - Madeira, Luis M.
AU  - Boaventura, Rui A. R.
DA  - 2009/12/30/
DO  - 10.1016/j.jhazmat.2009.08.027
DP  - ScienceDirect
J2  - Journal of Hazardous Materials
KW  - Biological degradation
Central composite design
Fenton's reagent
SBR
Textile effluent
L1  - files/537/Rodrigues et al. - 2009 - Treatment of textile effluent by chemical (Fenton'.pdf
M1  - 2–3
PY  - 2009
SN  - 0304-3894
SP  - 1551-1559
ST  - Treatment of textile effluent by chemical (Fenton's Reagent) and biological (sequencing batch reactor) oxidation
T2  - Journal of Hazardous Materials
TI  - Treatment of textile effluent by chemical (Fenton's Reagent) and biological (sequencing batch reactor) oxidation
UR  - http://www.sciencedirect.com/science/article/pii/S0304389409013065
files/536/S0304389409013065.html
VL  - 172
Y2  - 2013/01/15/09:51:52
ID  - 283
ER  - 


TY  - JOUR
AB  - In the present investigation an attempt was made to degrade organic pollutants in the textile effluent by homogeneous and heterogeneous Fenton systems. Experiments were carried out under the batch as well as under the continuous operating conditions. The effect of time, pH, H2O2 concentration, FeSO4.7H2O concentration and the mass of mesoporous activated carbon on the degradation of organics in the wastewater were critically examined. The kinetic constants and the thermodynamic parameters for the oxidation of organics in wastewater were determined. The quantitative removal of COD, BOD and TOC from the wastewater was evaluated. The degradation of organics in textile wastewater was confirmed through FT-IR, UV–Visible spectroscopy, and cyclic voltammetry.
AU  - Karthikeyan, S.
AU  - Titus, A.
AU  - Gnanamani, A.
AU  - Mandal, A. B.
AU  - Sekaran, G.
DA  - 2011/10/17/
DO  - 10.1016/j.desal.2011.08.019
DP  - ScienceDirect
J2  - Desalination
KW  - Heterogeneous Fenton oxidation
Homogeneous Fenton oxidation
Mesoporous activated carbon
Textile wastewater
L1  - files/108/Karthikeyan et al. - 2011 - Treatment of textile wastewater by homogeneous and.pdf
M1  - 0
PY  - 2011
SN  - 0011-9164
SP  - 438-445
ST  - Treatment of textile wastewater by homogeneous and heterogeneous Fenton oxidation processes
T2  - Desalination
TI  - Treatment of textile wastewater by homogeneous and heterogeneous Fenton oxidation processes
UR  - http://www.sciencedirect.com/science/article/pii/S001191641100720X
files/107/S001191641100720X.html
VL  - 281
Y2  - 2013/01/14/03:43:25
ID  - 284
ER  - 


TY  - JOUR
AB  - Attempts were made in this study to examine the efficiency of Fenton process combined with coagulation for treatment of water-based printing ink wastewater. Parameters affecting the Fenton process, such as pH, dosages of Fenton reagents and the settling time, were determined by using jar test experiments. 86.4% of color and 92.4% of chemical oxygen demand (COD) could be removed at pH 4, 50 mg/l H2O2, 25 mg/l FeSO4 and 30 min settling time. The coagulation using polyaluminium chloride (PAC) and ferrous sulfate (FeSO4) was beneficial to improve the Fenton process treated effluent in reducing the flocs settling time, enhancing color and COD removal. The overall color, COD and suspended solids (SS) removal reached 100%, 93.4% and 87.2% under selected conditions, respectively. Thus this study might offer an effective way for wastewater treatment of water-based ink manufacturer and printing corporation.
AU  - Ma, Xiang-Juan
AU  - Xia, Hui-Long
DA  - 2009/02/15/
DO  - 10.1016/j.jhazmat.2008.05.068
DP  - ScienceDirect
J2  - Journal of Hazardous Materials
KW  - Coagulation
Fenton reagents
Polyaluminium chloride
Water-based printing ink
L1  - files/366/Ma and Xia - 2009 - Treatment of water-based printing ink wastewater b.pdf
M1  - 1
PY  - 2009
SN  - 0304-3894
SP  - 386-390
ST  - Treatment of water-based printing ink wastewater by Fenton process combined with coagulation
T2  - Journal of Hazardous Materials
TI  - Treatment of water-based printing ink wastewater by Fenton process combined with coagulation
UR  - http://www.sciencedirect.com/science/article/pii/S030438940800736X
files/365/S030438940800736X.html
VL  - 162
Y2  - 2013/01/15/05:13:56
ID  - 285
ER  - 


TY  - JOUR
AB  - Organic compound, especially aromatic compound is the main pollutant in industrial effluent. Conventional wastewater treatment processes are inefficient for the removal of these types of toxic and hazardous pollutants from wastewater. Electro Fenton is one of the powerful and environmentally friendly emerging technologies for the remediation of wastewaters containing organic, especially aromatic compounds. This paper reviews the fundamentals and recent developments in electro Fenton process. Electro Fenton process utilizes different electrolytic reactors such as bubble reactor, filter press reactor, divided double-electrode electrochemical cell, divided three-electrode electrochemical cell and double compartment cell. Different cathodes as working electrode and anodes as counter electrode used in this process are analyzed. The effects of various operating parameters and their optimum ranges for maximum pollutant removal and mineralization are reviewed. Also various pollutants removed by this process are evaluated. Quick removal and mineralization of pollutants and their intermediate reaction products were reported.
AU  - Nidheesh, P. V.
AU  - Gandhimathi, R.
DA  - 2012/08/01/
DO  - 10.1016/j.desal.2012.05.011
DP  - ScienceDirect
J2  - Desalination
KW  - Degradation
Electro Fenton
Organic pollutant
Wastewater treatment
L1  - files/700/Nidheesh and Gandhimathi - 2012 - Trends in electro-Fenton process for water and was.pdf
M1  - 0
PY  - 2012
SN  - 0011-9164
SP  - 1-15
ST  - Trends in electro-Fenton process for water and wastewater treatment
T2  - Desalination
TI  - Trends in electro-Fenton process for water and wastewater treatment: An overview
UR  - http://www.sciencedirect.com/science/article/pii/S0011916412002603
files/699/S0011916412002603.html
VL  - 299
Y2  - 2013/01/15/15:43:43
ID  - 286
ER  - 


TY  - JOUR
AB  - The applicability of Fenton's oxidation to improve the biodegradability of a pharmaceutical wastewater to be treated biologically was investigated. The wastewater was originated from a factory producing a variety of pharmaceutical chemicals. Treatability studies were conducted under laboratory conditions with all chemicals (having COD varying from 900 to 7000 mg/L) produced in the factory in order to determine the operational conditions to utilize in the full-scale treatment plant. Optimum pH was determined as 3.5 and 7.0 for the first (oxidation) and second stage (coagulation) of the Fenton process, respectively. For all chemicals, COD removal efficiency was highest when the molar ratio of H2O2/Fe2+ was 150–250. At H2O2/Fe2+ ratio of 155, 0.3 M H2O2 and 0.002 M Fe2+, provided 45–65% COD removal. The wastewater treatment plant that employs Fenton oxidation followed by aerobic degradation in sequencing batch reactors (SBR), built after these treatability studies provided an overall COD removal efficiency of 98%, and compliance with the discharge limits. The efficiency of the Fenton's oxidation was around 45–50% and the efficiency in the SBR system which has two reactors each having a volume of 8 m3 and operated with a total cycle time of 1 day, was around 98%, regarding the COD removal.
AU  - Tekin, Huseyin
AU  - Bilkay, Okan
AU  - Ataberk, Selale S.
AU  - Balta, Tolga H.
AU  - Ceribasi, I. Haluk
AU  - Sanin, F. Dilek
AU  - Dilek, Filiz B.
AU  - Yetis, Ulku
DA  - 2006/08/21/
DO  - 10.1016/j.jhazmat.2005.12.012
DP  - ScienceDirect
J2  - Journal of Hazardous Materials
KW  - Biodegradability
Fenton's oxidation
Fenton's reagent
Pharmaceutical wastewater
Pretreatment
L1  - files/316/Tekin et al. - 2006 - Use of Fenton oxidation to improve the biodegradab.pdf
M1  - 2
PY  - 2006
SN  - 0304-3894
SP  - 258-265
ST  - Use of Fenton oxidation to improve the biodegradability of a pharmaceutical wastewater
T2  - Journal of Hazardous Materials
TI  - Use of Fenton oxidation to improve the biodegradability of a pharmaceutical wastewater
UR  - http://www.sciencedirect.com/science/article/pii/S0304389405008186
files/315/S0304389405008186.html
VL  - 136
Y2  - 2013/01/15/04:30:29
ID  - 287
ER  - 


TY  - JOUR
AB  - The oxidation of leachate coming from the composting of two organic wastes (wastewater sludge and organic fraction of municipal solid wastes) using the Fenton's reagent was studied using different ratios [Fe2+]/[COD]0 and maintaining a ratio [H2O2]/[COD]0 equal to 1. The optimal conditions for Fenton reaction were found at a ratio [Fe2+]/[COD]0 equal to 0.1. Both leachates were significantly oxidized under these conditions in terms of COD removal (77 and 75% for leachate from wastewater sludge composting and leachate from organic fraction of municipal solid wastes, respectively) and BOD5 removal (90 and 98% for leachate from wastewater sludge composting and leachate from organic fraction of municipal solid wastes, respectively). Fenton's reagent was found to oxidize preferably biodegradable organic matter of leachate. In consequence, a decrease in the biodegradability of leachates was observed after Fenton treatment for both leachates. Nevertheless, Fenton reaction proved to be a feasible technique for the oxidation of the leachate under study, and it can be considered a suitable treatment for this type of wastewaters.
AU  - Trujillo, Daniel
AU  - Font, Xavier
AU  - Sánchez, Antoni
DA  - 2006/11/02/
DO  - 10.1016/j.jhazmat.2006.05.053
DP  - ScienceDirect
J2  - Journal of Hazardous Materials
KW  - BOD5 removal
COD removal
Composting
Fenton reaction
Leachate
L1  - files/241/Trujillo et al. - 2006 - Use of Fenton reaction for the treatment of leacha.pdf
M1  - 1
PY  - 2006
SN  - 0304-3894
SP  - 201-204
ST  - Use of Fenton reaction for the treatment of leachate from composting of different wastes
T2  - Journal of Hazardous Materials
TI  - Use of Fenton reaction for the treatment of leachate from composting of different wastes
UR  - http://www.sciencedirect.com/science/article/pii/S0304389406005413
files/240/S0304389406005413.html
VL  - 138
Y2  - 2013/01/14/10:03:29
ID  - 288
ER  - 


TY  - JOUR
AB  - Fenton reagent has been used to test the degradation of different organic compounds (formic acid, phenol, 4-chlorophenol, 2,4-dichlorophenol and nitrobenzene) in aqueous solution. A stoichiometric coefficient for the Fenton reaction was found to be 0.5 mol of organic compound/mol of hydrogen peroxide, except for the formic acid where a value of approximately one was obtained (due to the direct formation of carbon dioxide). The treatment eliminates the toxic substances and increases the biodegradability of the treated water (measured as the ratio BOD5/COD). Biodegradability is attained when the initial compound is removed.
AU  - Chamarro, E.
AU  - Marco, A.
AU  - Esplugas, S.
DA  - 2001/03//
DO  - 10.1016/s0043-1354(00)00342-0
DP  - ScienceDirect
J2  - Water Research
KW  - advanced oxidation technologies (AOT)
Fenton reagent
L1  - files/319/Chamarro et al. - 2001 - Use of fenton reagent to improve organic chemical .pdf
M1  - 4
PY  - 2001
SN  - 0043-1354
SP  - 1047-1051
ST  - Use of fenton reagent to improve organic chemical biodegradability
T2  - Water Research
TI  - Use of fenton reagent to improve organic chemical biodegradability
UR  - http://www.sciencedirect.com/science/article/pii/S0043135400003420
files/318/S0043135400003420.html
VL  - 35
Y2  - 2013/01/15/04:30:29
ID  - 289
ER  - 


TY  - JOUR
AB  - This study investigated the potential of biological treatment as a single process as well as in association with chemical oxidation to treat a textile wastewater. The experimental part incorporated the following three schemes: biological treatment only (stage 1), chemical oxidation prior to biological treatment (stage 2), and biological treatment followed by chemical oxidation (stage 3). Biodegradation was accomplished employing three identical sequencing batch reactors (SBRs), each having a liquid volume of 10 L, while chemical treatment involved the addition of Fenton’s reagent in the range 25–300 mg/L, in a batch-type operation. Following an acclimation period of approximately 60 days, biological treatment resulted in a high percent reduction in chemical oxygen demand (COD), total Kjeldahl nitrogen (TKN), and total phosphorus (TP), and in a moderate decrease in color. The process was found to be independent of the variations in the anoxic time period studied; however, an increase in solids retention time (SRT) improved COD and color removal, although it reduced the nutrient (TKN and TP) removal efficiency. Furthermore, both combined treatment alternatives resulted in enhanced color reduction, in comparison to stage 1. Overall, chemical oxidation prior to biological treatment (stage 2) appears to be the best option regarding the treatment of the textile wastewater used.
AU  - Fongsatitkul, P.
AU  - Elefsiniotis, P.
AU  - Yamasmit, A.
AU  - Yamasmit, N.
DA  - 2004/11//
DO  - 10.1016/j.bej.2004.06.009
DP  - ScienceDirect
J2  - Biochemical Engineering Journal
KW  - Biodegradation
Chemical oxidation
Sequencing batch reactors
Textile wastewater treatment
L1  - files/534/Fongsatitkul et al. - 2004 - Use of sequencing batch reactors and Fenton’s reag.pdf
M1  - 3
PY  - 2004
SN  - 1369-703X
SP  - 213-220
ST  - Use of sequencing batch reactors and Fenton’s reagent to treat a wastewater from a textile industry
T2  - Biochemical Engineering Journal
TI  - Use of sequencing batch reactors and Fenton’s reagent to treat a wastewater from a textile industry
UR  - http://www.sciencedirect.com/science/article/pii/S1369703X04001858
files/533/S1369703X04001858.html
VL  - 21
Y2  - 2013/01/15/09:51:52
ID  - 290
ER  -